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1.
The monitoring of water quality, especially of karst springs, requires methods for rapidly estimating and quantifying parameters that indicate contamination. In the last few years, fluorescence-based measurements of tryptophan and humic acid have become a promising tool to assess water quality in near real-time. In this study, we conducted comparative tracer tests in a karst experimental site to investigate the transport properties and behavior of tryptophan and humic acid in a natural karst aquifer. These two tracers were compared with the conservative tracer uranine. Fluorescence measurements were conducted with an online field fluorometer and in the laboratory. The obtained breakthrough curves (BTCs) and the modeling results demonstrate that (1) the online field fluorometer is suitable for real-time fluorescence measurements of all three tracers; (2) the transport parameters obtained for uranine, tryptophan, and humic acid are comparable in the fast flow areas of the karst system; (3) the transport velocities of humic acid are slower and the resulting residence times are accordingly higher, compared to uranine and tryptophan, in the slower and longer flow paths; (4) the obtained BTCs reveal additional information about the investigated karst system. As a conclusion, the experiments show that the transport properties of tryptophan are similar to those of uranine while humic acid is partly transported slower and with retardation. These findings allow a better and quantitative interpretation of the results when these substances are used as natural fecal and contamination indicators.  相似文献   
2.
Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO2 sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.  相似文献   
3.
The occurrence of disasters such as extreme flooding in urban environments has severe consequences, not only on the human population but also on critical infrastructures such as the road networks, which are of vital importance for everyday living and particularly for emergency response. In this article, our main goal is to present-conceptually and in praxis-a model that could be used from the emergency responders for timely and efficient emergency management and response in an urban complex environment. For the city of Cologne in Germany, we aim to indicate possible ways to decrease the emergency response time during an extreme flood scenario through the development of an accessibility indicator, which consists of different components. Therefore, we will investigate the opportunities that occur, in a flood risk scenario, from the use of geographic information in different forms such as Volunteered Geographic Information (VGI) and open-source data in an ArcGIS environment, to increase urban resilience through the decreasing emergency response time. We will focus on network analysis for the fire brigades (first acting emergency responders) during a flood scenario to calculate their emergency response ranges and emergency response routes through flooded road networks, for the assistance of the possibly affected hospitals, refugee homes and fire brigades, which can be flooded. At the end of the paper, we suggest that the vulnerable community of the refugees could be taken into consideration as a new source of VGI, as an additional component that would lead to the decrease in the emergency response time. The geo-located information that could be provided by the refugee community can be very useful in emergency situations, such as those examined in this article where timely information can be forwarded to the proper authorities for a more focused and timely emergency response, increasing the resilience of the urban population and their community.  相似文献   
4.
Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston–cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm?1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P–T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from ??0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P–T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than ~?10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.  相似文献   
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6.
This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.  相似文献   
7.
Helium and neon distributions are reported for a variety of Stardust comet 81P/Wild 2 samples, including particle tracks and terminal particles, cell surface and subsurface slices from the comet coma and interstellar particle collection trays, and numerous small aerogel blocks extracted from comet cells C2044 and C2086. Discussions and conclusions in several abstracts published during the course of the investigation are included, along with the relevant data. Measured isotope ratios span a broad range, implying a similar range for noble gas carriers in the Wild 2 coma. The meteoritic phase Q‐20Ne/22Ne ratio was observed in several samples. Some of these, and others, exhibit 21Ne excesses too large for attribution to spallation by galactic cosmic ray irradiation, suggesting exposure to a solar proton flux greatly enhanced above current levels in an early near‐Sun environment. Still others display evidence for a solar wind component, particularly one C2086 block with large abundances of isotopically solar‐like helium and neon. Eighty‐nine small aerogel samples were cut from depths up to several millimeters below the cell C2044 surface and several millimeters away from the axis of major track T41. A fraction of these yielded measurable and variable helium and neon abundances and isotope ratios, although none contained visible tracks or carrier particle fragments and their locations were beyond estimated penetration ranges for small particles or ions incident on the cell surface, or for lateral ejecta from T41. Finding plausible emplacement mechanisms and sources for these gases is a significant challenge raised by this study.  相似文献   
8.
Mathematical Geosciences - Customary and routine practice of geostatistical modeling assumes that inter-point distances are a Euclidean metric (i.e., as the crow flies) when characterizing spatial...  相似文献   
9.
Synoptic atmospheric eddies are affected by lower tropospheric air-temperature gradients and by turbulent heat fluxes from the surface. In this study we examine how ocean fronts affect these quantities and hence the storm tracks. We focus on two midlatitude regions where ocean fronts lie close to the storm tracks: the north-west Atlantic and the Southern Ocean. An atmospheric climate model of reasonably high resolution (~50 km) is applied in a climate-length (60 year) simulation in order to obtain stable statistics. Simulations with frontal structure in the sea surface temperature (SST) in one of the regions are compared against simulations with globally smoothed SST. We show that in both regions the ocean fronts have a strong influence on the transient eddy heat and moisture fluxes, not just in the boundary layer, but also in the free troposphere. Local differences in these quantities between the simulations reach 20–40 % of the maximum values in the simulation with smoothed SST. Averaged over the entire region of the storm track over the ocean the corresponding differences are 10–20 %. The effect on the transient eddy meridional wind variance is strong in the boundary layer but relatively weak above that. The potential mechanisms by which the ocean fronts influence the storm tracks are discussed, and our results are compared against previous studies with regional models, Aquaplanet models, and coarse resolution coupled models.  相似文献   
10.
The goal of this contribution is to focus on improving the quality of gravity field models in the form of spherical harmonic representation via alternative configuration scenarios applied in future gravimetric satellite missions. We performed full-scale simulations of various mission scenarios within the frame work of the German joint research project “Concepts for future gravity field satellite missions” as part of the Geotechnologies Program, funded by the German Federal Ministry of Education and Research and the German Research Foundation. In contrast to most previous simulation studies including our own previous work, we extended the simulated time span from one to three consecutive months to improve the robustness of the assessed performance. New is that we performed simulations for seven dedicated satellite configurations in addition to the GRACE scenario, serving as a reference baseline. These scenarios include a “GRACE Follow-on” mission (with some modifications to the currently implemented GRACE-FO mission), and an in-line “Bender” mission, in addition to five mission scenarios that include additional cross-track and radial information. Our results clearly confirm the benefit of radial and cross-track measurement information compared to the GRACE along-track observable: the gravity fields recovered from the related alternative mission scenarios are superior in terms of error level and error isotropy. In fact, one of our main findings is that although the noise levels achievable with the particular configurations do vary between the simulated months, their order of performance remains the same. Our findings show also that the advanced pendulums provide the best performance of the investigated single formations, however an accuracy reduced by about 2–4 times in the important long-wavelength part of the spectrum (for spherical harmonic degrees ${<}50$ ), compared to the Bender mission, can be observed. Concerning state-of-the-art mission constraints, in particular the severe restriction of heterodyne lasers on maximum range-rates, only the moderate Pendulum and the Bender-mission are beneficial options, of course in addition to GRACE and GRACE-FO. Furthermore, a Bender-type constellation would result in the most accurate gravity field solution by a factor of about 12 at long wavelengths (up to degree/order 40) and by a factor of about 200 at short wavelengths (up to degree/order 120) compared to the present GRACE solution. Finally, we suggest the Pendulum and the Bender missions as candidate mission configurations depending on the available budget and technological progress.  相似文献   
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