Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution   总被引：1，自引：1，他引：0  

Masahiko Bessho  Takaaki Wajima  Takuro Ida  Takashi Nishiyama 《Environmental Earth Sciences》2011,64(2):311-318

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.  相似文献   

Archeological evidence of Pacific salmon distribution in northern Japan and implications for future global warming     

Yukimasa Ishida  Tsutomu Hariu  Junichi Yamashiro  Skip McKinnell  Takeshi Matsuda  Hiromasa Kaneko 《Progress in Oceanography》2001,49(1-4)

Archeological evidence of Pacific salmon in Hokkaido is reviewed and compared with results from western North America. Salmon remains have been found at 24 sites in Hokkaido from the Early Jomon Period to the Ainu Period (6000–100 years ago). Fish remains at three archeological sites in the Kushiro River basin indicated that Pacific salmon (Oncorhynchus spp.) were distributed and utilized from 6000 years ago. The present Kushiro Wetland was formerly covered with seawater and called the Paleo Kushiro Bay 5000–6000 years ago. Based on the molluscan fossil fauna, seawater temperature at Paleo Kushiro Bay was about 5°C warmer than at present. Warmer conditions for salmon in Kushiro 5000–6000 years ago corresponded with the poor conditions for salmon in the Columbia River basin 6000–7000 years ago. If the future global warming is similar to the conditions that prevailed 5000–6000 years ago, the southern limit of salmon distribution will shift northwards and the salmon production will decrease. However, they will not disappear from either Hokkaido or southwestern North America.  相似文献   

Thermal alteration of hydrated minerals during hypervelocity capture to silica aerogel at the flyby speed of Stardust     

Takaaki Noguchi  Tomoki Nakamura  Kyoko Okudaira  Hajime Yano  Seiji Sugita  Mark J. Burchell 《Meteoritics & planetary science》2007,42(3):357-372

Abstract— Outside the Earth's atmosphere, silica aerogel is one of the best materials to capture finegrained extraterrestrial particles in impacts at hypervelocities. Because silica aerogel is a superior insulator, captured grains are inevitably influenced by frictional heat. Therefore, we performed laboratory simulations of hypervelocity capture by using light‐gas guns to impact into aerogels finegrained powders of serpentine, cronstedtite, and Murchison CM2 meteorite. The samples were shot at >6 km s^?1 similar to the flyby speed at comet P/Wild‐2 in the Stardust mission. We investigated mineralogical changes of each captured particle by using synchrotron radiation X‐ray diffraction (SR‐XRD), transmission electron microscope (TEM), and field emission scanning electron microscope (FE‐SEM). SR‐XRD of each grain showed that the majority of the bulk grains keep their original mineralogy. In particular, SR‐XRD and TEM investigations clearly exemplified the presence of tochilinite whose decomposition temperature is about 300 °C in the interior of the captured Murchison powder. However, TEM study of these grains also revealed that all the samples experienced melting and vesiculation on the surface. The cronstedtite and the Murchison meteorite powder show remarkable fracturing, disaggregation, melting, and vesiculation. Steep thermal gradients, about 2500 °C/μm were estimated near the surface of the grains (<2 μm thick) by TEM observation. Our data suggests that the interior of >4 μm across residual grains containing abundant materials that inhibit temperature rise would have not experienced >300 °C at the center.  相似文献   

Primordial noble gases in a graphite‐metal inclusion from the Canyon Diablo IAB iron meteorite and their implications     

Jun‐ichi Matsuda  Miwa Namba  Teruyuki Maruoka  Takuya Matsumoto  Gero Kurat 《Meteoritics & planetary science》2005,40(3):431-443

Abstract— We have carried out noble gas measurements on graphite from a large graphite‐metal inclusion in Canyon Diablo. The Ne data of the low‐temperature fractions lie on the mixing line between air and the spallogenic component, but those of high temperatures seem to lie on the mixing line between Ne‐HL and the spallogenic component. The Ar isotope data indicate the presence of Q in addition to air, spallogenic component and Ar‐HL. As the elemental concentration of Ne in Q is low, we could not detect the Ne‐Q from the Ne data. On the other hand, we could not observe Xe‐HL in our Xe data. As the Xe concentration and the Xe/Ne ratio in Q is much higher than that in the HL component, it is likely that only the contribution of Q is observed in the Xe data. Xenon isotopic data can be explained as a mixture of Q, air, and “El Taco Xe.” The Canyon Diablo graphite contains both HL and Q, very much like carbonaceous chondrites, retaining the signatures of various primordial noble gas components. This indicates that the graphite was formed in a primitive nebular environment and was not heated to high, igneous temperatures. Furthermore, a large excess of ¹²⁹Xe was observed, which indicates that the graphite was formed at a very early stage of the solar system when ¹²⁹I was still present. The HL/Q ratios in the graphite in Canyon Diablo are lower than those in carbonaceous chondrites, indicating that some thermal metamorphism occurred on the former. We estimated the temperature of the thermal metamorphism to about 500–600 °C from the difference of thermal retentivities of HL and Q. It is also noted that “El Taco Xe” is commonly observed in many IAB iron meteorites, but its presence in carbonaceous chondrites has not yet been established.  相似文献   

Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components     

Takahito OSAWA  Hiroyuki KAGI  Tomoki NAKAMURA  Takaaki NOGUCHI 《Meteoritics & planetary science》2005,40(1):71-86

Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm^?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm^?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm^?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm^?1 compared to 3400 cm^?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm^?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm^?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm^?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.  相似文献   

Carbon isotope fractionation between graphite and diamond during shock experiments     

Teruyuki Maruoka  Christian Koeberl  Jun‐ichi Matsuda  Yasuhiko Syono 《Meteoritics & planetary science》2003,38(8):1255-1262

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.  相似文献   

Sensitivity Analysis of a Feedforward Neural Network for Considering Genetic Mechanisms of Kuroko Deposits     

Matsuda  Setsuro  Koike  Katsuaki 《Natural Resources Research》2003,12(4):291-301

Exploration for volcanogenic massive sulfide deposits of the kuroko-type is underway in many places. Clarifying the spatial patterns of the metals in kuroko deposits will be useful for understanding their genetic mechanisms and for future exploration of such types of deposits. This study represents a spatial distribution analysis on the contents of principal metals of kuroko deposits: Cu, Pb, and Zn, in the Hokuroku district, northern Japan, by a feedforward neural network and 1917 sample data at 143 drillhole sites. The network, which consists of three layers, was trained by the principle of SLANS in which the numbers of neurons in the middle layer and training data are changed to improve estimation accuracy. Using the weight coefficients connecting adjacent neurons, sensitivity analysis of the neural network was carried out to identify factors influencing spatial distributions of the three metals. The coordinates depth (z) direction, Bouguer gravity, and specific lithology such as dacite were determined to be influencing factors. The high frequency of the z coordinate signifies that the metal contents differ to a large extent by depth. The sensitivity vector was defined using sensitivity coefficients for x, y, and z coordinates of an estimation point. We determined that the directions of large vectors were different inside and outside of the Hanawa-Ohdate area. This characteristic is considered to originate from the differences in the permeability of fractures that became the paths for rising ore solutions, and the depths that the solutions mixed with sea water.  相似文献   

A model for superoutbursts in SU UMa-type binaries     

D. V. Bisikalo  A. A. Boyarchuk  P. V. Kaigorodov  O. A. Kuznetsov  T. Matsuda 《Astronomy Reports》2004,48(7):588-596

We suggest a new mechanism for the superoutbursts in SU UMa binaries, in which the increase in the accretion rate resulting in a superoutburst is associated with the formation of a spiral “precessional” wave in the inner parts of the disk, where gas-dynamical perturbations are negligible. The existence of such waves was suggested by us previously. The results of three-dimensional gas-dynamical simulations have shown that a considerable increase in the accretion rate (by up to an order of magnitude) is associated with the formation of the precessional wave. The features of the precessional spiral wave can explain both the energy release in the superoutburst and all its observational manifestations. One distinguishing feature of superoutbursts in SU UMa-type stars is the formation of a “superhump” in the light curve. Our model reproduces well both the formation of a superhump and its observational features, including its period, which is up to 3–7% longer than the orbital period, and the detectability of the superhump independent of the orbital inclination of the binary.  相似文献   

Observation of Pore Spaces and Microcracks Using a Fluorescent Technique in Some Reservoir Rocks of Oil, Gas and Geothermal Fields in the Green Tuff Region, Japan     

Takaaki WAJIMA  Shuji OKUDA  Youqing CHEN  Masahiko BESSHO  Takashi NISHIYAMA 《Resource Geology》2000,50(3):191-200

Abstract: Pore spaces and microcracks in representative oil, gas and geothermal reservoir rocks from the Green Tuff region, Japan, were examined using a fluorescent technique. This technique was developed to visualize microscopically pore spaces and microcracks filled with synthetic resin mixed with fluorescent paint under ultraviolet light. Various morphology of pore spaces and microcracks was clearly identified. Spaces in studied reservoir rocks are classified into following three types: pore spaces in matrix, pore spaces in particles, and microcracks. It is observed that valuable oil and gas reservoir rocks relatively include many pore spaces, while microcracks are important for geothermal rocks. Correlation between textural characteristics and porosity or permeability was found in the oil reservoir rocks. Effective permeability depends upon pore spaces in matrix more than upon other components such as pore spaces in particles and microcracks. Looseness in matrix caused by larger grain size of particles is strongly correlated with permeability. Pore spaces play an important role as a reservoir in oil and gas fields, but are less important in geothermal field. Instead, microcracks are important for geothermal reservoir system.  相似文献   

Surface Soil Effects Study Using Short-period Microtremor Observations in Almería City, Southern Spain     

M. Navarro  T. Enomoto  F. J. Sánchez  I. Matsuda  T. Iwatate  A. M. Posadas  F. Luzón  F. Vidal  K. Seo 《Pure and Applied Geophysics》2001,158(12):2481-2497

—?In Almería city large earthquakes occurred and many buildings were completely destroyed in these historical earthquakes. The actual population of Almería city is about 200,000 people. This population is rapidly increasing and new urbanizing areas are growing to the eastern part of the city where they are located in softer soil conditions. Consequently, the evaluation of surface soil conditions is very important from a standpoint of earthquake disaster mitigation. We have obtained a landform classification map developed by analysing aerial photos, large-scale topographic maps and 80 borehole data. Eleven unit areas, which have different soil conditions, were inferred from this research. Also, S-wave velocity prospecting tests were carried out at several sites within the city. The shear-velocity values of the ground vary from 1689?m/s in hard rock to 298?m/s in soft soil. These results are useful for understanding the uppermost soil characteristics and are used for soil classification. Finally, short-period microtremor observations were densely carried out in the research area and NAKAMURA's method (1989) was applied for determining predominant periods. Microtremors were observed at about 173 sites with mainly 400?m interval in rock sites and 200?m interval in relatively soft soil sites. From the result of these microtremor measurements, the predominant period determined at rock site, in the western part of the city and historic area, is very short, about 0.1?s, and very stable. However at soft soil sites, in the center of the city, near Zapillo Beach and in the newly developed urban area, the predominant period is about 1.0?s and even larger in concordance with the geological conditions. Finally, at medium soil sites, in the eastern part of the city, the predominant period is about 0.4?s and it appears very stable in the whole region. The difference of predominant periods between hard rock and soft soil sites is very clear and it has been observed that the distribution of predominant periods depends heavily on the surface soil conditions.  相似文献