Interaction of bentonite colloids with Cs, Eu, Th and U in presence of humic acid: A flow field-flow fractionation study   总被引：2，自引：0，他引：2  

Muriel Bouby  Horst Geckeis  Silvia Mihai  Thorsten Schäfer 《Geochimica et cosmochimica acta》2011,75(13):3866-3880

The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10⁻³ mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca²⁺ concentration of 2.1 × 10⁻⁴ mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca²⁺ ion exchange against Li⁺ and Na⁺ at the permanently charged basal clay planes. Furthermore, the Ca²⁺ concentration lies close to the critical coagulation concentration (CCC) of 10⁻³ mol L⁻¹ for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO₂(OH)₃⁻ complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.  相似文献   

Evaluation of hydrogeochemical processes and groundwater quality for suitability of drinking and irrigation purposes: a case study in the Aosta Valley region,Italy     

Ashwani Kumar Tiwari  Raffaella Ghione  Marina De Maio  Muriel Lavy 《Arabian Journal of Geosciences》2017,10(12):264

The present study aims to discuss the hydrogeochemical processes in the Aosta Valley region and assess the quality of its groundwater for suitability of drinking and irrigation purposes. One hundred twenty-two samples were collected from the Aosta Valley region in the years 2007 and 2008 (61 per year), and analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, major cations and anions. The pH of the samples in both years indicated a near-neutral to alkaline nature of the groundwater. The cation and anion chemistry showed the general ionic abundance as: Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ and HCO₃ ^?>SO₄ ^2?>Cl^?>NO₃ ^?>F^? in both years. Ca²⁺-Mg²⁺-HCO₃ ^? and Ca²⁺-Mg²⁺-Cl^?-SO₄ ^2? were the dominant hydrogeochemical facies. The computed saturation indices demonstrated that the groundwater was supersaturated with respect to dolomite and calcite in both years. The groundwater chemistry of the study area was mainly controlled by the dissolution of carbonate, sulphate and silicate minerals, as well as ion exchange processes. A comparison of the groundwater quality in relation to drinking water standards showed that most of the water samples were suitable for drinking and domestic uses. The computed water quality index (WQI) values of the study area groundwater ranged from 24 to 84 in the year 2007 and from 22 to 82 in the year 2008, and all the location fell under the Excellent to Good category. Quality assessment for irrigation uses revealed that the groundwater was good to permissible quality for irrigation; however, locally higher salinity, residual sodium carbonate (RSC) and magnesium hazard (MH) restricted its suitability for irrigation at a few sites. These results will be useful in implementing future measures in groundwater resource management at regional and national level.  相似文献   

Astronomical Site Testing in Northwest of Argentina     

Pablo Recabarren  Pablo Recabarren  Mirta Mosconi  Hernán Muriel  Hernán Muriel  Diego García Lambas  Diego García Lambas  Marc Sarazin  Riccardo Giovanelli 《Astrophysics and Space Science》2004,290(3-4):409-413

We present the preliminary results of the astronomical site testing, which the group IATE of the OAC is developing in northwest of Argentine in collaboration with ESO and the Department of Astronomy of Cornell University. We show the results, which we have obtained from the analysis of GOES 8 satellite images in the 10.7 μm band, which allowed us to configurate a map of clear sky regions in an area between 23° and 28° S, and 66° 30′ and 69° W. We also comment logistical and tectonic aspects, and discuss next steps to follow in the research.  相似文献   

Groups of galaxies: relationship between environment and galaxy properties     

Héctor J. Martínez  Hernán Muriel 《Monthly notices of the Royal Astronomical Society》2006,370(2):1003-1007

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Monitoring Moisture Migration in the Vadose Zone with Resistivity   总被引：1，自引：0，他引：1  

William F. Kean  Muriel Jennings Waller  H. Richard Layson 《Ground water》1987,25(5):562-571

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Velocity dispersion estimates of APM galaxy clusters     

M. Victoria Alonso  Carlos Valotto  Diego G. Lambas  Hernán Muriel 《Monthly notices of the Royal Astronomical Society》1999,308(3):618-622

We present 83 new galaxy radial velocities in the field of 18 APM clusters with redshifts between 0.06 and 0.13. The clusters have Abell identifications and the galaxies were selected within 0.75  h ⁻¹ Mpc in projection from their centres. We derive new cluster velocity dispersions for 13 clusters using our data and published radial velocities.
We analyse correlations between cluster velocity dispersions and cluster richness counts as defined in Abell and APM catalogues. The correlations show a statistically significant trend although with a large scatter, suggesting that richness is a poor estimator of cluster mass irrespectively of cluster selection criteria and richness definition. We find systematically lower velocity dispersions in the sample of Abell clusters that do not fulfil APM cluster selection criteria, suggesting artificially higher Abell richness counts owing to contamination by projection effects in this subsample.  相似文献   

Serpentinites act as sponges for fluid‐mobile elements in abyssal and subduction zone environments     

Fabien Deschamps  Stéphane Guillot  Marguerite Godard  Muriel Andreani  Kéiko Hattori 《地学学报》2011,23(3):171-178

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Benthic species as mud patrol - modelled effects of bioturbators and biofilms on large-scale estuarine mud and morphology     

Muriel Z.M. Brückner  Christian Schwarz  Giovanni Coco  Anne Baar  Márcio Boechat Albernaz  Maarten G. Kleinhans 《地球表面变化过程与地形》2021,46(6):1128-1144

Sediment-stabilizing and -destabilizing organisms, i.e. microphytobenthos (biofilms) and macrozoobenthos (bioturbators), affect the erodibility of muddy sediments, potentially altering large-scale estuarine morphology. Using a novel eco-morphodynamic model of an idealized estuary, we investigate eco-engineering effects of microphytobenthos and two macrozoobenthic bioturbators. Local mud erodibility is based on species pattern predicted through hydrodynamics, soil mud content, competition and grazing. Mud resuspension and export is enhanced under bioturbation and prevented under biostabilization through respective exposure and protection of the supra- and intertidal. Bioturbation decreases mud thickness and bed elevations, which increases net mud fluxes. Microphytobenthos reduces erosion, leading to a local mud increase of intertidal sediments. In multi-species scenarios, an effective mud-prone bioturbator strongly alters morphology, exceeding that of a more abundant sand-prone moderate species, showing that morphological change depends on species traits as opposed to abundance. Altering their habitat, the effective mud-prone bioturbator facilitates expansion of the sand-prone moderate bioturbator. Grazing and species competition favor species distributions of dominant bioturbators. Consequently, eco-engineering affects habitat conditions while species interactions determine species dominance. Our results show that eco-engineering species determine the mud content of the estuary, which suggests large effects on the morphology of estuaries with aggravating habitat degradation.  相似文献   

Multi-technique monitoring of ocean tide loading in northern France     

Muriel Llubes  Nicolas Florsch  Jean-Paul Boy  Martine Amalvict  Pascal Bonnefond  Marie-Noëlle Bouin  Stphane Durand  Marie-France Esnoult  Pierre Exertier  Jacques Hinderer  Marie-Franoise Lalancette  Frdric Masson  Laurent Morel  Joëlle Nicolas  Mathilde Vergnolle  Guy Wppelmann 《Comptes Rendus Geoscience》2008,340(6):379-389

We have organised afield study of ocean tide loading in the northwestern part of France, where tidal amplitudes are known to be among the highest in the world. GPS and gravimetric techniques have already proved their capability to measure such weak and high-frequency signals. In this study, these classical observations are complemented with less usual techniques, such as tiltmeter and Satellite Laser Ranging (SLR) measurements. We present here the preliminary results for a common period of observations spanning from 12–19 May 2004. Additional measurements from the French Transportable Laser Ranging Station (FTLRS) were available during September and October 2004. Observation residuals are computed as the difference between the observed and the predicted time signals. We obtain small RMS residuals for GPS measurements (2.5/3.1/4.5 mm for the eastward, northward and upward components), for absolute and relative gravimetry (9 nm/s² and 13 nm/s²) and for tiltmeters (0.05 μrad for EW component). We also fit the amplitude of the main M2 tidal constituent to FTLRS observations and we find a value of 3.731 cm, which is comparable to the theoretical value.  相似文献   

6. Environmental Context     

Hervé Martin  Philippe Claeys  Muriel Gargaud  Daniele Pinti  Franck Selsis 《Earth, Moon, and Planets》2006,98(1-4):205-245

On Earth, the Archaean aeon lasted from 4.0 to 2.5 Ga; it corresponds to a relatively stable period. Compared with today, internal Earth heat production was several times greater resulting in high geothermal flux that induced the genesis of rocks such as komatiites and TTG suites, which are no more generated on Earth since 2.5 Ga. Similarly, the details of plate tectonic modalities (plate size, plate motion rate, plate thickness, tectonic style, irregular crustal growth, etc...) were different of modern plate tectonics. Both atmosphere and ocean compositions have been progressively modified and the greater heat production favoured the development of hydrothermalism and therefore created niches potentially favourable for the development of some forms of life. Catastrophic events such as giant meteorite falls or world-sized glaciations drastically and suddenly changed the environment of Earth surface, thus being able to strongly affect development of life. Even if specialists still debate about the age of the oldest indubitable fossil trace of life, Archaean can be considered as having been extremely favourable for life development and diversification.  相似文献