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1.
Acta Geotechnica - The elastic stiffness of a fine sand at small to moderate strains ( $$\varepsilon \le 2 \times 10^{-4}$$ ) has been studied based on cyclic triaxial tests on cube-shaped samples...  相似文献   
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This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ18Odiatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ18Odiatom values range from +29.8 to +35.0‰, and relatively higher δ18Odiatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ18Odiatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ18Odiatom values, whereas lower lake levels cause higher δ18Odiatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ18Odiatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ18Odiatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.  相似文献   
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Urban areas are the focus of major ecological, social and economical activity. They are thus also prime locations of increasing conflict with regard to water use and water protection. As a direct and/or indirect consequence of urban land use and human activity, urban water systems are frequently polluted with organic contaminants including waste water-born xenobiotics such as pharmaceuticals, personal care products (collectively known as PPCPs) and endocrine-active substances. This study reviews new integrated methodologies including flux calculations as well as chemical investigations for determining the impact of human activities on urban water systems and on processes within the urban watershed. The use of indicator substances, representing different contaminant sources and pathways, integral pumping tests and mass balance approaches are suitable alternatives within these environments. The issues are explored using contaminant mass balance examples from Halle/Saale and Leipzig, Germany.  相似文献   
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Vitreous materials are quite routinely found in natural settings. Most of them are aluminosilicates, which often occur in large deposits. Considering the geological formations in which naturally occurring vitreous aluminosilicates are found, they have generally remained stable for more than 1 Ma on the earth's surface, even in different geological and climatic environments. These non-crystalline solids played a very important role in the development of ancient human civilizations, long before the introduction of metallic tools. Today, however, the properties of natural glasses are of interest to mankind for completely different reasons. For example, industrial glasses are used today for encapsulating toxic wastes, especially radioactive waste, which remains active for centuries or more, in order to prevent the unwanted transfer of harmful materials to the environment. The chemical compositions of industrially produced glasses are in large part different from the compositions of natural glasses. Little is quantitatively known about the stability of industrial glasses over very long periods of time (>10,000 years). However, the physical and chemical stability of natural aluminosilicate glasses is known to extend over very long periods of time.The advancement of technological design to prevent or at least minimize the melt down of toxic waste during the encapsulation process is currently a major challenge, using glasses of natural chemical composition. Brecciated glass, which is found frequently in natural settings, provides a special clue to the possibility of producing vitreous solids by sintering glass fragments without melting the cullets. It is essential to prevent melting of the cullets because the melt has the potential of chemically reacting with the toxic waste.This paper summarizes the geological, chemical, and physical facts concerning naturally produced glasses, and seeks to establish a recognized database for further research in the domain of understanding the glass-forming processes that occur in nature. Furthermore, the authors hope to stimulate research into the utilization of natural resources that to solve the problem of storing of toxic waste safely.Major and trace element data have been collected over the past 100 years. These data constitute a sufficient basis for the chemical characterization of natural glasses. More information about the major elements is not required, in order to understand the chemical properties of these materials. On the other hand, large gaps in compositional data exist where other related components are concerned: e.g., in the case of “water-species”, with its different forms of bonding in silicates or oxygen (oxygen fugacity), CO2-, sulphur - or hydrocarbons (methane)-, hydrogen-, chlorine-and fluorine-species. All these components have a significant impact on the properties of glasses, even when present only in minor quantities. Glass textures and crystal morphologies reflect the processes of nucleation and crystal growth in a glass-forming matrix during the cooling and reheating cycles which are currently not thoroughly understood. In nature, the processes that led to the formation of vitreous materials are very different from those used in the production of industrial glasses. The different genetic conditions under which glass formation occurs permit differentiation between magmatic and metamorphic vitreous solids. Sedimentary and biogenetic processes also contribute to the formation of non-crystalline solids.  相似文献   
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The method of geometric-astronomical leveling is presented as a suited technique for the validation of GNSS (Global Navigation Satellite System) heights. In geometric-astronomical leveling, the ellipsoidal height differences are obtained by combining conventional spirit leveling and astronomical leveling. Astronomical leveling with recently developed digital zenith camera systems is capable of providing the geometry of equipotential surfaces of the gravity field accurate to a few 0.1 mm per km. This is comparable to the accuracy of spirit leveling. Consequently, geometric-astronomical leveling yields accurate ellipsoidal height differences that may serve as an independent check on GNSS height measurements at local scales. A test was performed in a local geodetic network near Hanover. GPS observations were simultaneously carried out at five stations over a time span of 48 h and processed considering state-of-the-art techniques and sophisticated new approaches to reduce station-dependent errors. The comparison of GPS height differences with those from geometric-astronomical leveling shows a promising agreement of some millimeters. The experiment indicates the currently achievable accuracy level of GPS height measurements and demonstrates the practical applicability of the proposed approach for the validation of GNSS height measurements as well as the evaluation of GNSS height processing strategies.  相似文献   
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A possible asynchronicity of the spatial and temporal moisture availability on the Tibetan Plateau has been a controversial subject of discussion in recent years. Here we present the first attempt to systematically investigate possible spatial and temporal variations in moisture availability by examining two lakes, Tangra Yumco and Nam Co, on an east–west transect on the southern Tibetan Plateau using identical proxies for palaeoenvironmental reconstruction. In this study, an independent record from Tangra Yumco was analysed applying a multi‐proxy approach to reconstruct variations in moisture availability since the Lateglacial. Results were subsequently compared with previously published records from Nam Co and additional records from Tso Moriri (northwestern Himalaya) and Naleng Co (southeastern Tibetan Plateau). Our results show that Tangra Yumco was at least partially ice covered prior to 17.1 cal. ka BP. A temperature rise after 17.1 cal. ka BP probably resulted in thawing of the permafrost. At 16.0 cal. ka BP moisture availability increased, representing an initial monsoonal intensification. Warmer conditions between 13.0 and 12.4 cal. ka BP and cooler conditions between 12.4 cal. ka BP and the onset of the Holocene reflect the Bølling‐Allerød and Younger Dryas. At the onset of the Holocene moisture availability rapidly increased, with moisture highest prior to 8.5 cal. ka BP when temperatures were also highest. After 8.5 cal. ka BP the moisture availability gradually decreased and showed only minor amplitude variations. These findings are consistent with the records from large lakes like Nam Co, Tso Moriri, and Naleng Co, revealing a synchronous pattern of moisture availability on the southern Tibetan Plateau.  相似文献   
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