Si and O self-diffusion in hydrous forsterite and iron-bearing olivine from the perspective of defect chemistry     

Hongzhan Fei  Tomoo Katsura 《Physics and Chemistry of Minerals》2016,43(2):119-126

We discuss the experimental results of silicon and oxygen self-diffusion coefficients in forsterite and iron-bearing olivine from the perspective of defect chemistry. Silicon diffusion is dominated by V_O ^··-associated V_Si″″, whereas oxygen diffusion is dominated by hopping of V_O ^·· under anhydrous conditions, and by (OH)_O ^· under hydrous conditions. By considering the charge neutrality condition of [(OH)_O ^·] = 2[V_Me″] in hydrous forsterite and iron-bearing olivine, we get D _Si ∝ (\(C_{{{\text{H}}_{2} {\text{O}}}}\))^1/3 and D _O ∝ (\(C_{{{\text{H}}_{2} {\text{O}}}}\))⁰, which explains the experimental results of water effects on oxygen and silicon self-diffusion rates (Fei et al. in Nature 498:213–215, 2013; J Geophys Res 119:7598–7606, 2014). The \(C_{{{\text{H}}_{2} {\text{O}}}}\) dependence of creep rate in the Earth’s mantle should be close to that given by Si and O self-diffusion coefficients obtained under water unsaturated conditions.  相似文献   

The difference in chemical composition of the 1962 lava from miyakezima magma reservoir in Japan     

I. Iwasaki  T. Ozawa  M. Yoshida  T. Katsura  Chan Kuk Kim  M. Aoyagi  Y. Yoshiike 《Bulletin of Volcanology》1982,45(2):81-85

Many examples of mixed magmas in banded lavas have been studied. Another type of mixed magmas or inhomogeneity of magma reservoir found in the 1962 lava flows of Miyake-zima Volcano erupted from fissures is reported.  相似文献   

Water saturated phase relations of some andesites with application to the estimation of the initial temperature and water pressure at the time of eruption     

Toshimori Sekine  Takashi Katsura  Shigeo Aramaki 《Geochimica et cosmochimica acta》1979,43(8):1367-1376

Near-liquidus phase relations in one-atmosphere dry and water-saturated high pressure conditions were experimentally determined on products of three historic andesitic eruptions. Run conditions ranged from 900 to 1100°C, at pressures up to 1500 bars with fO₂ controlled close to the nickel-nickel oxide (NNO) buffer. In order to represent the compositions of the true liquid parts of the erupting magmas, groundmass portions were mechanically separated from the porphyritic andesites. Such groundmass materials should lie exactly on the liquidus field boundary between the phases precipitating from the magma just prior to eruption under the prevailing P-T condition.All the samples showed a crossing of the plagioclase and orthopyroxene liquidi in the pressure-temperature range from 1 to 800 bar and 950–1090°C. The crossing condition approximates the magmatic condition immediately prior to eruption. In the case of the 1970 eruption of Akita-komagatake, the crossing point is at 150 bar and 1090°C, matching closely the observed explosive gas pressure and the temperature. In both cases of the 1783 eruption of Asama and the 1914–1915 eruption of Sakurajima volcanoes, the crossing point shift from higher water pressure and lower temperature for the earlier erupting magmas to lower pressure and higher temperature for the later magmas. This regularity may be explained by a vertical gradient of the temperature and water content within the magma column prior to eruption.  相似文献   

Radioactivity of volcanic gases in Japan     

I. Iwasaki  T. Katsura  H. Shimojima  M. Kamada 《Bulletin of Volcanology》1956,18(1):103-123

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Pressure-temperature cartography of Fe-S-Si immiscible system     

G. Morard  T. Katsura 《Geochimica et cosmochimica acta》2010,74(12):3659-3667

Multi-anvil press experiments were performed using a single cell assembly containing six different compositions. This set-up allows a careful sampling of the miscibility gap for given P-T conditions. Shrinking of the miscibility gap in the Fe-S-Si system has been studied from 4 to 12 GPa up to 2200 K, demonstrating a stable immiscible zone up to 4 GPa and 2200 K and its closure at higher pressures. Presence of both S and Si in the Earth’s core is suggested by chondritic models. Therefore, its composition is inherited from processes at pressures higher than 4 GPa. This evolution of the Fe-S-Si miscibility gap is linked with the change in the local short-range order in Fe and Fe-S liquids. Our results indicate that core formation under reducing conditions would be affected by immiscibility for planetesimals up to size of the Moon. Furthermore, due to the difference in wetting properties between the two immiscible liquid phases, the S-rich metal phase would control the chemical exchange between liquid metals and silicates during early differentiation in planetesimals.  相似文献   

Hydraulic properties of and pressure-head dynamics in thick pyroclastic-fall deposits in Atsuma,Northern Japan: implications for the role of water in shallow landslides induced by the 2018 Hokkaido Eastern Iburi Earthquake     

Aoki  Toshiya  Katsura  Shin&#;ya  Koi  Takashi  Tanaka  Yasutaka  Yamada  Takashi 《Landslides》2022,19(8):1813-1824

Landslides - The 2018 Hokkaido Eastern Iburi Earthquake triggered numerous shallow landslides on slopes covered with thick pyroclastic-fall deposits. The landslides occurred more frequently on...  相似文献   

Perturbed physics ensemble using the MIROC5 coupled atmosphere–ocean GCM without flux corrections: experimental design and results     

Hideo Shiogama  Masahiro Watanabe  Masakazu Yoshimori  Tokuta Yokohata  Tomoo Ogura  James D. Annan  Julia C. Hargreaves  Manabu Abe  Youichi Kamae  Ryouta O’ishi  Rei Nobui  Seita Emori  Toru Nozawa  Ayako Abe-Ouchi  Masahide Kimoto 《Climate Dynamics》2012,39(12):3041-3056

In this study, we constructed a perturbed physics ensemble (PPE) for the MIROC5 coupled atmosphere–ocean general circulation model (CGCM) to investigate the parametric uncertainty of climate sensitivity (CS). Previous studies of PPEs have mainly used the atmosphere-slab ocean models. A few PPE studies using a CGCM applied flux corrections, because perturbations in parameters can lead to large radiation imbalances at the top of the atmosphere and climate drifts. We developed a method to prevent climate drifts in PPE experiments using the MIROC5 CGCM without flux corrections. We simultaneously swept 10 parameters in atmosphere and surface schemes. The range of CS (estimated from our 35 ensemble members) was not wide (2.2–3.2?°C). The shortwave cloud feedback related to changes in middle-level cloud albedo dominated the variations in the total feedback. We found three performance metrics for the present climate simulations of middle-level cloud albedo, precipitation, and ENSO amplitude that systematically relate to the variations in shortwave cloud feedback in this PPE.  相似文献   

Long-term change and variation of salinity in the western North Pacific subtropical gyre revealed by 50-year long observations along 137°E     

Eitarou Oka  Shota Katsura  Hiroyuki Inoue  Atsushi Kojima  Moeko Kitamoto  Toshiya Nakano  Toshio Suga 《Journal of Oceanography》2017,73(4):479-490

The 137°E repeat hydrographic section for 50 winters during 1967–2016 has been analyzed to examine interannual to interdecadal variations and long-term changes of salinity and temperature in the surface and intermediate layers of the western North Pacific, with a particular focus on freshening in the subtropical gyre. Rapid freshening on both isobars and isopycnals began in the mid-1990s and persisted for the last 20 years in the upper main thermocline/halocline in the western subtropical gyre. In addition, significant decadal variability of salinity existed in the subtropical mode water (STMW), as previously reported for the shallower layers. An analysis of the 144°E repeat hydrographic section during 1984–2013 supplemented by Argo profiling float data in 2014 and 2015 revealed that the freshening trend and decadal variability observed at 137°E originated in the winter mixed layer in the Kuroshio Extension (KE) region and was transmitted southwestward to 137°E 1–2 years later in association with the subduction and advection of STMW. The mechanism of these changes and variations in the source region was further investigated. In addition to the surface freshwater flux in the KE region pointed out by previous studies, the decadal KE variability in association with the Pacific Decadal Oscillation likely contributes to the decadal salinity variability through water exchange between the subtropics and the subarctic across the KE. Interdecadal change in both the surface freshwater flux and the KE state, however, failed to explain the rapid freshening for the last 20 years.  相似文献   

库木库里背斜活动性初步研究          下载免费PDF全文

孙浩越  何宏林  付碧宏  杨顺虎  白濱吉起  池田安隆  狩野谦一  越後智雄 《地震地质》2014,36(1):1-13

库木库里盆地位于青藏高原北缘,与柴达木盆地一山之隔,是二者的过渡地带,也是高原主体部分向NE扩展的前缘地区;现今构造表现为被3条大型活动构造带(走滑的阿尔金断裂带、东昆仑断裂带和逆冲的祁漫塔格褶皱逆冲系)所夹持。因此,该盆地对于研究青藏高原北缘的构造活动性、活动历史,探讨高原的扩展模式具有十分重要的意义。虽然库木库里盆地南、北两侧均发育活动性很强的大型走滑断裂,但是在盆地中央发育1条大型背斜,走向NWW-SEE,与祁漫塔格褶皱逆冲系和柴达木盆地内的褶皱构造走向一致,说明盆地目前遭受NNE向的挤压。通过对盆地地形横、纵剖面和阶地展布形态的分析,得出背斜有自西向东扩展变形的特征;野外调查和测年结果显示,背斜东段冰川融水形成了大型冰水扇,形成年龄为(87.09±2.31)~(102.4±3.7)ka,进而获得背斜东段自晚更新世以来平均隆升速率的最大值为(2.78±0.28)~(3.28±0.28)mm/a。库木库里盆地整体的活动性很强,在构造上与其北边的柴达木盆地类似,都受控于阿尔金断裂南侧的NNE向的区域挤压作用。  相似文献   

1600 K和20 GP温压条件下的顽火辉石电导率   总被引：2，自引：1，他引：1       下载免费PDF全文

张宝华  吴小平  许俊闪  Tomoo Katsura  Takashi Yoshino 《地球物理学报》2010,53(3):760-764

在温度750～1600 K和压力10～20 GPa条件下,借助于Kawai-5000多面顶砧高温高压设备,就位测量了(Mg_0.9Fe_0.1) SiO₃ 顽火辉石的电导率.实验结果显示,顽火辉石的电导率在高温区以小极化子机制为主,在低温区以质子导电为主,因为实验后的样品中有一定的水含量.另外,X射线衍射实验表明压力（20 GPa）诱发了顽火辉石向林伍德石的相变,这是我们首次在顽火辉石的电导率实验中观测到林伍德石含水相变,而且含水林伍德石的电导率与已有的实验结果相当一致.  相似文献