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1.
The term “working landscape” (WL) is increasingly used by American planners and policy makers to describe the rural places and livelihoods they aim to shape. This paper draws from a mixed-methods study of WL language as a collective action frame in the state of Vermont, where WL has been formalized into policy. Natural resource leaders and professionals share a common definition of WL that is supported by four key beliefs. However, interviews conducted in two representative farming communities suggest that landuse practitioners have not adopted WL language, and in some cases are skeptical of its meaning. The analysis explores potential explanations for the failure of the WL collective action frame to resonate across scales. The paper argues for a bottom-up planning approach that produces working landscapes policies that allow for diverse forms of work and accommodate the specificities of place.  相似文献   
2.
Saturated floodplains in Arctic deltas provide conditions favourable for frost mound growth. Little work has been reported from these settings to determine the origin of frost mounds and the controls on their distribution, to assess the longevity of individual mounds, or to quantify variation of mound distribution over time. A case study is presented on low mounds in low‐centred syngenetic ice‐wedge polygons of Big Lake Delta Plain, outer Mackenzie Delta. In 2008 and 2009, 12 mounds were examined by drilling to describe their morphologic variations and to investigate their growth processes. The mounds, containing a core of ice 15 to 58 cm thick, were less than 1 m high and 3 · 7 to 8 · 5 m in diameter; other mounds were over 10 m long. Organic inclusions in the ice, bubble densities, electrical conductivity profiles, and ice‐crystal structure indicated that the mounds were hydrostatic frost blisters. Up to six frost blisters were found within individual polygons due to the relatively small volume of water needed to create each mound. Frost‐blister densities, of greater than 1700 km–2, increased toward the wet centres of alluvial islands down gentle topographic gradients. The frost blisters were perennial, with individuals remaining identifiable on aerial photographs and satellite images for up to 10 years. Frost blisters collapsed along dilation cracks opened by hydrostatic uplift and by thawing from their sides caused by snow drifting and water ponding. Cyclical growth and decay of the mounds may degrade the visible polygonal network over time. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
3.
Sediment samples were selected from 28 sites across the deep (212–3527 m) northern Gulf of Mexico (GOM) as part of the Deep Gulf of Mexico Benthos (DGoMB) program, and analyzed for geochemical parameters related to organic carbon (OC) distribution and characteristics. The results of this study indicate that the OC content of sediments in the deep northern GOM is controlled by several factors; including water depth, overlying water productivity, sediment carbonate content, sediment oxygen exposure time, OC sources, and regional influences. The best correlation between sediment OC content, on a CaCO3-free basis, and other parameters examined was an inverse correlation of OC with water depth. The OC/SA ratio had a wide range of values and, along with variable sources of sedimentary OC, indicated that the organism-available concentration of metabolizable organic matter may not be simply related to sedimentary OC content. This was perhaps reflected in the observation that benthic macrofaunal and meiofaunal biomass abundances were well correlated with sedimentary OC, but the abundance of bacteria in sediments was not.  相似文献   
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An investigation has been made of available data on the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on Ocean Thermal Energy Conversion (OTEC) heat exchangers. Pertinent oceanographic data is lacking at or near potential OTEC sites for the calculation of the degree of saturation of seawater with respect to calcium carbonate. Consequently, only “extrapolated” saturation values can be used. These indicate that near surface seawater is probably supersaturated, with respect to the calcium carbonate phases calcite and aragonite, at all potential OTEC sites. The deep seawater that would be brought to the surface at the potential Atlantic Ocean sites is also likely to be supersaturated with respect to calcium carbonate. The deep seawater at the potential Pacific Ocean sites may be slightly undersaturated.The fact that OTEC heat exchangers will be operating in seawater, which is supersaturated with respect to calcium carbonate, means that if nucleation of calcite or aragonite occurs on the heat exchanger surfaces, significant growth rates of calcium carbonate scale may be expected. The potential for calcium carbonate nucleation is highest at cathodic metal surface locations, which are produced as the result of aluminum corrosion in seawater. Consequently, corrosion and scale formation may be closely related. What the possible effects of biofouling may be on this process are not known.  相似文献   
6.
Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.  相似文献   
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8.
The formation of earliest stable planetary crust poses the following dilemma. All surface crusts formed by direct quenching of planetary-scale magma are mafic and dense, and will founder. All felsic crystals light enough to float will form only after protracted differentiation and will grow too slowly to be separated from their parent magma on the short timescale of near-surface residence. Early crust must be intrinsically stable to accretionary bombardment in order to survive, hence it must float. One solution is to make pop-up felsic crust on a rapid time scale by collecting the lighter evolved liquid, not the crystals. Such a liquid is produced by solute rejection at depth from growing mafic crystals, and it rises by compositional convection. It stirs and cools the magma and reduces the accretionary thermal maximum, perhaps to zero. It has a high viscosity and high barrier to nucleation, hence may coalesce metastably. Near the surface, rapid crystallization will follow spontaneous nucleation. Rafts and rockbergs will coalesce to form the earliest crust. On the moon, this is anorthositic. On the earth, the presence of water enhances the silica content of the network-rich liquid and gives rise to tonalite. Existing ancient tonalites may reflect an original tonalitic crust. Modern oceanic rhyolites and trondhjemites may owe their existence to a similar process of liquid collection, and could therefore serve as a test of the crust-forming hypothesis.  相似文献   
9.
The chemistry of orthophosphate uptake from synthetic seawater onto the surfaces of synthetic calcite, aragonite and low-magnesium biogenic calcite has been studied, in order to elucidate the kinetics of the process (generally believed to be the major control of dissolved reactive phosphate in carbonate-rich marine sediments). Our results differ from those obtained by others, who have studied orthophosphate uptake in low ionic strength solutions and at much higher supersaturations relative to apatite.In both ‘free drift’ and chemostat experiments, Mg and F have only a minor effect on the reaction rate. Even at constant solution composition the rate of orthophosphate uptake was found to decrease by 106 over a two week period. The data from the ‘free drift’ experiments can be fitted to the Elovich equation. This indicates that the kinetics observed for this reaction can be explained by an exponential decrease in available surface reaction sites and/or a linear increase in the activation energy associated with chemisorption as the reaction proceeds.  相似文献   
10.
The primary factors that control the concentration of total reduced (inorganic) sulfide in coastal sediments are believed to be the availability of reactive iron, dissolved sulfate and metabolizable organic carbon. We selected nine sites in shallow (<3 m), close to sub-tropical, estuaries and bays along the central Texas coast that represented a range in sediment grain size (a proxy for reactive iron), salinity (a proxy for dissolved sulfate), and total organic carbon (a proxy for metabolizable organic carbon). Based on these parameters a prediction was made of which factor was likely to control total reduced sulfide at each site and what the relative total reduced sulfide concentration was likely to be. To test the prediction, the sediments were analyzed for total reduced sulfide, acid volatile sulfide, and citrate dithionate-extractable, HCl-extractable and total Fe in the solid phase. Using solid-state gold–mercury amalgam microelectrodes and voltammetry, we determined pore water depth profiles of Fe(II) and ΣH2S and presence or absence of FeS(aq). At five of the nine sites the calculated degree of sufildization of citrate dithionite-reactive-iron was close to or greater than 1 indicating that rapidly reactive iron was probably the limiting factor for iron sulfide mineral formation. At one site (salinity = 0.9) dissolved Fe(II) was high, ΣH2S was undetectable and the total reduced sulfide concentration was low indicating sulfate limitation. At the last three sites a low degree of sulfidization and modest total reduced (inorganic) sulfide concentrations appeared to be the result of a limited supply of metabolizable organic carbon. Fe(II)–S(-II) clusters (FeS(aq)) were undetectable in 10 out of 12 bay sediment profiles where ΣH2S was close to or below detection limits, but was observed in all other porewater profiles. Acid volatile sulfide, but not total reduced sulfide, was well correlated with total organic carbon and ranged from being undetectable in some cores to representing a major portion of total reduced sulfide in other cores. Although predicted controls on total reduced sulfide were good for very low salinity water or sandy sediments, they were only right about half the time for the other sediments. The likely reasons for the wrong predictions are the poor correlation of total organic carbon with grain size and differing fractions of metabolizable organic carbon in different sedimentary environments. Differences in sediment accumulation rates may also play a role, but these are difficult to determine in this region where hurricanes often resuspend and move sediments. This study demonstrates the need to examine more complex and often difficult to determine parameters in anoxic “normal marine” sediments if we are to understand what controls the concentration and distribution of sulfides.  相似文献   
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