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An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes. 相似文献
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This paper illustrates the seismic risk preliminary estimates of two different groups of structures located on the territory of the Friuli–Venezia Giulia region (NE Italy) : the first group includes some special industrial plants, and the second group includes bridges and tunnels belonging to the regional highway network. The part of the study on special industrial plants tries to evaluate the degree of expected damage, taking into account their structural typology and ground shaking expressed in terms of macroseismic intensity. The second part of the study is an application of the HAZUS methodology to the tunnels and bridges of a highway network: the combination of expected ground shaking and the construction characteristics lead to very different risk levels, especially when considering the bridges. The resulting damage levels to bridges and tunnels are still only indicative because of the fragility curves used in the evaluations: they were developed for existing bridge and tunnel structural typologies in the U.S.A. Moreover, both examples show the power of GIS technology in storing, elaborating, and mapping spatial data. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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Optimal parametrization of tomographic models 总被引：1，自引：0，他引：1
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The 1631 Vesuvius eruption. A reconstruction based on historical and stratigraphical data 总被引：1，自引：0，他引：1
Mauro Rosi Claudia Principe Raffaella Vecci 《Journal of Volcanology and Geothermal Research》1993,58(1-4)
The eruption of 1631 A.D. was the most violent and destructive event in the recent history of Vesuvius. More than fifty primary documents, written in either Italian or Latin, were critically examined, with preference given to the authors who eyewitnessed volcanic phenomena. The eruption started at 7 a.m. on December 16 with the formation of an eruptive column and was followed by block and lapilli fallout east and northeast of the volcano until 6 p.m. of the same day. At 10 a.m. on December 17, several nuées ardentes were observed to issue from the central crater, rapidly descending the flanks of the cone and devastating the villages at the foot of Vesuvius. In the night between the 16th and 17th and on the afternoon of the 17th, extensive lahars and floods, resulting from rainstorms, struck the radial valleys of the volcano as well as the plain north and northeast.Deposits of the eruption were identified in about 70 localities on top of an ubiquitous paleosol formed during a long preeruptive volcanic quiescence. The main tephra unit consists of a plinian fallout composed of moderately vesicular dark green lapilli, crystals and lithics. Isopachs of the fallout are elongated eastwards and permit a conservative volume calculation of 0.07 km3. The peak mass flux deduced from clast dispersal models is estimated in the range 3–6 × 107 kg/s, corresponding to a column height of 17–21 km. East of the volcano the plinian fallout is overlain by ash-rich low-grade ignimbrite, surges, phreatomagmatic ashes and mud flows. Ash flows occur in paleovalleys around the cone of Vesuvius but are lacking on the Somma side, suggesting that pyroclastic flows had not enough energy to overpass the caldera wall of Mt. Somma. Deposits are generally unconsolidated, massive with virtually no ground layer and occasionally bearing sparse rests of charred vegetation. Past interpretations of the products emitted on the morning of December 17 as lava flows are inconsistent with both field observations and historical data. Features of the final phreatomagmatic ashes are suggestive of alternating episodes of wet ash fallout and rainfalls. Lahars interfingered with primary ash fallout confirm episodes of massive remobilization of loose tephra by heavy rainfalls during the final stage of the eruption.Chemical analyses of scoria clasts suggest tapping of magma from a compositionally zoned reservoir. Leucite-bearing, tephritic-phonolite (SiO2 51.17%) erupted in the early plinian phase was in fact followed by darker and slightly more mafic magma richer in crystals (SiO2 49.36%). During the nuées ardentes phase the composition returned to that of the early phase of the eruption.The reconstruction of the 1631 eruptive scenario supplies new perspectives on the hazards related to plinian eruptions of Vesuvius. 相似文献
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Adrianna Ianora Raffaella Casotti Mauro Bastianini Christophe Brunet Giuliana D’Ippolito Francesco Acri Angelo Fontana Adele Cutignano Jefferson T. Turner Antonio Miralto 《Marine Ecology》2008,29(3):399-410
Egg production rates and/or hatching success in the copepods Acartia clausi, Calanus helgolandicus and Temora longicornis were negatively affected by a late spring (May–June 2003) phytoplankton bloom in the North Adriatic Sea, dominated mainly by the large diatom Cerataulina pelagica. Highest total concentrations of 3.3·104 cells·ml?1 were located in the vicinity of the Po River, which also corresponded to the area where the highest numbers of phaeophorbides were measured (0.779, 0.528 and 0.419 μg·l?1, respectively, compared to an average of the remaining stations of 0.183 ± 0.049 SD), suggesting some grazing on the bloom. Phytoplankton biomass in terms of carbon was dominated by diatoms, representing on average 42% of total phytoplankton carbon and more than 80% at several stations. Cerataulina pelagica, Cyclotella spp., Chaetoceros spp. and small unidentified centric diatoms dominated the diatom community numerically but C. pelagica was by far the dominant diatom in terms of carbon due to its large cell size. This species represented more than 60% of the diatom biomass at nine of the 14 stations sampled, and was absent only at one station, which was the most offshore station sampled during the cruise. Although polyunsaturated aldehydes (PUAs) were not detected, other oxylipins which are hydroxy and keto derivatives of eicosapentaenoic and docosahexaenoic acids that affect copepod reproduction were found in these samples. Hence, we can attribute the negative impact of diatoms not only to PUAs, as previously believed, but also to these compounds. This is the first direct evidence of the presence of oxylipins other than PUAs in marine blooms dominated by diatoms. 相似文献
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Elisabetta Preziosi Giuseppe Giuliano Raffaella Vivona 《Environmental Earth Sciences》2010,61(5):885-897
Natural background levels (NBL) and threshold values (TV) derivation is an important task for EU Member States to correctly assess the chemical status of groundwater bodies within the context of the recently adopted Groundwater Directive. Attempts are being made both by water authorities and scientific community to test application viability of proposed methods to different real situations and to develop tailored adjustments and refinements. The aim of this paper is to describe a methodological case study of NBL and TV determination in a large area (5,500 km2) located in Central Italy where both natural and anthropogenic contamination occurs, resulting in several substances be detected in ground waters with concentration frequently exceeding drinking water standards. This paper shows the key role played in the determination process by knowledge on the hydrogeological setting and hydrogeochemical features. The adoption of appropriate pre-selection criteria of samples, the establishment of TV at the groundwater body scale for natural origin substances, and the evaluation of TVs exceedances in a multiparameter context are experimentally discussed. Beyond the critical evaluation of NBL and TV determination method, this research aims at increasing consciousness in the water management agencies that groundwater status assessment should be conceived as a scientific evaluation procedure and not as a mere technical/administrative exercise to be performed using any set of available data. As such, it should be supported by adequate knowledge of hydrogeological setting, hydrochemical processes occurring in groundwater bodies, and human activities acting overland to be progressively verified. 相似文献
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Yves Noel Raffaella Demichelis Fabien Pascale Piero Ugliengo Roberto Orlando Roberto Dovesi 《Physics and Chemistry of Minerals》2009,36(1):47-59
The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL
code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc21, P21/c. Cmcm turns out to correspond to a transition state, whereas Cmc21 and P21/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially
the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies
shows a good agreement for the Al-O part of the spectrum (under 790 cm−1). For the Al-OH bending modes (800–1,300 cm−1) an absolute differences of 50–100 cm−1 is observed; for the OH stretching modes (3,200–3,500 cm−1) it increases to 120–200 cm−1: anharmonicity is large because OH groups are involved in strong hydrogen bonds. 相似文献