The Dual-Domain Porosity Apparatus: Characterizing Dual Porosity at the Sediment/Water Interface     

Courtney R. Scruggs  Martin Briggs  Frederick D. Day-Lewis  Dale Werkema  John W. Lane Jr 《Ground water》2019,57(4):640-646

The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.  相似文献   

A Postcard from the COVID-19 Crisis Response: Lessons and Opportunities for Remediation     

John Horst  Nicklaus Welty  Aaron Svitana  Terry Young  Moniqua Williams  James Strunk Jr. 《Ground Water Monitoring & Remediation》2020,40(4):19-26

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Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

MoisturEC: A New R Program for Moisture Content Estimation from Electrical Conductivity Data   总被引：1，自引：0，他引：1       下载免费PDF全文

Neil Terry  Frederick D. Day‐Lewis  Dale Werkema  John W. Lane Jr 《Ground water》2018,56(5):823-831

Noninvasive geophysical estimation of soil moisture has potential to improve understanding of flow in the unsaturated zone for problems involving agricultural management, aquifer recharge, and optimization of landfill design and operations. In principle, several geophysical techniques (e.g., electrical resistivity, electromagnetic induction, and nuclear magnetic resonance) offer insight into soil moisture, but data‐analysis tools are needed to “translate” geophysical results into estimates of soil moisture, consistent with (1) the uncertainty of this translation and (2) direct measurements of moisture. Although geostatistical frameworks exist for this purpose, straightforward and user‐friendly tools are required to fully capitalize on the potential of geophysical information for soil‐moisture estimation. Here, we present MoisturEC, a simple R program with a graphical user interface to convert measurements or images of electrical conductivity (EC) to soil moisture. Input includes EC values, point moisture estimates, and definition of either Archie parameters (based on experimental or literature values) or empirical data of moisture vs. EC. The program produces two‐ and three‐dimensional images of moisture based on available EC and direct measurements of moisture, interpolating between measurement locations using a Tikhonov regularization approach.  相似文献   

P–T–t estimation of deformation in low‐grade quartz‐feldspar‐bearing rocks using thermodynamic modelling and 40Ar/39Ar dating techniques: example of the Plan‐de‐Phasy shear zone unit (Briançonnais Zone,Western Alps)     

Pierre Lanari  Yann Rolland  Stéphane Schwartz  Olivier Vidal  Stéphane Guillot  Pierre Tricart  Thierry Dumont 《地学学报》2014,26(2):130-138

Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and ⁴⁰Ar/³⁹Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision.  相似文献   

Integrating hydropower and intermittent climate‐related renewable energies: a call for hydrology          下载免费PDF全文

B. François  M. Borga  S. Anquetin  J. D. Creutin  K. Engeland  A. C. Favre  B. Hingray  M. H. Ramos  D. Raynaud  B. Renard  E. Sauquet  J. F. Sauterleute  J. P. Vidal  G. Warland 《水文研究》2014,28(21):5465-5468

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Threshold of motion of bivalve and gastropod shells under oscillatory flow in flume experiments     

Cristiano Fick  Eduardo Puhl  Elírio Ernestino Toldo Jr 《Sedimentology》2020,67(1):627-648

The threshold of motion of non-fragmented mollusc shells was studied for the first time under oscillatory flow. In this regard, flume experiments were used to investigate the threshold of motion of three bivalve and three gastropod species, two typical mollusc classes of coastal coquina deposits. The sieve diameters ranged from 2·0 to 15·9 mm. These experiments were performed on a flat-bottom setup under regular non-breaking waves (swell) produced by a flap-type wave generator. The critical Shields values for each species of mollusc were plotted against the sieve and nominal diameter. Moreover, the dimensionless Corey shape factor of the shells was evaluated in order to investigate the effect of mollusc shell shapes on the threshold of motion. According to their critical Shields parameter, the mollusc threshold data under oscillatory flow present smaller values than the siliciclastic sediments when considering their sieve diameter. In addition, the mollusc datasets are below the empirical curves built from siliciclastic grain data under current and waves. When considering the nominal diameter, the critical Shields parameter increases and the mollusc data are closer to siliciclastic sediments. Bivalves, which have a flat-concave shape (form factor: 0·27 to 0·37), have a higher critical Shields parameter for smaller particles and more uniform datasets than the gastropod scattered data, which have a rounded shape (form factor: 0·58 to 0·62) and have varied morphologies (ellipsoidal, conical and cubic). The comparison between previous current-driven threshold data of bioclastic sediment motion and the data of mollusc whole shells under oscillatory flow shows a fair correlation on the Shields diagram, in which all datasets are below the mean empirical curves for siliciclastic sediments. These findings indicate that the shape effect on the transport initiation is predominant for smaller shells. The use of the nominal diameter is satisfactory to improve the bioclastic and siliciclastic data correlation.  相似文献   

Long-Term Evaluation of Mulch Biowall Performance to Treat Chlorinated Solvents     

Kenneth L. Walker Jr.  Travis M. McGuire  David T. Adamson  R. Hunter Anderson 《Ground Water Monitoring & Remediation》2020,40(1):35-46

Permeable reactive barriers (PRBs), such as mulch biowalls, have been installed at numerous groundwater cleanup sites, and laboratory and field studies have demonstrated biotic and abiotic processes that degrade chlorinated volatile organic compounds (CVOCs) in groundwater passing through these engineered remedies. However, the longevity of mulch biowalls remains a fundamental research question. Soil and groundwater sampling at seven mulch biowalls at Altus Air Force Base (AFB) approximately 10 years after installation demonstrated the ongoing degradation of CVOCs. Trichloroethene was not detected in five of seven groundwater samples collected from the biowall despite upgradient detections above federal drinking water standards. Microbial sampling established the presence of key dechlorinating bacteria and the abundance of genes encoding specific enzymes for degradation, high methane concentrations, low sulfate concentrations, and negative oxidation-reduction potential, all indicative of highly reducing conditions within the biowalls and favorable conditions for CVOC destruction via microbial reductive dechlorination. High cellulose content (>79%) of the mulch, elevated total organic carbon (TOC) content in groundwater, and elevated potentially bioavailable organic carbon (PBOC) measurements in soil samples further supports an ongoing, long-lived source of carbon. These results demonstrate the ongoing and long-term efficacy of the mulch biowalls at Altus AFB. In addition, concentrations of bacteria, TOC, PBOC, and other geochemical parameters suggest a modest impact of the biowalls downgradient. The continued presence of CVOCs downgradient may be attributable to back diffusion from low-permeability shale. However, the biowalls continue to provide benefits by removing CVOCs in groundwater, thus reducing further CVOC loading to the downgradient, low-permeability strata.  相似文献   

Environmental changes over the past 25 000 years in the southern Middle Atlas,Morocco          下载免费PDF全文

Jalal Tabel  Carla Khater  Ali Rhoujjati  Laurent Dezileau  Ilham Bouimetarhan  Matthieu Carre  Laurence Vidal  Abdelfattah Benkaddour  Majda Nourelbait  Rachid Cheddadi 《第四纪科学杂志》2016,31(2):93-102

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Contrasting isotopic signatures between anthropogenic and geogenic Zn and evidence for post-depositional fractionation processes in smelter-impacted soils from Northern France   总被引：2，自引：0，他引：2  

Farid Juillot  Delphine Jouvin  Philipe Telouk  Philippe Ildefonse  Steve Sutton  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308

Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ⁶⁶Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ⁶⁶Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ⁶⁶Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe₂O₄)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ⁶⁶Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ⁶⁶Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ⁶⁶Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments.  相似文献