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1.
Toshihiro Yoshimura Atsushi Suzuki Yusuke Tamenori Hodaka Kawahata 《Geo-Marine Letters》2014,34(1):1-9
Micro-scale distributions of trace and minor elements in, for example, coral skeletons are crucial as geochemical tracers of past environmental conditions, because they have the inherent advantage of accounting for confounding diagenetic and physiological effects. To extract reproducible paleoceanographic records from coral skeletons, a selective measurement of specific ultrastructures at high spatial resolution is required. Compared to warm-water reef-building corals, such data are limited in cold-water corals and, to the best of the authors’ knowledge, the latter have to date not been examined by means of micro-X-ray fluorescence. This technique was used for micrometer-scale imaging of P, Mg, Sr, O, and Fe intensities (counts per unit time) in a fossil specimen (as yet unknown age) of the cold-water coral Desmophyllum sp. from surface sediments of the NW Pacific. Cross plots confirmed that the micro-XRF signals were associated with corresponding trends in elemental concentration (ppm). Two major structural components of the septum—centers of calcification (COCs) and the surrounding fibrous aragonite portion—differed in composition. The COCs were characterized by higher intensities of P and Mg (650 and 220 counts per 5 s, respectively), and lower intensities of Sr (2,800) and O (580; corresponding values for the fibrous aragonite are 370, 180, 3,300 and 620 counts per 5 s, respectively). Oxygen intensity values were mostly homogeneous, but slightly lower in COCs and substantially higher in a well-defined patch in the fibrous aragonite. The mostly homogeneous P signals in the fibrous aragonite confirm the utility of this structural component and of coral septa in general for tracer studies of oceanic P. Nevertheless, spot occurrences of elevated P (>950 counts per 5 s) spanning tens of micrometers in specific parts of the fibrous region of the septum would cause overestimates of oceanic P, and should evidently not be overlooked in future research. The distribution of Fe showed no correlation with P, indicating no significant contamination in the form of P-bearing diagenetic ferromanganese precipitates. Such hotspots plausibly reflect the presence of other mineral phases, such as crystalline hydroxylapatite inclusions or contamination with organic material. The P signal intensity was positively correlated with Mg (r=0.553, p<0.001), and negatively with Sr (r=–0.489, p<0.001) and O (r=–0.311, p<0.001). There was no discernible evidence of control by water temperature in the Sr distribution pattern. These findings establish micro-X-ray fluorescence as a highly suitable pre-screening tool in cold-water coral sclerochronology, which can serve to refine sampling strategies without sample damage, and complement other micrometer-scale spatial distribution analyses of elements (notably, Ca) based on well-known approaches involving micro-milling, electron microprobes, secondary ion mass spectrometry, and laser ablation. 相似文献
2.
Lallan Prasad Gupta Hodaka Kawahata Mio Ltakeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2006,56(2):191-196
Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions. 相似文献
3.
The skeletal oxygen isotope ratio of Porites corals is the most frequently used proxy of past seawater temperature and composition for tropical and subtropical oceans. However, field calibration of the proxy signals is often difficult owing to the dual dependence of skeletal oxygen isotope ratio on temperature and the oxygen isotope composition of water. We conducted tank experiments in which we grew Porites spp. colonies for 142 d in thermostated seawater at five temperature settings between 21°C and 29°C under moderate light intensity of 250 μmol m−2 s−1 with a 12:12 light:dark photoperiod. A skeletal isotope microprofiling technique applied along the major growth axis of each colony revealed that the oxygen isotope ratios of newly deposited skeleton in most colonies remained almost constant during tank incubation, thus providing an ideal situation for precise calibration of oxygen isotope ratio proxy signals. However, the oxygen isotope ratios displayed an unusually large intercolony variability (∼1‰) at each temperature setting although the mean slope (∼0.15‰ °C−1) obtained for the temperature-skeletal oxygen isotope ratio relationship was close to previous results. The intercolony variations in the oxygen isotope ratios were apparently caused by kinetic isotope effects related to variations in the skeletal growth rate rather than by species-specific variability or genetic differences within species. No correlation was found between skeletal carbon isotope ratios and temperature. The carbon isotope ratios showed significantly inverse correlation with linear growth rates, suggesting a kinetic isotope control at low growth rates. Observed intercolony variability in skeletal carbon isotope ratios (∼5‰) can be partly attributed to growth-rate-related kinetic isotope effects. 相似文献
4.
Lallan Prasad Gupta Hodaka Kawahata Mio Takeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2005,55(4):357-372
Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws. 相似文献
5.
Preparation of a New Geological Survey of Japan Geochemical Reference Material: Coral JCp-1 总被引：2，自引：0，他引：2
Takashi Okai Atsushi Suzuki Hodaka Kawahata Shigeru Terashima Noboru Imai 《Geostandards and Geoanalytical Research》2002,26(1):95-99
A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed. 相似文献
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7.
Hodaka Kawahata Hideaki Ohshima Azumi Kuroyanagi 《Journal of Asian Earth Sciences》2011,40(6):430-1202
The Mixed Water Region (MWR) between the Oyashio Current and the Kuroshio Extension and surrounding terrestrial region have been affected by the global climatic change. The sedimentary core KR02-15 PC6 collected at 40°23.8871′N, 143°29.8663′E in the MWR provides detailed records of pollen and spores and alkenone sea surface temperature (SST) during the last 15 kyr, showing that both ocean and terrestrial environments have been appreciably linked. Abundance of Picea, a proxy for terrestrial cool climate, fluctuated, coinciding with the alkenone-SST change during the interstadial period (15.0–7.7 cal kyr B.P.). Alkenone-SST increased to the modern level at 8.0 cal kyr B.P. and remained almost constant until 2.0 kyr B.P. while the terrestrial warming still continued until 4.0 cal kyr B.P. The rainfall under terrestrial warm condition increased gradually from 7.9 cal kyr B.P. and rapidly from 2.0 cal kyr B.P. Both terrestrial and marine environments cooled down during the last 2 kyr possibly due to the intensified cold Oyashio Current. 相似文献
8.
Takuya Manaka Hiroyuki Ushie Daisuke Araoka Akihiko Inamura Atsushi Suzuki Hodaka Kawahata 《Aquatic Geochemistry》2013,19(4):281-302
The global carbon cycle, one of the important biogeochemical cycles controlling the surface environment of the Earth, has been greatly affected by human activity. Anthropogenic nutrient loading from urban sewage and agricultural runoff has caused eutrophication of aquatic systems. The impact of this eutrophication and consequent photosynthetic activity on CO2 exchange between freshwater systems and the atmosphere is unclear. In this study, we focused on how nutrient loading to lakes affects their carbonate system. Here, we report results of surveys of lakes in Japan at different stages of eutrophication. Alkalization due to photosynthetic activity and decreases in PCO2 had occurred in eutrophic lakes (e.g., Lake Kasumigaura), whereas in an acidotrophic lake (Lake Inawashiro) that was impacted by volcanic hot springs, nutrient loading was changing the pH and carbon cycling. When the influence of volcanic activity was stronger in the past in Lake Inawashiro, precipitation of volcanic-derived iron and aluminum had removed nutrients by co-precipitation. During the last three decades, volcanic activity has weakened and the lake water has become alkalized. We inferred that this rapid alkalization did not result just from the reduction in acid inputs but was also strongly affected by increased photosynthetic activity during this period. Human activities affect many lakes in the world. These lakes may play an important part in the global carbon cycle through their influence on CO2 exchange between freshwater and the atmosphere. Biogeochemical changes and processes in these systems have important implications for future changes in aquatic carbonate systems on land. 相似文献
9.
Four year-long time-series sediment trap experiments were conducted along the equatorial Pacific Ocean in order to understand the biogeochemistry of particulate organic matter (POM) on the basis of amino acid (AA) and hexosamine (HA) compositions of the settling particles. Total mass flux in the study area varied over 4 orders of magnitude without a common seasonality among all trap sites. Planktonic blooms were apparent in terms of total mass and AA fluxes at the easternmost end of the Niño-4 region. AA fluxes closely followed the total mass flux profiles, suggesting that increased particle flux delivered a greater amount of labile OM to the deep ocean. A labile OM index (LI)-based classification showed that during the El Niño conditions in 2002, the eastern side of the equatorial Pacific transported relatively more labile OM than the western equatorial Pacific. An overall change in AA and HA composition of settling particles could be revealed with the help of discriminant analysis, suggesting that settling particles during El Niño were compositionally different from those settling during La Niña condition in the equatorial Pacific. 相似文献
10.
Hodaka Kawahata Mayuri Inoue Masato Nohara Atsushi Suzuki 《Journal of Oceanography》2006,62(4):405-412
The δ18O, δ13C and trace element composition of pearls collected from Ago Bay, Japan, were investigated in order to evaluate biomineralization
in the cultured pearl oyster (Pinctada fucata martensii). The oxygen isotopic data suggest that the pearls were produced around 23–24°C, mainly in June to early July, which is consistent
with their occurrence in the field. Therefore the pearls were produced under or close to isotopic equilibrium conditions,
although they showed high calcification rates (higher than 0.2–1.0 g cm− 2yr−1) under which, for example, coral skeletons (calcification rate ∼0.28 g cm− 2yr−1) often show non-equilibrium isotope partitioning. The δ13C values were ∼− 2.9‰ lower than those calculated for offshore waters under equilibrium conditions. This may be due to low-δ13C bottom waters resulting from the degradation of organic matter (OM) or to a contribution of low-δ 13C food. In the latter case, a simple mass balance calculation gives a respiration component of 14%. Twelve trace elements
of bulk pearl samples were classified into four groups on the basis of their enrichment/depletion patterns relative to seawater
and inter-element relationships: group 1, Co, Cr, Pb; group 2, Ba, Cs, U; group 3, Cu, Sn, V, and group 4, Mn, Rb, Mo. Comparison
with coral skeletons suggests that Ba and Mn (groups 2 and 4) were definitely much enriched in proteinaceous OM relative to
aragonite crystals in pearls and that V (group 3) in pearls showed only slight enrichment in the organicrich layer. By contrast,
the other elements showed small differences between both layers (enrichment factor of <3), suggesting that these elements
occur largely in aragonite crystals. 相似文献