Effect of leaf litter degradation and seasonality on D/H isotope ratios of n-alkane biomarkers     

Michael Zech  Nikolai Pedentchouk  Katharina Leiber  Slobodan B. Markovi? 《Geochimica et cosmochimica acta》2011,75(17):4917-4928

During the last decade, compound-specific hydrogen isotope analysis of plant leaf-wax and sedimentary n-alkyl lipids has become a promising tool for paleohydrological reconstructions. However, with the exception of several previous studies, there is a lack of knowledge regarding possible effects of early diagenesis on the δD values of n-alkanes. We therefore investigated the n-alkane patterns and δD values of long-chain n-alkanes from three different C3 higher plant species (Acer pseudoplatanus L., Fagus sylvatica L. and Sorbus aucuparia L.) that have been degraded in a field leaf litterbag experiment for 27 months.We found that after an initial increase of long-chain n-alkane masses (up to ∼50%), decomposition took place with mean turnover times of 11.7 months. Intermittently, the masses of mid-chain n-alkanes increased significantly during periods of highest total mass losses. Furthermore, initially high odd-over-even predominances (OEP) declined and long-chain n-alkane ratios like n-C₃₁/C₂₇ and n-C₃₁/C₂₉ started to converge to the value of 1. While bulk leaf litter became systematically D-enriched especially during summer seasons (by ∼8‰ on average over 27 months), the δD values of long-chain n-alkanes reveal no systematic overall shifts, but seasonal variations of up to 25‰ (Fagus, n-C₂₇, average ∼13‰).Although a partly contribution by leaf-wax n-alkanes by throughfall cannot be excluded, these findings suggest that a microbial n-alkane pool sensitive to seasonal variations of soil water δD rapidly builds up. We propose a conceptual model based on an isotope mass balance calculation that accounts for the decomposition of plant-derived n-alkanes and the build-up of microbial n-alkanes. Model results are in good agreement with measured n-alkane δD results. Since microbial ‘contamination’ is not necessarily discernible from n-alkane concentration patterns alone, care may have to be taken not to over-interpret δD values of sedimentary n-alkanes. Furthermore, since leaf-water is generally D-enriched compared to soil and lake waters, soil and water microbial n-alkane pools may help explain why soil and sediment n-alkanes are D-depleted compared to leaves.  相似文献   

Experimental synthesis of seismic horizontal free-field motion of soil in finite-domain simulations with absorbing boundary     

Ronald Y.S. Pak  Mahdi SoudkhahFarzad Abedzadeh 《Soil Dynamics and Earthquake Engineering》2011

In this paper, a fundamental assessment of the method of physical wave-absorbing boundary and centrifuge modeling is presented in the context of experimental simulations of seismic free-field ground motion. Focusing on the characteristics of a sand stratum, a series of seismic tests on models of uniform density and a large width-to-depth ratio with Duxseal as the side boundary were performed using an in-box shake-table system. By means of the transfer function approach in the frequency domain, the complex three-dimensional nature of the dynamic response of the finite soil model with the boundary treatment is demonstrated in terms of its variable resonant frequency distribution at different g-levels. Apart from being helpful in quantifying the difficulty in interpreting the finite-domain response simulations using one-dimensional theories or homogenized representations, the measured data substantiates the need and usefulness of coupling the Duxseal boundary approach with a three-dimensional elastodynamic synthesis. With the aid of a corresponding boundary element implementation, the feasibility of identifying the soil's in-flight shear modulus variation, Poisson's ratio and horizontal-to-vertical earth pressure ratio from the centrifuge model's free-field measurements is also explored.  相似文献   

Preface: Value and dynamics of salt lakes in a changing world     

Aharon  Oren  Deng  Tianlong  Shadrin  Nikolai V.  Zheng  Mianping  Zadereev  Egor S. 《中国海洋湖沼学报》2018,36(6):1901-1906

正Thestatementthattheworld’secosystemsare rapidly deteriorating due to human intervention and global warming is nowadays commonplace. Some o the ecosystems most heavily impacted are inland sal lakes. The salt lakes are among the most valuable and fascinating ecosystems on Earth, and their study has both basic scientifi c interest as well as applied aspects  相似文献   

Weakly compressible SPH simulation of cnoidal waves with strong plunging breakers     

Sarfaraz  Mohammad  Pak  Ali 《Ocean Dynamics》2019,69(6):657-678

Ocean Dynamics - Hydrodynamics of highly nonlinear cnoidal waves and their subsequent strong plunging breakers are among the least understood and most significant issues in coastal engineering. In...  相似文献   

Elastic lateral dynamic impedance functions for a rigid cylindrical shell type foundation          下载免费PDF全文

R. He  R.Y.S. Pak  L.Z. Wang 《国际地质力学数值与分析法杂志》2017,41(4):508-526

Elastic lateral dynamic impedance functions are defined as the ratio of the lateral dynamic force/moment to the corresponding lateral displacement/rotation at the top ending of a foundation at very small strains. Elastic lateral dynamic impedance functions have a defining influence on the natural frequencies of offshore wind turbines supported on cylindrical shell type foundations, such as suction caissons, bucket foundations, and monopiles. This paper considers the coupled horizontal and rocking vibration of a cylindrical shell type foundation embedded in a fully saturated poroelastic seabed in contact with a seawater half‐space. The formulation of the coupled seawater–shell–seabed vibration problem is simplified by treating the shell as a rigid one. The rigid shell vibration problem is approached by the integral equation method using ring‐load Green's functions for a layered seawater‐seabed half‐space. By considering the boundary conditions at the shell–soil interface, the shell vibration problem is reduced to Fredholm integral equations. Through an analysis of the corresponding Cauchy singular equations, the intrinsic singular characteristics of the problem are rendered explicit. With the singularities incorporated into the solution representation, an effective numerical method involving Gauss–Chebyshev method is developed for the governing Fredholm equations. Selected numerical results for the dynamic contact load distributions, displacements of the shell, and lateral dynamic impedance functions are examined for different shell length–radius ratio, poroelastic materials, and frequencies of excitation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Pore scale study of permeability and tortuosity for flow through particulate media using Lattice Boltzmann method     

Ali Ghassemi  Ali Pak 《国际地质力学数值与分析法杂志》2011,35(8):886-901

In this paper, Lattice Boltzmann method (LBM) has been used to study the effects of permeability and tortuosity on flow through saturated particulate media and identify the relationships between permeability and tortuosity with other parameters such as particles diameter, grain specific surface, and porosity. LBM is a simple kinematic model that can incorporate the essential physics of microscopic and mesoscopic processes involved in flow through granular soils. The obtained results indicate that the 2D LB model, due to its inherent theoretical advantages, is capable of demonstrating that the porosity and specific surface are the most influential parameters in determining the intrinsic permeability of granular media. The obtained results show that particles' size diameter has a two‐fold effect on the coefficient of permeability: one is through specific surface and the other is by tortuosity factor. Numerical study also reveals that tortuosity of granular soils decreases almost linearly with increasing the porosity. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Observations of natural fluorescence with an underwater radiometer     

James C. Kitchen  Hasong Pak 《Journal of Oceanography》1987,43(6):356-362

Measurements of subsurface irradiance spectra in the ocean consistently indicate intensities of long-wavelength visible light (589 nm) greater than could be derived from the penetration of sunlight. This can be attributed to natural fluorescence and/or to spectral crosstalk due to light leakage through the blocking filters of each discrete detector. A comparison of observed profiles with modelled contributions from these two possible sources indicates that both factors are contributing. At 671 and 694 nm wavelength, the excess signal appears to be predominantly fluorescence while that at 589 nm is mostly crosstalk. Both effects appear to be important at 625 nm although the amount of excess light is small compared to the other wavelengths.The above observations and interpretations are consistent with the optical design of the instrument used and the shape of natural irradiance spectra. Fluorescence efficiencies derived from the irradiance measurements correlate well with measuredin situ fluorescence.  相似文献   

Composition and distribution of copepods, a major prey of capelin in the central Barents Sea, in moderate and warm years     

Orlova  Emma L.; Boitsov  Vladimir D.; Nesterova  Valentina N.; Ushakov  Nikolai G. 《ICES Journal of Marine Science》2002,59(5):1053-1061

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Multi-scale characterization of a complex karst and alluvial aquifer system in southern Germany using a combination of different tracer methods     

Fahrmeier  Nikolai  Frank  Simon  Goeppert  Nadine  Goldscheider  Nico 《Hydrogeology Journal》2022,30(6):1863-1875

Water suppliers face major challenges such as climate change and population growth. To prepare for the future, detailed knowledge of water resources is needed. In southern Germany, the state water supplier Zweckverband Landeswasserversorgung provides 3 million people with drinking water obtained from a complex karst and alluvial aquifer system and the river Danube. In this study, a combination of different tracing techniques was used with the goal of a multi-scale characterization of the aquifer system and to gain additional knowledge about groundwater flow toward the extraction wells in the Danube Valley. For the small-scale characterization, selected groundwater monitoring wells were examined using single-borehole dilution tests. With these tests, a wide range of flow behavior could be documented, including fast outflow within just a few hours in wells with good connection to the aquifer, but also durations of many weeks in low-permeability formations. Vertical flow, caused by multiple flow horizons or uprising groundwater, was detected in 40% of the tested wells. A regional multi-tracer test with three injections was used to investigate the aquifer on a large scale. For the highly karstified connection between a swallow hole and a spring group, high flow velocities of around 80 m/h could be documented. Exceptionally delayed arrivals, 250 and 307 days after the injection, respectively showing maximum velocities of 0.44 and 0.39 m/h, were observed in an area where low-permeability sediments overlay the karst conduits. With the chosen methods, a distinct heterogeneity caused by the geological setting could be documented on both scales.

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The Type IIn supernova 1994W: evidence for the explosive ejection of a circumstellar envelope     

Nikolai N. Chugai  Sergei I. Blinnikov  Robert J. Cumming  Peter Lundqvist  Angela Bragaglia  Alexei V. Filippenko  Douglas C. Leonard  Thomas Matheson  Jesper Sollerman 《Monthly notices of the Royal Astronomical Society》2004,352(4):1213-1231

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