Sediment Trend Analysis through the variation of granulometric parameters: A review of theories and applications     

Emmanuel Poizot  Yann Méar  Laurie Biscara 《Earth》2008,86(1-4):15-41

Spatial variations in grain-size parameters (i.e. grain-size trends) contain information on sediment transport patterns. Analytical procedures have been proposed using the grain-size trend to determine net sediment transport pathways. In the first part of this study, the fundamentals of the theory are presented through methods for analysing 1D and 2D variations. The methods used are critically discussed, while pointing out some severe problems. So far, these methods suffer from limitations leading to serious interpretational errors, making it necessary to take account of two kinds of uncertainties. Inputs uncertainties are linked to the physical sediment properties as well as procedures of sampling and analysis. Model uncertainties are then discussed for each step of the grain-size trend analysis. The validity of Sediment Trend Analysis under natural conditions is tested against published field studies to determine the most appropriate variation trend to use in a specific environment. Proposals are given for each step of the procedure for optimal use of the method using a Quality Assurance (QA) approach. Further developments are proposed, such as integration into a Geographic Information System.  相似文献   

Fractionation of Cu and Zn isotopes during adsorption onto amorphous Fe(III) oxyhydroxide: Experimental mixing of acid rock drainage and ambient river water     

Laurie S. Balistrieri  David M. Borrok  W. Ian Ridley 《Geochimica et cosmochimica acta》2008,72(2):311-328

Fractionation of Cu and Zn isotopes during adsorption onto amorphous ferric oxyhydroxide is examined in experimental mixtures of metal-rich acid rock drainage and relatively pure river water and during batch adsorption experiments using synthetic ferrihydrite. A diverse set of Cu- and Zn-bearing solutions was examined, including natural waters, complex synthetic acid rock drainage, and simple NaNO₃ electrolyte. Metal adsorption data are combined with isotopic measurements of dissolved Cu (⁶⁵Cu/⁶³Cu) and Zn (⁶⁶Zn/⁶⁴Zn) in each of the experiments. Fractionation of Cu and Zn isotopes occurs during adsorption of the metal onto amorphous ferric oxyhydroxide. The adsorption data are modeled successfully using the diffuse double layer model in PHREEQC. The isotopic data are best described by a closed system, equilibrium exchange model. The fractionation factors (α_soln-solid) are 0.99927 ± 0.00008 for Cu and 0.99948 ± 0.00004 for Zn or, alternately, the separation factors (Δ_soln-solid) are −0.73 ± 0.08‰ for Cu and −0.52 ± 0.04‰ for Zn. These factors indicate that the heavier isotope preferentially adsorbs onto the oxyhydroxide surface, which is consistent with shorter metal-oxygen bonds and lower coordination number for the metal at the surface relative to the aqueous ion. Fractionation of Cu isotopes also is greater than that for Zn isotopes. Limited isotopic data for adsorption of Cu, Fe(II), and Zn onto amorphous ferric oxyhydroxide suggest that isotopic fractionation is related to the intrinsic equilibrium constants that define aqueous metal interactions with oxyhydroxide surface sites. Greater isotopic fractionation occurs with stronger metal binding by the oxyhydroxide with Cu > Zn > Fe(II).  相似文献   

Dissolved and labile concentrations of Cd, Cu, Pb, and Zn in the South Fork Coeur d’Alene River, Idaho: Comparisons among chemical equilibrium models and implications for biotic ligand models     

Laurie S. Balistrieri  Richard G. Blank 《Applied Geochemistry》2008,23(12):3355-3371

In order to evaluate thermodynamic speciation calculations inherent in biotic ligand models, the speciation of dissolved Cd, Cu, Pb, and Zn in aquatic systems influenced by historical mining activities is examined using equilibrium computer models and the diffusive gradients in thin films (DGT) technique. Several metal/organic-matter complexation models, including WHAM VI, NICA-Donnan, and Stockholm Humic model (SHM), are used in combination with inorganic speciation models to calculate the thermodynamic speciation of dissolved metals and concentrations of metal associated with biotic ligands (e.g., fish gills). Maximum dynamic metal concentrations, determined from total dissolved metal concentrations and thermodynamic speciation calculations, are compared with labile metal concentrations measured by DGT to assess which metal/organic-matter complexation model best describes metal speciation and, thereby, biotic ligand speciation, in the studied systems. Results indicate that the choice of model that defines metal/organic-matter interactions does not affect calculated concentrations of Cd and Zn associated with biotic ligands for geochemical conditions in the study area, whereas concentrations of Cu and Pb associated with biotic ligands depend on whether the speciation calculations use WHAM VI, NICA-Donnan, or SHM. Agreement between labile metal concentrations and dynamic metal concentrations occurs when WHAM VI is used to calculate Cu speciation and SHM is used to calculate Pb speciation. Additional work in systems that contain wide ranges in concentrations of multiple metals should incorporate analytical speciation methods, such as DGT, to constrain the speciation component of biotic ligand models.  相似文献   

Oxygen isotope heterogeneity in chondrules from the Mokoia CV3 carbonaceous chondrite     

Rhian H Jones  Laurie A Leshin  Zachary D Sharp  Alan J Schilk 《Geochimica et cosmochimica acta》2004,68(16):3423-3438

We report a study of the oxygen isotope ratios of chondrules and their constituent mineral grains from the Mokoia, oxidized CV3 chondrite. Bulk oxygen isotope ratios of 23 individual chondrules were determined by laser ablation fluorination, and oxygen isotope ratios of individual grains, mostly olivine, were obtained in situ on polished mounts using secondary ion mass spectrometry (SIMS). Our results can be compared with data obtained previously for the oxidized CV3 chondrite, Allende. Bulk oxygen isotope ratios of Mokoia chondrules form an array on an oxygen three-isotope plot that is subparallel to, and slightly displaced from, the CCAM (carbonaceous chondrite anhydrous minerals) line. The best-fit line for all CV3 chondrite chondrules has a slope of 0.99, and is displaced significantly (by δ¹⁷O ∼ −2.5‰) from the Young and Russell slope-one line for unaltered calcium-aluminum-rich inclusion (CAI) minerals. Oxygen isotope ratios of many bulk CAIs also lie on the CV-chondrule line, which is the most relevant oxygen isotope array for most CV chondrite components. Bulk oxygen isotope ratios of most chondrules in Mokoia have δ¹⁸O values around 0‰, and olivine grains in these chondrules have similar oxygen isotope ratios to their bulk values. In general, it appears that chondrule mesostases have higher δ¹⁸O values than olivines in the same chondrules. Our bulk chondrule data spread to lower δ¹⁸O values than any ferromagnesian chondrules that have been measured previously. Two chondrules with the lowest bulk δ¹⁸O values (−7.5‰ and −11.7‰) contain olivine grains that display an extremely wide range of oxygen isotope ratios, down to δ¹⁷O, δ¹⁸O around -50‰ in one chondrule. In these chondrules, there are no apparent relict grains, and essentially no relationships between olivine compositions, which are homogeneous, and oxygen isotopic compositions of individual grains. Heterogeneity of oxygen isotope ratios within these chondrules may be the result of incorporation of relict grains from objects such as amoeboid olivine aggregates, followed by solid-state chemical diffusion without concomitant oxygen equilibration. Alternatively, oxygen isotope exchange between an ¹⁶O-rich precursor and an ¹⁶O-poor gas may have taken place during chondrule formation, and these chondrules may represent partially equilibrated systems in which isotopic heterogeneities became frozen into the crystallizing olivine grains. If this is the case, we can infer that the earliest nebular solids from which chondrules formed had δ¹⁷O and δ¹⁸O values around -50‰, similar to those observed in refractory inclusions.  相似文献   

PUTTING THE MESSINESS BACK IN: TOWARDS A GEOGRAPHY OF DEVELOPMENT AS CREATIVITY     

Nina D. Laurie 《Singapore journal of tropical geography》2005,26(1):32-35

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Do sedentary behavior and physical activity spatially cluster? Analysis of a population-based sample of Boston adolescents     

Kosuke Tamura  Dustin T. Duncan  Jessica Athens  Marc Scott  Michael RientiJr.  Jared Aldstadt  Laurie M. Brotman  Brian Elbel 《GeoJournal》2018,83(4):775-782

Sedentary behavior and lack of physical activity are key modifiable behavioral risk factors for chronic health problems, such as obesity and diabetes. Little is known about how sedentary behavior and physical activity among adolescents spatially cluster. The objective was to detect spatial clustering of sedentary behavior and physical activity among Boston adolescents. Data were used from the 2008 Boston Youth Survey Geospatial Dataset, a sample of public high school students who responded to a sedentary behavior and physical activity questionnaire. Four binary variables were created: (1) TV watching (>2 h/day), (2) video games (>2 h/day), (3) total screen time (>2 h/day); and (4) 20 min/day of physical activity (≥5 days/week). A spatial scan statistic was utilized to detect clustering of sedentary behavior and physical activity. One statistically significant cluster of TV watching emerged among Boston adolescents in the unadjusted model. Students inside the cluster were more than twice as likely to report >2 h/day of TV watching compared to respondents outside the cluster. No significant clusters of sedentary behavior and physical activity emerged. Findings suggest that TV watching is spatially clustered among Boston adolescents. Such findings may serve to inform public health policy-makers by identifying specific locations in Boston that could provide opportunities for policy intervention. Future research should examine what is linked to the clusters, such as neighborhood environments and network effects.  相似文献   

Neo-rural populations and their relations with local decision makers in rural Québec: collaboration or conflict?   总被引：1，自引：0，他引：1  

Myriam Simard  Laurie Guimond  Julie Vézina 《GeoJournal》2018,83(3):613-629

The socio-demographic recomposition of the countryside is affecting local interactions and power relations. Understanding these relationships remains a challenge, as the studies to date are often limited to conflicts between neo-rural populations (newcomers) and long-time country residents over partial issues, without including decision makers. To go beyond this conflictual and fragmentary perspective, the objective of this article is to present an overall picture of both cooperative and oppositional relations between four groups, namely, newcomers, long-time rural residents, leaders of local organizations and municipal officials, in regard to all the issues that concern them. The data are based on interviews with these various actors in two contrasting rural areas of Québec (Canada). After looking at the newcomers’ mixed assessment of their participation in community life, we concentrate on areas of collaboration and/or conflict between all the actors regarding demographic, economic, sociocultural, political, environmental and agricultural issues. Three main trends emerge, revealing unexpected ways of interacting, complex power relations and antagonistic conceptions of rural spaces and their future development.  相似文献   

Spatial variability of liquefaction potential in regional mapping using CPT and SPT data   总被引：5，自引：0，他引：5  

Jennifer A. Lenz  Laurie G. Baise   《Soil Dynamics and Earthquake Engineering》2007,27(7):690-702

Cone penetration test (CPT) and standard penetration test (SPT) are widely used for the site specific evaluation of liquefaction potential and are getting increased use in the regional mapping of liquefaction hazard. This paper compares CPT and SPT-based liquefaction potential characterizations of regional geologic units using the liquefaction potential index (LPI) across the East Bay of the San Francisco Bay, California, USA and examines the statistical and spatial variability of LPI across and within geologic units. Overall, CPT-based LPI characterizations result in higher hazard than those derived from the SPT. This bias may result from either mis-classifications of soil type in the CPT or a bias in the CPT simplified procedure for liquefaction potential. Regional mapping based on cumulative distribution of LPI values show different results depending on which dataset is used. For both SPT and CPT-based characterizations, the geologic units in the area have broad LPI distributions that overlap between units and are not distinct from the population as a whole. Regional liquefaction classifications should therefore give a distribution, rather than a single hazard rating that does not provide for variability within the area. The CPT-based LPI values have a higher degree of spatial correlation and a lower variance over a greater distance than those estimated from SPTs. As a result, geostatistical interpolation can provide a detailed map of LPI when densely sampled CPT data are available. The statistical distribution of LPI within specific geologic units and interpolated maps of LPI can be used to understand the spatial variability of liquefaction potential.  相似文献   

The longevity of subcontinental lithospheric mantle beneath Jiangsu-Anhui Region     

Xiachen Zhi  Zicheng Peng  Daogong Chen  Chunjiang Yu  Weidong Sun  Laurie Reisberg 《中国科学D辑(英文版)》2001,44(12):1110-1118

The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The¹⁸⁷Os/¹⁸⁸Os ratio of the sample set ranges from 0.119 to 0.129 (25 samples, USTC) and from 0.117 to 0.131 (17 samples, CRPG). The Os isotopic compositions of most samples are less than 0.129 and depleted relatively to the primitive mantle, showing a good correlation with the major element compositions. With the¹⁸⁷Os/¹⁸⁸Os-Al₂O₃ alumichron, the samples yield a model age of 2.5 ± 0.1 Ga (data of USTC) and 1.9 ± 0.1 Ga (data of CRPG), late Archean to early Pro-terozoic. The two samples with the lowest¹⁸⁷Os/¹⁸⁸Os ratio (0.119 and 0.117) have the T_RD (Re depleted age) of 1.1 Ga (USTC) and 1.4 Ga (CRPG), mid-Proterozoic. The Os isotope model age shows that the peridotite xenoliths from Cenozoic alkali basalt in Jiangsu-Anhui provinces have an old formation age (early- to mid- Proterozoic). They are not newly produced mantle after the Phanerozoic replacement of the lithosphere mantle, but residual fractions of Proterozoic mantle.  相似文献   

Influence of hydraulic conductivity on communities of microorganisms and invertebrates in porous media: a case study in drinking water slow sand filters   总被引：3，自引：0，他引：3  

Laurie Mauclaire  Andreas Schürmann  Florian Mermillod-Blondin 《Aquatic Sciences - Research Across Boundaries》2006,68(1):100-108

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