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1.
The Mikabu and Sorachi–Yezo belts comprise Jurassic ophiolitic complexes in Japan, where abundant basaltic to picritic rocks occur as lavas and hyaloclastite blocks. In the studied northern Hamamatsu and Dodaira areas of the Mikabu belt, these rocks are divided into two geochemical types, namely depleted (D-) and enriched (E-) types. In addition, highly enriched (HE-) type has been reported from other areas in literature. The D-type picrites contain highly magnesian relic olivine phenocrysts up to Fo93.5, and their Fo–NiO trend indicates fractional crystallization from a high-MgO primary magma. The MgO content is calculated as high as 25 wt%, indicating mantle melting at unusually high potential temperature (T p) up to 1,650 °C. The E-type rocks represent the enrichment in Fe and LREE and the depletion in Mg, Al and HREE relative to the D-type rocks. These chemical characteristics are in good accordance with those of melts from garnet pyroxenite melting. Volcanics in the Sorachi–Yezo belts can be divided into the same types as the Mikabu belt, and the D-type picrites with magnesian olivines also show lines of evidence for production from high T p mantle. Evidence for the high T p mantle and geochemical similarities with high-Mg picrites and komatiites from oceanic and continental large igneous provinces (LIPs) indicate that the Mikabu and Sorachi–Yezo belts are accreted oceanic LIPs that were formed from hot large mantle plumes in the Late Jurassic Pacific Ocean. The E- and D-type rocks were formed as magmas generated by garnet pyroxenite melting at an early stage of LIP magmatism and by depleted peridotite melting at the later stage, respectively. The Mikabu belt characteristically bears abundant ultramafic cumulates, which could have been formed by crystal accumulation from a primary magma generated from Fe-rich peridotite mantle source, and the HE-type magma were produced by low degrees partial melting of garnet pyroxenite source. They should have been formed later and in lower temperatures than the E- and D-type rocks. The Mikabu and Sorachi Plateaus were formed in a low-latitude region of the Late Jurassic Pacific Ocean possibly near a subduction zone, partially experienced high P/T metamorphism during subduction, and then uplifted in association with (or without, in case of Mikabu) the supra-subduction zone ophiolite. The Mikabu and Sorachi Plateaus may be the Late Jurassic oceanic LIPs that could have been formed in brotherhood with the Shatsky Rise.  相似文献   
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Granulitized coesite-bearing eclogite from Weihai, northeastern part of the Shandong peninsula, eastern China was studied in detail to reveal the modification of mineral chemistry during decompression metamorphism. Considerable modification of chemical composition is recorded in clinopyroxene that occurs both as inclusions in garnet and as a matrix mineral. Careful examination of chemical variation with the change in microstructure made it possible to estimate the equilibrium composition of minerals at the coesite eclogite and garnet granulite stages. We were able to define three reference points on the PT path, namely, coesite eclogite (3 GPa, 660±40°C), granulite (1 GPa, 700±30°C) and amphibolite (0.9 GPa, 600±20°C). The path thus obtained is similar to those obtained by previous workers and supports nearly isothermal decompression of coesite eclogite.  相似文献   
4.
Chromites separated from the upper mantle or lower crustal portions of 18 ophiolites ranging in age from 900 Ma to 50 Ma are examined for Re-Os isotopic systematics. The ophiolites include both MORB and back arc types, although most are from supra-subduction zone (SSZ) settings. The chromites are robust indicators of the initial Os isotopic compositions of the systems sampled. There is very limited range in calculated initial γOs values, with the entire group averaging +1.31. Least squares linear regression of the age of chromite formation (in Ga) versus initial 187Os/188Os of a filtered suite yields a slope of −0.0058±0.0019 (2σ) and a present day intercept of 0.12809±0.00085 (2σ), equivalent to a γOs value of +0.9±0.6. Of the suite of 51 samples analyzed, 68% lie within ±1% of this evolution trajectory.Although most of the samples formed in SSZ environments, there is little evidence to suggest modification of the mantle Os isotopic composition via radiogenic melts or fluids derived from subducting slabs. The ophiolite data are interpreted as representative of the convecting upper mantle and suggest that the present isotopic composition of the convecting upper mantle averages approximately 1.2% less radiogenic than the estimated minimum composition of the primitive upper mantle of 0.1296±8 (Meisel et al., 2001). The most likely explanation for the difference is the formation, subduction and isolation of some portion of the mafic oceanic crust. Using models based on the assumption that the convecting upper mantle comprises 50% of the total mass of the mantle, and that the average isolation period for subducted oceanic crust is 1.5 to 2.0 Ga, it is estimated that approximately 2 to 3% of the total mass of the mantle is composed of subducted mafic oceanic crust that remains isolated from the convecting upper mantle. Because the isotopic compositions of the DMM and PUM overlap within uncertainties, however, the results do not require any isolated slab component.  相似文献   
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Humic acids from Recent lacustrine and marine sediments were divided into five components by extractions with organic solvents and characterized by elementary composition, ultraviolet, visible and infrared absorption spectra and n.m.r. spectra. The results suggest that sedimentary humic acids have a cyclic structure (40–50% of the total carbon), which is considered to be alicyclic rather than aromatic. No marked differences except for an absorption near 410 mμ were observed between humic acids from lake and marine sediments.  相似文献   
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We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C24 to C30 alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C27 to C33 alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C24 to C30 alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C24 to C30 alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ13C values of n-C27 to C33 alkanes (e.g. ?29‰ to ?33‰ for C31) indicate the presence of C3-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C24 to C30 alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C27 to C33 alkane parameter are generally higher than those using lignin phenol or n-C24 to C30 alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.  相似文献   
9.
The Matachingai River basin is known among the few ophiolitic complexes on eastern Chukotka as the southern boundary of the Chukotka Fold System (in terms of tectonics, the Chukotka microcontinent or a fragment of the Arctic Alaska–Chukotka microplate). This complex comprises tectonic blocks of residual spinel harzburgite with dunite bodies and pyroxenite, olivine gabbro, and leucogabbro veins; blocks of hornblende gabbro, diorite, and plagiogranite; and Upper Jurassic–Lower Cretaceous basaltic–cherty and cherty–carbonate rocks. The geological relationships of rocks within tectonic blocks, the compositions of primary minerals, the bulk geochemistry of rocks, as well as the strontium, neodymium, and lead isotopic compositions, make it possible to consider individual tectonic blocks of the complex as fragments of a disintegrated oceanic-type lithosphere that formed in a back-arc spreading center. The melts, crystallization products of which are represented by hornblende gabbro of blocks, olivine gabbro of veins, and basalts, separated from geochemically and isotopically heterogeneous mantle. Blocks composed of rocks with various modal composition are likely relicts of an oceanic lithosphere of different segments of a back-arc basin. The studied complex may be a lithosphere of one of the Middle–Late Jurassic back-arc basins. Fragments of these basins are retained in ophiolitic complexes on Great Lyakhovsky Island of the New Siberian Islands Archipelago, western Chukotka, and the Brooks Range in Alaska.  相似文献   
10.
Serpentinites (massive and schistose) and listvenite occur as tectonic sheets and lenses within a calcareous metasedimentary mélange of the Tulu Dimtu, western Ethiopia. The massive serpentinite contains high-magnesian metamorphic olivine (forsterite [fo] ~96 mol%) and rare relict primary mantle olivine (Fo90–93). Both massive and schistose serpentinites contain zoned chromian spinel; the cores with the ferritchromite rims preserve a pristine Cr/(Cr+Al) atomic ratio (Cr# = 0.79–0.87), suggesting a highly depleted residual mantle peridotite, likely formed in a suprasubduction zone setting. Listvenite associated with serpentinites of smaller ultramafic lenses also contain relict chromian spinel having identical Cr# to those observed in serpentinites. However, the relict chromian spinel in listvenite has significantly higher Mg/(Mg+Fe2+) atomic ratios. This suggests that a nearly complete metasomatic replacement of ultramafic rocks by magnesite, talc, and quartz to prevent Mg–Fe2+ redistribution between relict chromian spinel and the host, that is, listvenite formation, took place prior to re-equilibration between chromian spinel and the surrounding mafic minerals in serpentinites. Considering together with the regional geological context, low-temperature CO2-rich hydrothermal fluids would have infiltrated into ultramafic rocks from host calcareous sedimentary rocks at a shallow level of accretionary prism before a continental collision to form the East African Orogen (EAO).  相似文献   
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