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1.
. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l–1, which decreased to 9.5 µg l–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.  相似文献   
2.
Mathematical Geosciences - Modeling a mineral microstructure accurately in three dimensions can render realistic mineralogical patterns which can be used for three-dimensional processing...  相似文献   
3.
Zusammenfassung In Fortfühung einer früheren Arbeit der Autoren werden einige weitere theoretische Untersuchungen skizziert, bei denen die elastischen Eigenschaften der Verwitterungschicht geeignet abgeändert sind. Bei Anregung der Schicht durch einen momentanen Impuls (Nadelimpuls) ergibt sich, daß die Frequenz der seismischen Welle nicht durch den Gradienten der Geschwindigkeit, sondern durch den Gradienten des Schallwiderstandes bestimmt wird.
Summary Continuating an earlier paper the authors present some further theoretical investigations on the influence of the weathering layer; the assumptions with regard to the elastic nature of the layer are properly modified. The result is as follows: If the layer is acted on by a momentary pulse (needle pulse) then the frequency of the seismic wave is determined by the gradient of the acoustical resistance, not by the gradient of the velocity of propagation.
  相似文献   
4.
The headwaters of mountainous, discontinuous permafrost regions in north‐eastern Mongolia are important water resources for the semi‐arid country, but little is known about hydrological processes there. Run‐off generation on south‐facing slopes, which are devoid of permafrost, has so far been neglected and is totally unknown for areas that have been affected by recent forest fires. To fill this knowledge gap, the present study applied artificial tracers on a steppe‐vegetated south‐facing and on two north‐facing slopes, burned and unburned. Combined sprinkling and dye tracer experiments were used to visualize processes of infiltration and water fluxes in the unsaturated zone. On the unburned north‐facing slope, rapid and widespread infiltration through a wet organic layer was observed down to the permafrost. On the burned profile, rapid infiltration occurred through a combusted organic and underlying mineral layer. Stained water seeped out at the bottom of both profiles suggesting a general tendency to subsurface stormflow (SSF). Ongoing SSF could directly be studied 24 h after a high‐intensity rainfall event on a 55‐m hillslope section in the burned forest. Measurements of water temperature proved the role of the permafrost layer as a base horizon for SSF. Repeated tracer injections allowed direct insights into SSF dynamics: A first injection suggested rather slow dispersive subsurface flow paths; whereas 18 h later, a second injection traced a more preferential flow system with 20 times quicker flow velocities. We speculate that these pronounced SSF dynamics are limited to burned slopes where a thermally insulating organic layer is absent. On three south‐facing soil profiles, the applied tracer remained in the uppermost 5 cm of a silt‐rich mineral soil horizon. No signs of preferential infiltration could be found, which suggested reduced biological activity under a harsh, dry and cold climate. Instead, direct observations, distributed tracers and charcoal samples provided evidence for the occurrence of overland flow. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
5.
The potential impacts of climate change on potatoes cropping in the Peruvian highlands (Altiplano) is assessed using climate projections for 2071–2100, obtained from the HadRM3P regional atmospheric model of the Hadley Centre. The atmospheric model is run under two different special report on emission scenarios: high CO2 concentration (A2) and moderate CO2 concentration (B2) for four locations situated in the surroundings of Lake Titicaca. The two main varieties of potato cultivated in the area are studied: the Andean potato (Solanum tuberosum) and the bitter potato (Solanum juzepczukii). A simple process-oriented model is used to quantify the climatic impacts on crops cycles and yields by combining the effects of temperature on phenology, of radiation and CO2 on maximum yield and of water balance on yield deficit. In future climates, air temperature systematically increases, precipitation tends to increase at the beginning of the rainy season and slightly decreases during the rest of the season. The direct effects of these climatic changes are earlier planting dates, less planting failures and shorter crop cycles in all the four locations and for both scenarios. Consequently, the harvesting dates occur systematically earlier: roughly in January for the Andean potato instead of March in the current situation and in February for the bitter potato instead of April. Overall, yield deficits will be higher under climate change than in the current climate. There will be a strong negative impact on yields for S. tuberosum (stronger under A2 scenario than under B2); the impact on S. juzepczukii yields, however, appears to be relatively mixed and not so negative.  相似文献   
6.
7.
Menz.  WP 周培 《气象科技》2000,28(2):9-16
自1994年4月以来,新一代静止气象卫星大气垂直探测器一直在18个红外谱段测量大气辐射,提供了研究海洋与大气的能力,其能力大大超出上一代GOES。Menzel和Purdom预见到了GOES-8/9大气探测器多项可能的改进。本文论述了取得了一些成果,详细介绍了大气探测器的飞行性能,给出了经业务定期可得的试验产品,并描述了它们对临近预报和天气预报扔影响。  相似文献   
8.
9.
At sub‐arc depths, the release of carbon from subducting slab lithologies is mostly controlled by fluid released by devolatilization reactions such as dehydration of antigorite (Atg‐) serpentinite to prograde peridotite. Here we investigate carbonate–silicate rocks hosted in Atg‐serpentinite and prograde chlorite (Chl‐) harzburgite in the Milagrosa and Almirez ultramafic massifs of the palaeo‐subducted Nevado‐Filábride Complex (NFC, Betic Cordillera, S. Spain). These massifs provide a unique opportunity to study the stability of carbonate during subduction metamorphism at PT conditions before and after the dehydration of Atg‐serpentinite in a warm subduction setting. In the Milagrosa massif, carbonate–silicate rocks occur as lenses of Ti‐clinohumite–diopside–calcite marbles, diopside–dolomite marbles and antigorite–diopside–dolomite rocks hosted in clinopyroxene‐bearing Atg‐serpentinite. In Almirez, carbonate–silicate rocks are hosted in Chl‐harzburgite and show a high‐grade assemblage composed of olivine, Ti‐clinohumite, diopside, chlorite, dolomite, calcite, Cr‐bearing magnetite, pentlandite and rare aragonite inclusions. These NFC carbonate–silicate rocks have variable CaO and CO2 contents at nearly constant Mg/Si ratio and high Ni and Cr contents, indicating that their protoliths were variable mixtures of serpentine and Ca‐carbonate (i.e., ophicarbonates). Thermodynamic modelling shows that the carbonate–silicate rocks attained peak metamorphic conditions similar to those of their host serpentinite (Milagrosa massif; 550–600°C and 1.0–1.4 GPa) and Chl‐harzburgite (Almirez massif; 1.7–1.9 GPa and 680°C). Microstructures, mineral chemistry and phase relations indicate that the hybrid carbonate–silicate bulk rock compositions formed before prograde metamorphism, likely during seawater hydrothermal alteration, and subsequently underwent subduction metamorphism. In the CaO–MgO–SiO2 ternary, these processes resulted in a compositional variability of NFC serpentinite‐hosted carbonate–silicate rocks along the serpentine‐calcite mixing trend, similar to that observed in serpentinite‐hosted carbonate‐rocks in other palaeo‐subducted metamorphic terranes. Thermodynamic modelling using classical models of binary H2O–CO2 fluids shows that the compositional variability along this binary determines the temperature of the main devolatilization reactions, the fluid composition and the mineral assemblages of reaction products during prograde subduction metamorphism. Thermodynamic modelling considering electrolytic fluids reveals that H2O and molecular CO2 are the main fluid species and charged carbon‐bearing species occur only in minor amounts in equilibrium with carbonate–silicate rocks in warm subduction settings. Consequently, accounting for electrolytic fluids at these conditions slightly increases the solubility of carbon in the fluids compared with predictions by classical binary H2O–CO2 fluids, but does not affect the topology of phase relations in serpentinite‐hosted carbonate‐rocks. Phase relations, mineral composition and assemblages of Milagrosa and Almirez (meta)‐serpentinite‐hosted carbonate–silicate rocks are consistent with local equilibrium between an infiltrating fluid and the bulk rock composition and indicate a limited role of infiltration‐driven decarbonation. Our study shows natural evidence for the preservation of carbonates in serpentinite‐hosted carbonate–silicate rocks beyond the Atg‐serpentinite breakdown at sub‐arc depths, demonstrating that carbon can be recycled into the deep mantle.  相似文献   
10.
Zusammenfassung Nach einer Theorie von Press und Ewing entsteht die seismische Bodenunruhe dadurch, daß atmosphärische Energie von der Meeresoberfläche in einer Kompressionswelle durch das Wasser auf den Ozeanboden übertragen und im Untergrunde in einer elastischen Welle den Kontinenten zugeleitet wird. Es wird der Effekt der von Press und Ewing vernachlässigten Reibung des Wassers am Meeresboden abgeschätzt. Das wesentlichste Ergebnis der Theorie von Press und Ewing, die quantitativ richtige Erklärung der in der seismischen Bodenunruhe zu beobachtenden Perioden durch den Effekt der Dispersion, bleibt auch bei Berücksichtigung der Reibung näherungsweise erhalten. Der Effekt der Dispersion bei den Wellen, die nach der Wiechertschen Brandungshypothese entstehen würden, wird auch abgeschätzt. Er führt zu einer Periode von 11,9 sec, ein Wert, der etwas zu hoch ist. Die Rechnungsgrundlagen sind aber sehr unsicher.
On the theory of microseisms
Summary According to a theory advanced by Press and Ewing atmospheric energy is transmitted to the sea-bottom by compression waves and forwarded to the continents by elastic oscillations of the sub-soil. In the paper that follows an estimate is made of the effect of friction (of the water on the sea-bottom), an effect which has been neglected by Press and Ewing. The outstanding result of their theory, the explanation of the periods observed in microseisms as an effect of dispersion (which is quantitatively correct), is found to remain approximately valid if friction is taken into account. In addition the effect of dispersion is estimated for waves corresponding to Wiechert's surf hypothesis, and a period of 11,9 sec is found, which is somewhat too high. The bases of calculation are, however, by no means reliable.


Herrn Prof. Dr. F. Errulat, seinem verehrten Lehrer, zum 60. Geburtstage gewidmet vom Verfasser.  相似文献   
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