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1.
Preface     
  相似文献   
2.
In the subduction complex of the Tianshan mountains, western China, massive blueschist is cross-cut by an eclogite-facies major fluid conduit surrounded by a reaction zone which is mainly composed of omphacite and garnet. Petrological as well as geochemical evidence suggest that formation of the vein and the eclogitic selvage around the vein was caused by fluid infiltration under peak metamorphic conditions of 21 ± 1.5 kbar and 510 ± 30 °C. The combination of whole-rock with mineral trace-element data as well as mass-balance calculations indicate that substantial differences exist between the unaltered host rock and the part of the system which was altered by fluid-rock interaction. These differences include: (1) depletion of mainly large-ion lithophile elements (LILE) and Li of up to 60% relative to their concentrations in the unaltered host rock; (2) an extreme enrichment of CaO (∼115%), Sr and Pb (>300%) in the altered parts of the vein-wall-rock system; (3) redistribution of heavy rare earth elements (HREE) from partly replaced rutile and recrystallized titanite in the blueschist-eclogite transition zone into newly grown garnet rims in the eclogitic selvage around the vein; (4) transformation of high Nb/Ta rutile into low Nb/Ta titanite which is associated with preferred mobilization of Nb over Ta; and (5) decoupling of Zr and Hf from Nb and Ta; the latter are depleted by ∼30% relative to the unaltered blueschist host rock whereas the former are depleted by only ∼10%. The prerequisite for the transformation of Ca-poor blueschist (6-7 wt.% CaO) into Ca-rich eclogite (up to 13 wt.% CaO) was the infiltration of a Ca-rich fluid. The release of trace elements can be attributed to partitioning of these elements into the passing fluid phase during dissolution-reprecipitation processes in the course of eclogitization. The reactivity of the precursor mineral assemblage and the chemical gradients between the reacting and passing fluid of the conduit are mainly responsible for trace-element mobilization in the studied samples. The suite of trace elements released upon fluid-induced eclogitization of the reactive wall-rock resembles that in island arc magmas showing strong enrichment of LIL elements, strong depletions in HFS elements and intermediate concentrations of REE.  相似文献   
3.
High-pressure and ultrahigh-pressure (UHP) eclogite-bearing metamorphic assemblages in the North Tianshan of Kyrgyzstan are known from the Aktyuz and Makbal areas, where eclogites and garnet amphibolites are associated with continental rocks such as granitoid gneisses in Aktyuz and shallow-water clastic (passive margin?) metasediments in Makbal. We present the first Lu–Hf isotope data for an eclogite and two garnet amphibolite samples from the two metamorphic terranes which, combined with petrological analysis, tightly constrain the age of high-pressure metamorphism in the Kyrgyz North Tianshan. A five-point isochron for an Aktyuz eclogite sample provides a Lu–Hf age of 474.3 ± 2.2 Ma, and a four-point isochron on a Makbal sample corresponds to 470.1 ± 2.5 Ma. A prograde, subduction-related path is inferred for both samples with peak P–T conditions ranging from 1.4 to 1.6 GPa and 610–620 °C. A further Makbal sample provided a significantly older Lu–Hf age of 486 ± 5.4 Ma, most likely due to late alteration in the sample (late addition of unradiogenic Hf). We conclude that garnet growth in all three samples occurred around ca. 474 Ma and that these rocks likely experienced UHP metamorphism contemporaneously. Our results support previous geochronological evidence for an Early Ordovician collision belt in the North Tianshan and allow refinement of a tectonic model involving subduction of thinned continental crust to considerable depth along the margin of a small microcontinent.  相似文献   
4.
Base-metal sulfides in magmatic Ni-Cu-PGE deposits are important carriers of platinum-group elements (PGE). The distribution and concentrations of PGE in pentlandite, pyrrhotite, chalcopyrite, and pyrite were determined in samples from the mineralized portion of four Merensky Reef intersections from the eastern and western Bushveld Complex. Electron microprobe analysis was used for major elements, and in situ laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) for trace elements (PGE, Ag, and Au). Whole rock trace element analyses were performed on representative samples to obtain mineralogical balances. In Merensky Reef samples from the western Bushveld, both Pt and Pd are mainly concentrated in the upper chromitite stringer and its immediate vicinity. Samples from the eastern Bushveld reveal more complex distribution patterns. In situ LA-ICP-MS analyses of PGE in sulfides reveal that pentlandite carries distinctly elevated PGE contents, whereas pyrrhotite and chalcopyrite only contain very low PGE concentrations. Pentlandite is the principal host of Pd and Rh in the ores. Palladium and Rh concentrations in pentlandite reach up to 700 and 130 ppm, respectively, in the samples from the eastern Bushveld, and up to 1,750 ppm Pd and up to 1,000 ppm Rh in samples from the western Bushveld. Only traces of Pt are present in the base-metal sulfides (BMS). Pyrrhotite contains significant though generally low amounts of Ru, Os, and Ir, but hardly any Pd or Rh. Chalcopyrite contains most of the Ag but carries only extremely low PGE concentrations. Mass balance calculations performed on the Merensky Reef samples reveal that in general, pentlandite in the feldspathic pyroxenite and the pegmatoidal feldspathic pyroxenite hosts up to 100 % of the Pd and Rh and smaller amounts (10–40 %) of the Os, Ir, and Ru. Chalcopyrite and pyrrhotite usually contain less than 10 % of the whole rock PGE. The remaining PGE concentrations, and especially most of the Pt (up to 100 %), are present in the form of discrete platinum-group minerals such as cooperite/braggite, sperrylite, moncheite, and isoferroplatinum. Distribution patterns of whole rock Cu, Ni, and S versus whole rock Pd and Pt show commonly distinct offsets. The general sequence of “offset patterns” of PGE and BMS maxima, in the order from bottom to top, is Pd in pentlandite?→?Pd in whole rock?→?(Cu, Ni, and S). The relationship is not that straightforward in general; some of the reef sequences studied only partially show similar trends or are more complex. In general, however, the highest Pd concentrations in pentlandite appear to be related to the earliest, volumetrically rather small sulfide liquids at the base of the Merensky Reef sequence. A possible explanation for the offset patterns may be Rayleigh fractionation.  相似文献   
5.
A gravity field model is computed from the four accurate gravitational gradient components of GOCE (Gravity field and steady-state Ocean Circulation Explorer), combined with the analysis of the kinematic orbits, and some moderate constraint (or stabilization) in the polar areas where no observation from GOCE is available due to the orbit geometry. The normal matrix of each component is computed individually in order to study its contribution to the combined solution. The results show that the contribution of Vzz is the largest, with an average value of 32.74% of the total solution; the second and the third largest are Vzz and Vyy, with average values of 28.04% and 26.08%, respectively; the component Vxz contributes 11.81%. Validation with external data shows that each component has its characteristic value and that the information content of the component Vxz is not negligible and should be included for gravity field recovery. The orbit part as derived from high-low satellite-to-satellite tracking (SST-hl) to the GPS contributes mostly to the coefficients below degree and order (d/o) 20, and to non-zonal coefficients from d/o 20 to 80. The mean value of the contribution of the polar stabilization is the smallest with a value of 0.22%, nevertheless it is important. In addition to the contribution analysis in terms of the normal matrices, each individual component of the gradiometer has been combined with SST and polar stabilization, to give a set of single component gravity field models. These partially combined solutions are compared to the fully combined solution in terms of geoid differences. They show that the partially combined solution with Vzz is closest to the complete solution. Even closer is a combination with Vxx and Vyy. In addition to the GOCE-only solution, a GOCE-GRACE (Gravity Recovery And Climate Experiment) combined gravity field model is derived and the information content of GOCE and an available set of normal equations of GRACE are investigated. Results show that, as expected, GRACE dominates the solution below degree 90 and GOCE above degree 140.  相似文献   
6.
Traditionally the Chinese South Tianshan has been regarded as a late Paleozoic orogenic belt. However, little is known about the early Paleozoic tectonic architecture of the region. This paper presents the first evidence of Cambrian–Ordovician MORB-type basalts and adakitic diorites on the southern margin of the Yili plate in China. Basalts from Xiate in southwestern Tianshan show a typical transitional (T-) MORB and ferrobasalt composition, which indicate a formation at a propagating spreading ridge. The basalts give a weighted mean 206Pb/238U crystallization age of 516.3 ± 7.4 Ma by SHRIMP U–Pb zircon dating and have experienced contact metamorphism due to the intrusion of a dioritic pluton. The dioritic pluton has a weighted mean 206Pb/238U crystallization age of 470 ± 12 Ma and geochemical characteristics resembling that of adakitic rocks. The pluton is considered to have been formed by partial melting of garnet amphibolites from thickened lower crust in arc or continental collision settings. The basalts and diorites are considered to outline the eastern extension of the early Paleozoic suture zone, the Nikolaev Line, which stretches east–west for hundreds of kilometers between the Northern Tianshan and Central Tianshan terranes of Kyrgyzstan. Our findings substantiate that the Yili and Central Tianshan plates were separated by the early Paleozoic Terskey ocean. The Terskey ocean probably closed during the early stage of the late Ordovician (Lomize et al. in Geotectonics 31(6):463–482, 1997), resulting in the final amalgamation of the Yili and Central Tianshan plates. Consequently, an early Paleozoic suture zone is documented in the Chinese Tianshan region, which is most likely represented by the North Nalati fault.  相似文献   
7.
Despite reduced anthropogenic deposition during the last decades, deposition sulphate may still play an important role in the biogeochemical cycles of S and many catchments may act as net sources of S that may remain for several decades. The aim of this study is to elucidate the temporal and spatial dynamics of both SO42− and δ34SSO4 in stream water from catchments with varying percentage of wetland and forest coverage and to determine their relative importance for catchment losses of S. Stream water samples were collected from 15 subcatchments ranging in size from 3 to 6780 ha, in a boreal stream network, northern Sweden. In forested catchments (<2% wetland cover) S-SO42− concentrations in stream water averaged 1.7 mg L−1 whereas in wetland dominated catchments (>30% wetland cover) the concentrations averaged 0.3 mg L−1. A significant negative relationship was observed between S-SO42− and percentage wetland coverage (r2 = 0.77, p < 0.001) and the annual export of stream water SO42− and wetland coverage (r2 = 0.76, p < 0.001). The percentage forest coverage was on the other hand positively related to stream water SO42− concentrations and the annual export of stream water SO42− (r2 = 0.77 and r2 = 0.79, respectively). The annual average δ34SSO4 value in wetland dominated streams was +7.6‰ and in streams of forested catchments +6.7‰. At spring flood the δ34SSO4 values decreased in all streams by 1‰ to 5‰. The δ34SSO4 values in all streams were higher than the δ34SSO4 value of +4.7‰ in precipitation (snow). The export of S ranged from 0.5 kg S ha−1 yr−1 (wetland headwater stream) to 3.8 kg S ha−1 yr−1 (forested headwater stream). With an average S deposition in open field of 1.3 kg S ha−1 yr−1 (2002-2006) the mass balance results in a net export of S from all catchments, except in catchments with >30% wetland. The high temporal and spatial resolution of this study demonstrates that the reducing environments of wetlands play a key role for the biogeochemistry of S in boreal landscapes and are net sinks of S. Forested areas, on the other hand were net sources of S.  相似文献   
8.
9.
Science Requirements on Future Missions and Simulated Mission Scenarios   总被引:4,自引:0,他引:4  
The science requirements on future gravity satellite missions, following from the previous contributions of this issue, are summarized and visualized in terms of spatial scales, temporal behaviour and accuracy. This summary serves the identification of four classes of future satellite mission of potential interest: high-altitude monitoring, satellite-to-satellite tracking, gradiometry, and formation flights. Within each class several variants are defined. The gravity recovery performance of each of these ideal missions is simulated. Despite some simplifying assumptions, these error simulations result in guidelines as to which type of mission fulfils which requirements best.  相似文献   
10.
苏文  高俊  Reiner  KLEMD  熊贤明 《岩石学报》2006,22(5):1380-1386
运用电子探针和显微Fourier变换红外光谱技术,对新疆西天山3个榴辉岩样品中的石榴石进行了详细的主量元素和结构水分析。结果显示,石榴石发育以核部富锰铝榴石组分、边部富镁铝榴石组分进变质作用的成分环带。石榴石中OH^-1分布也具有规律:核部→边缘。其结构水OH^-1逐步增加,即从核部的89-239ppm增加到边部的367-658ppm;与石榴石边部相比,石榴石的核部含有较低的OH^-1,却含有较高的H2O和Mn含量。这表明,在蓝片岩向榴辉岩进变质作用过程中,含水矿物脱水反应而释放出大量的分子水,这部分水促进了高压变质反应,形成榴辉岩相矿物,石榴石核部的结晶就是在富水和Mn的条件下进行的。随着高压变质作用的继续,石榴石核部的分子水逐步失水而进入石榴石晶格,形成结构水。因此,在高压变质作用过程中,OH^-1演化实际上是一个由内部不平衡逐步向平衡转变过程。P588.348  相似文献   
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