Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry     

Daniel P. Glavin  Jason P. Dworkin  Andrew Aubrey  Oliver Botta  James H. Doty  Zita Martins  Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.  相似文献   

Large-scale structure in the ELAIS S1 Survey     

E. A. Gonzalez-Solares  S. Oliver  C. Gruppioni  F. Pozzi  C. Lari  M. Rowan-Robinson  S. Serjeant  F. La Franca  M. Vaccari 《Monthly notices of the Royal Astronomical Society》2004,352(1):44-48

  相似文献   

The ELAIS deep X-ray survey – I. Chandra source catalogue and first results     

J. C. Manners †  O. Johnson  O. Almaini  C. J. Willott  E. Gonzalez-Solares  A. Lawrence  R. G. Mann  I. Perez-Fournon  J. S. Dunlop  R. G. McMahon  S. J. Oliver  M. Rowan-Robinson  S. Serjeant 《Monthly notices of the Royal Astronomical Society》2003,343(1):293-305

  相似文献   

Project cyclops study: Conclusions and recommendations     

Bernard M. Oliver 《Icarus》1973,19(3):425-428

  相似文献   

Fe57 Mossbauer spectroscopy of the Leoville meteorite     

Frederick W. Oliver 《Planetary and Space Science》1978,26(3):289-290

The Mossbauer spectra has been measured for the Leoville meteorite. Experimental results identify it as a type III carbonaceous meteorite. The spectrum shows the principle iron components to be olivine, magnetite, metallic iron, troilite and phyllosilicate material.  相似文献   

Proximity of galactic civilizations     

B.M. Oliver 《Icarus》1975,25(2):360-367

Approximate expressions are derived for the number of civilizations within a few tens of light years of each other since intelligent life first evolved in the Galaxy. The number is proportional to the square of the usual selectivity factors and to the first power of the longevity. Arguments are presented for expecting intelligent life in certain multiple star systems, and the number of coexistent civilizations in such systems is estimated.  相似文献   

The enigma of helium and anomalous xenon     

Oliver K. Manuel 《Icarus》1980,41(2):312-315

Isotopically anomalous xenon in chondrites is closely associated with low-Z noble gases, but there is no helium (or neon) in the noble gas component with normal xenon. The correlation of elemental and isotopic heterogeneities in meteoritic noble gases places stringent limits on the origin of isotopically anomalous elements in meteorites and on the formation of the solar system.  相似文献   

Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia     

Geordie Mark  Nicholas H. S. Oliver  Patrick J. Williams 《Mineralium Deposita》2006,40(8):769-801

The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pb_titanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis.  相似文献   

Rapid orbit determination of LEO satellites using IGS clock and ephemeris products   总被引：4，自引：2，他引：4  

Oliver Montenbruck  Eberhard Gill  Remco Kroes 《GPS Solutions》2005,9(3):226-235

Different types of GPS clock and orbit data provided by the International GPS Service (IGS) have been used to assess the accuracy of rapid orbit determination for satellites in low Earth orbit (LEO) using spaceborne GPS measurements. To avoid the need for reference measurements from ground-based reference receivers, the analysis is based on an undifferenced processing of GPS code and carrier-phase measurements. Special attention is therefore given to the quality of GPS clock data that directly affects the resulting orbit determination accuracy. Interpolation of clock data from the available 15 min grid points is identified as a limiting factor in the use of IGS ultra-rapid ephemerides. Despite this restriction, a 10-cm orbit determination accuracy can be obtained with these products data as demonstrated for the GRACE-B spacecraft during selected data arcs between 2002 and 2004. This performance may be compared with a 5-cm orbit determination accuracy achievable with IGS rapid and final products using 5 min clock samples. For improved accuracy, high-rate (30 s) clock solutions are recommended that are presently only available from individual IGS centers. Likewise, a reduced latency and more frequent updates of IGS ultra-rapid ephemerides are desirable to meet the requirements of upcoming satellite missions for near real-time and precise orbit determination.  相似文献   

Evaluation of the Reduction in Uncertainty Obtained by Conditioning a 3D Stochastic Channel to Multiwell Pressure Data     

Fengjun Zhang  Albert C. Reynolds  Dean S. Oliver 《Mathematical Geology》2002,34(6):715-742

A stochastic channel embedded in a background facies is conditioned to data observed at wells. The background facies is a fixed rectangular box. The model parameters consist of geometric parameters that describe the shape, size, and location of the channel, and permeability and porosity in the channel and nonchannel facies. We extend methodology previously developed to condition a stochastic channel to well-test pressure data, and well observations of the channel thickness and the depth of the top of the channel. The main objective of this work is to characterize the reduction in uncertainty in channel model parameters and predicted reservoir performance that can be achieved by conditioning to well-test pressure data at one or more wells. Multiple conditional realizations of the geometric parameters and rock properties are generated to evaluate the uncertainty in model parameters. The ensemble of predictions of reservoir performance generated from the suite of realizations provides a Monte Carlo estimate of the uncertainty in future performance predictions. In addition, we provide some insight on how prior variances, data measurement errors, and sensitivity coefficients interact to determine the reduction in model parameters obtained by conditioning to pressure data and examine the value of active and observation well data in resolving model parameters.  相似文献