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1.
Noninvasive geophysical estimation of soil moisture has potential to improve understanding of flow in the unsaturated zone for problems involving agricultural management, aquifer recharge, and optimization of landfill design and operations. In principle, several geophysical techniques (e.g., electrical resistivity, electromagnetic induction, and nuclear magnetic resonance) offer insight into soil moisture, but data‐analysis tools are needed to “translate” geophysical results into estimates of soil moisture, consistent with (1) the uncertainty of this translation and (2) direct measurements of moisture. Although geostatistical frameworks exist for this purpose, straightforward and user‐friendly tools are required to fully capitalize on the potential of geophysical information for soil‐moisture estimation. Here, we present MoisturEC, a simple R program with a graphical user interface to convert measurements or images of electrical conductivity (EC) to soil moisture. Input includes EC values, point moisture estimates, and definition of either Archie parameters (based on experimental or literature values) or empirical data of moisture vs. EC. The program produces two‐ and three‐dimensional images of moisture based on available EC and direct measurements of moisture, interpolating between measurement locations using a Tikhonov regularization approach.  相似文献   
2.
The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.  相似文献   
3.
We present a multi‐chronometric approach for reconstructing deep‐time thermal histories using southern Baffin Island as a case study. This continuous thermal history begins with the Palaeoproterozoic Trans‐Hudson Orogeny and is derived from inverse and forward models that integrate thermochronometers spanning some 500°C: new apatite U–Pb ages and K‐feldspar 40Ar/39Ar multi‐diffusion domain data, published (U–Th)/He zircon ages and new multi‐kinetic fission‐track results. Integration of data from a wider temperature range reduces ambiguities in thermal‐history modelling and permits us to constrain the timing of geological processes including, extended post‐orogenic cooling, enhanced later Proterozoic cooling, and then episodic burial and exhumation in the Palaeozoic–Mesozoic.  相似文献   
4.
Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
5.
Small tidal forces in the Earth–Moon system cause detectable changes in the orbit. Tidal energy dissipation causes secular rates in the lunar mean motion n, semimajor axis a, and eccentricity e. Terrestrial dissipation causes most of the tidal change in n and a, but lunar dissipation decreases eccentricity rate. Terrestrial tidal dissipation also slows the rotation of the Earth and increases obliquity. A tidal acceleration model is used for integration of the lunar orbit. Analysis of lunar laser ranging (LLR) data provides two or three terrestrial and two lunar dissipation parameters. Additional parameters come from geophysical knowledge of terrestrial tides. When those parameters are converted to secular rates for orbit elements, one obtains dn/dt = \(-25.97\pm 0.05 ''/\)cent\(^{2}\), da/dt = 38.30 ± 0.08 mm/year, and di/dt = ?0.5 ± 0.1 \(\upmu \)as/year. Solving for two terrestrial time delays and an extra de/dt from unspecified causes gives \(\sim \) \(3\times 10^{-12}\)/year for the latter; solving for three LLR tidal time delays without the extra de/dt gives a larger phase lag of the N2 tide so that total de/dt = \((1.50 \pm 0.10)\times 10^{-11}\)/year. For total dn/dt, there is \(\le \)1 % difference between geophysical models of average tidal dissipation in oceans and solid Earth and LLR results, and most of that difference comes from diurnal tides. The geophysical model predicts that tidal deceleration of Earth rotation is \(-1316 ''\)/cent\(^{2}\) or 87.5 s/cent\(^{2}\) for UT1-AT, a 2.395 ms/cent increase in the length of day, and an obliquity rate of 9 \(\upmu \)as/year. For evolution during past times of slow recession, the eccentricity rate can be negative.  相似文献   
6.
Vegetation changes associated with climate shifts and anthropogenic disturbance can have major impacts on biogeochemical cycling and soils. Much of the Great Basin, U.S. is currently dominated by sagebrush (Artemisia tridentate (Rydb.) Boivin) ecosystems. Sagebrush ecosystems are increasingly influenced by pinyon (Pinus monophylla Torr. & Frém and Pinus edulis Engelm.) and juniper (Juniperus osteosperma Torr. and Juniperus occidentalis Hook.) expansion. Some scientists and policy makers believe that increasing woodland cover in the intermountain western U.S. offers the possibility of increased organic carbon (OC) storage on the landscape; however, little is currently known about the distribution of OC on these landscapes, or the role that nitrogen (N) plays in OC retention. We quantified the relationship between tree cover, belowground OC, and total below ground N in expansion woodlands at 13 sites in Utah, Oregon, Idaho, California, and Nevada, USA. One hundred and twenty nine soil cores were taken using a mechanically driven diamond tipped core drill to a depth of 90 cm. Soil, coarse fragments, and coarse roots were analyzed for OC and total N. Woodland expansion influenced the vertical distribution of root OC by increasing 15-30 cm root OC by 2.6 Mg ha−1 and root N by 0.04 Mg ha−1. Root OC and N increased through the entire profile by 3.8 and 0.06 Mg ha−1 respectively. Woodland expansion influenced the vertical distribution of soil OC by increasing surface soil (0-15 cm) OC by 2.2 Mg ha−1. Woodland expansion also caused a 1.3 Mg ha−1 decrease in coarse fragment associated OC from 75-90 cm. Our data suggests that woodland expansion into sagebrush ecosystems has limited potential to store additional belowground OC, and must be weighed against the risk of increased wildfire and exotic grass invasion.  相似文献   
7.
Benthic nitrogen (N) cycling was investigated at six stations along a transect traversing the Peruvian oxygen minimum zone (OMZ) at 11°S. An extensive dataset including porewater concentration profiles and in situ benthic fluxes of nitrate (NO3), nitrite (NO2) and ammonium (NH4+) was used to constrain a 1-D reaction-transport model designed to simulate and interpret the measured data at each station. Simulated rates of nitrification, denitrification, anammox and dissimilatory nitrate reduction to ammonium (DNRA) by filamentous large sulfur bacteria (e.g. Beggiatoa and Thioploca) were highly variable throughout the OMZ yet clear trends were discernible. On the shelf and upper slope (80-260 m water depth) where extensive areas of bacterial mats were present, DNRA dominated total N turnover (?2.9 mmol N m−2 d−1) and accounted for ?65% of NO3 + NO2 uptake by the sediments from the bottom water. Nonetheless, these sediments did not represent a major sink for dissolved inorganic nitrogen (DIN = NO3 + NO2 + NH4+) since DNRA reduces NO3 and, potentially NO2, to NH4+. Consequently, the shelf and upper slope sediments were recycling sites for DIN due to relatively low rates of denitrification and high rates of ammonium release from DNRA and ammonification of organic matter. This finding contrasts with the current opinion that sediments underlying OMZs are a strong sink for DIN. Only at greater water depths (300-1000 m) did the sediments become a net sink for DIN. Here, denitrification was the major process (?2 mmol N m−2 d−1) and removed 55-73% of NO3 and NO2 taken up by the sediments, with DNRA and anammox accounting for the remaining fraction. Anammox was of minor importance on the shelf and upper slope yet contributed up to 62% to total N2 production at the 1000 m station. The results indicate that the partitioning of oxidized N (NO3, NO2) into DNRA or denitrification is a key factor determining the role of marine sediments as DIN sinks or recycling sites. Consequently, high measured benthic uptake rates of oxidized N within OMZs do not necessarily indicate a loss of fixed N from the marine environment.  相似文献   
8.
Co-management institutional arrangements have an important role in creating conditions for social learning and adaptation in a rapidly changing Arctic environment, although how that works in practice has not been clearly articulated. This paper draws on three co-management cases from the Canadian Arctic to examine the role of knowledge co-production as an institutional trigger or mechanism to enable learning and adapting. Experience with knowledge co-production across the three cases is variable but outcomes illustrate how co-management actors are learning to learn through uncertainty and environmental change, or learning to be adaptive. Policy implications of this analysis are highlighted and include the importance of a long-term commitment to institution building, an enabling policy environment to sustain difficult social processes associated with knowledge co-production, and the value of diverse modes of communication, deliberation and social interaction.  相似文献   
9.
Here we examine the arrangement of plant species across an oligotrophic bog/poor fen peatland complex in the North American boreal plain and the relationships of these species to their physical and chemical environment. A semi‐uniform spatial sampling approach was utilized to describe the species assemblages, pore‐water chemistry and physical condition of 100 plots throughout a single peatland complex. Regardless of sharing the same ground cover of Sphagnum mosses, the remaining species separated into four distinct assemblages, each with unique indicators. These species groups along with associated chemical and physical factors are organized into four ecosites: bog, margin (edge) and two poor fen ecosites. The plant assemblages of this peatland have a complex relationship with numerous gradients, both physical and chemical, including depth to water table, shade, pH, nutrient and base cation. Rather than being homogenous across the landscape, most environmental variables exhibit distinct spatial patterns and do so in relationship to the plant assemblages, forming spatially distinct ecosites across the complex. Base cation concentrations play a smaller role than previously thought in differentiating these ecosites, and in addition to shade and depth to water table, nitrogen in the form of dissolved organic nitrogen was highly related to the placement of these ecosites. Many significant chemical factors appear related to evaporative water loss within the peatland complex, and these chemical factors are used to differentiate the ecosites. However, the mediation of evaporative water loss is due largely to self‐generated responses of the plant assemblages related to shade through plant morphology and peat acrotelm development related to depth to water table. We conclude that plant species and associated environmental gradients act together to form spatially distinct ecosites. The distribution of these ecosites within this large, environmentally complex peatland is largely controlled by differing self‐generated responses along the hydrotopographical gradient of differential water loss.  相似文献   
10.
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