The geochemistry of gem opals as evidence of their origin     

Eloïse Gaillou  Aurlien Delaunay  Benjamin Rondeau  Martine Bouhnik-le-Coz  Emmanuel Fritsch  Guy Cornen  Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.  相似文献   

Response-based method for determining the extreme behaviour of floating offshore platforms     

Said Mazaheri  Martine J. Downie 《Ocean Engineering》2005,32(3-4):363-393

The accurate prediction of extreme excursion and mooring force of floating offshore structures due to multi-variete environmental conditions which requires the joint probability analysis of environmental conditions for the worst case situation is still impractical as the processing of large amount of met-ocean data is required. On the other hand, the simplified multiple design criteria (e.g. the N-year wave with associated winds and currents) recommended by API known as traditional method does lead neither to the N-year platform response nor to the N-year mooring force. Therefore, in order to reduce the level of conservatism as well as uncertainties involved in the traditional method the response-based method can be used as a reliable alternative approach. In this paper this method is described. In order to perform the calculations faster using large databases of sea states, Artificial Neural Networks (ANN) is designed and employed. In the paper the response-based method is applied to a 200,000 tdw FPSO and the results are discussed.  相似文献   

Uranium co-precipitation with iron oxide minerals   总被引：2，自引：0，他引：2  

Martine C. DuffJessica Urbanik Coughlin  Douglas B. Hunter 《Geochimica et cosmochimica acta》2002,66(20):3533-3547

In oxidizing environments, the toxic and radioactive element uranium (U) is most soluble and mobile in the hexavalent oxidation state. Sorption of U(VI) on Fe-oxides minerals (such as hematite [α-Fe₂O₃] and goethite [α-FeOOH]) and occlusion of U(VI) by Fe-oxide coatings are processes that can retard U transport in environments. In aged U-contaminated geologic materials, the transport and the biological availability of U toward reduction may be limited by coprecipitation with Fe-oxide minerals. These processes also affect the biological availability of U(VI) species toward reduction and precipitation as the less soluble U(IV) species by metal-reducing bacteria.To examine the dynamics of interactions between U(VI) and Fe oxides during crystallization, Fe-oxide phases (containing 0.5 to 5.4 mol% U/(U + Fe)) were synthesized by means of solutions of U(VI) and Fe(III). Wet chemical (digestions and chemical extractions) and spectroscopic techniques were used to characterize the synthesized Fe oxide coprecipitates after rinsing in deionized water. Leaching the high mol% U solids with concentrated carbonate solution (for sorbed and solid-phase U(VI) species) typically removed most of the U, leaving, on average, about 0.6 mol% U. Oxalate leaching of solids with low mol% U contents (about 1 mol% U or less) indicated that almost all of the Fe in these solids was crystalline and that most of the U was associated with these crystalline Fe oxides. X-ray diffraction and Fourier-transform infrared (FT-IR) spectroscopic studies indicate that hematite formation is preferred over that of goethite when the amount of U in the Fe-oxides exceeds 1 mol% U (∼4 wt% U). FT-IR and room temperature continuous wave luminescence spectroscopic studies with unleached U/Fe solids indicate a relationship between the mol% U in the Fe oxide and the intensity or existence of the spectra features that can be assigned to UO₂²⁺ species (such as the IR asymmetric υ₃ stretch for O = U = O for uranyl). These spectral features were undetectable in carbonate- or oxalate-leached solids, suggesting solid phase and sorbed U(VI)O₂²⁺ species are extracted by the leach solutions. Uranium L₃-edge x-ray absorption spectroscopic (XAFS) analyses of the unleached U-Fe oxide solids with less than 1 mol% U reveal that U(VI) exists with four O atoms at radial distances of 2.19 and 2.36 Å and second shell Fe at a radial distance at 3.19 Å.Because of the large ionic radius of UO₂²⁺ (∼1.8 Å) relative to that of Fe³⁺ (0.65 Å), the UO₂²⁺ ion is unlikely to be incorporated in the place of Fe in Fe(III)-oxide structures. Solid-phase U(VI) can exist as the uranyl [U(VI)O₂²⁺] species with two axial U-O double bonds and four or more equatorial U-O bonds or as the uranate species (such as γ-UO₃) without axial U-O bonds. Our findings indicate U⁶⁺ (with ionic radii of 0.72 to 0.8 Å, depending on the coordination environment) is incorporated in the Fe oxides as uranate (without axial O atoms) until a point of saturation is reached. Beyond this excess in U concentration, precipitating U(VI) forms discrete crystalline uranyl phases that resemble the uranyl oxide hydrate schoepite [UO₂(OH)₂·2H₂O]. Molecular modeling studies reveal that U⁶⁺ species could bond with O atoms from distorted Fe octahedra in the hematite structure with an environment that is consistent with the results of the XAFS. The results provide compelling evidence of U incorporation within the hematite structure.  相似文献   

Oxydation expérimentale de Fe-tourmalines et corrélation avec une déprotonation des groupes hydroxyleAnnealing in oxidising conditions of Fe-tourmalines and correlated deprotonation of OH groups     

Yves Fuchs  Martine Lagache  Jorge Linares 《Comptes Rendus Geoscience》2002,334(4):245-249

Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O₂)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe²⁺ into Fe³⁺ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe²⁺ into Fe³⁺ is charge-balanced by deprotonation of the external OH₍₃₎ groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249.  相似文献   

Adsorption of REE(III)-humate complexes onto MnO₂: Experimental evidence for cerium anomaly and lanthanide tetrad effect suppression     

Mélanie Davranche  Olivier Pourret  Gérard Gruau  Aline Dia  Martine Le Coz-Bouhnik 《Geochimica et cosmochimica acta》2005,69(20):4825-4835

Experiments were conducted to evaluate the impact of organic complexation on the development of Ce anomalies and the lanthanide tetrad effect during the adsorption of rare-earth elements (REE) onto MnO₂. Two types of aqueous solutions—NaCl and NaNO₃—were tested at pH 5 and 7.5. Time-series experiments indicate that a steady-state is reached within less than 10 h when REE occur as free inorganic species, whereas steady state is not reached before 10 d when REE occur as REE-humate complexes. The distribution coefficients (K_d^REE) between suspended MnO₂ and solution show no or only very weak positive Ce anomaly or lanthanide tetrad effect when REE occur as humate complexes, unlike the results obtained in experiments with REE occurring as free inorganic species. Monitoring of dissolved organic carbon (DOC) concentrations show that log K_d^REE_organic/K_d^DOC ratios are close to 1.0, implying that the REE and humate remain bound to each other upon adsorption. Most likely, the Ce anomaly reduction/suppression in the organic experiments arises from a combination of two processes: (i) inability of MnO₂ to oxidize Ce(III) because of shielding of MnO₂ surfaces by humate molecules and (ii) Ce(IV) cannot be preferentially removed from solution due to quantitative complexation of the REE by organic matter. We suggest that the lack of lanthanide tetrad effect arises because the adsorption of REE-humate complexes onto MnO₂ occurs dominantly via the humate side of the complexes (anionic adsorption), thereby preventing expression of the differences in Racah parameters for 4f electron repulsion between REE and the oxide surface. The results presented here explain why, despite the development of strongly oxidizing conditions and the presence of MnO₂ in the aquifer, no (or insignificant) negative Ce anomalies are observed in organic-rich waters. The present study demonstrates experimentally that the Ce anomaly cannot be used as a reliable proxy of redox conditions in organic-rich waters or in precipitates formed at equilibrium with organic-rich waters.  相似文献   

Steroid and triterpenoid distributions in bransfield strait sediments: Hydrothermally-enhanced diagenetic transformations     

Martine Brault  Bernd R.T. Simoneit 《Organic Geochemistry》1988,13(4-6)

Recent sediments from Bransfield Strait, Antarctica have been analyzed for triterpenoid and steroid hydrocarbons, sterols and steroid ketones to consider the effects of hydrothermal fluids on the sedimentary organic matter. The steroid distributions in unaltered and altered sediments are controlled more by inputs from source organisms than by the effects of hydrothermal activity, which is suggested to be limited to low temperature alteration. Nevertheless, chemical reactions occurred in altered sediments and include dehydration of sterols to sterenes, isomerization of triterpenes and sterenes, rearrangement of sterenes to diasterenes and reductive processes leading to generation of phytane from phytol via phytenes.  相似文献   

The geoid: From geodesy to geophysics and from geophysics to geodesy     

Martine Amalvict  Joaquim Boavida 《Surveys in Geophysics》1993,14(4-5):477-494

The word geoid appeared for the first time in 1873 in a work by Listing, at a time when an increasing number of measurements of meridian arcs were made, in order to determine the figure of the Earth.From that time, the mathematical methods (least squares, inverse methods ...) and the observation and modelling methods (collecting data, precision ...) have made concurrently great progress. Owing to these advances, the geometric method first, and the dynamic method next were developed by geodesy for the computation of the geoid. In particular, the increasing of data brought by satellites since the 60's led to a detailed knowledge of the geoid.The determination of the geoid is, for geodesy, a goal in itself. The geophysical viewpoint is to study the inner structure and the internal dynamics of the Earth, by the interpretation of the shape of the geoid and its anomalies. The two approaches are complementary to one another and react one on the other: from geodesy to geophysics and from geophysics to geodesy. The geoid has three advantages that can be stated in a few words each, although the third advantage brings in a complex subject. They are: first, the advantage of thinking in terms of small numbers; second, the fact that we know or can know directly the form of the geoid as a physical reality over much of the earth's surface; third, the geophysical implications of a knowledge of the geoid. Walter D. Lambert, 1961  相似文献   

Depth versus (age)^1/2: A perspective on mid-ocean rises     

Anne Martine Tréhu 《Earth and Planetary Science Letters》1975,27(2):287-304

The straight-line relationship between depth and the square root of age predicted by recent variations of the thermal contraction model for ocean rise elevation is confirmed to an age of 80 m.y.We then examine this relationship in the immediate vicinity of the rise crest in an attempt to determine the sensitivity of the slopes thus obtained. Depth versus t^1/2 profiles from a variety of rise types ranging from the topographically smooth, fast-spreading Pacific-Antarctic rise to the rough, slow-spreading Mid-Atlantic rise are discussed, ages having been assigned using a finite rotation pole. Because of the variety of superimposed anomalous features concentrated within a limited and well-surveyed region, the Galapagos Spreading Center has provided a suitable arena for determining the precision with which the method can decompose such an agglomeration into distinctly recognizable components. Although topographic “noise” precludes precise quantification of the slopes, it is concluded that, by removing the first-order effect of thermal contraction, the method can be quite revealing when topography is examined in relation to other data. Slopes for several profiles across the Pacific-Antarctic and Pacific-Nazca rises reveal the pattern expected in the case of asymmetric spreading, a conclusion which has independently been derived from the magnetic anomalies. In the Galapagos region “jumps” of the spreading center, a basic compositional difference, and uplift from below are exposed by their predictable effect on the slopes obtained from the depth versus t^1/2 plots.  相似文献   

Determination of the Earth rotation parameters by the Bureau International de l'Heure, 1962–1979     

Feissel  Martine 《Journal of Geodesy》1980,54(1):81-102

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Relating remotely sensed forest damage data to wind data: storms Lothar (1999) and Vivian (1990) in Switzerland     

Tilo Usbeck  Peter Waldner  Matthias Dobbertin  Christian Ginzler  Christian Hoffmann  Flurin Sutter  Charlotte Steinmeier  Richard Volz  Gustav Schneiter  Martine Rebetez 《Theoretical and Applied Climatology》2012,108(3-4):451-462

This study compares the surface wind speed and forest damage data of two exceptionally severe winter storms, Vivian 1990 and Lothar 1999. The study area comprises the region that suffered damage in Switzerland. The wind speed data were derived from simulations of MeteoSwiss (Federal Office of Meteorology and Climatology), measurements during the storm periods and expert analyses of the data. The remotely sensed forest damage data were provided by the Federal Office for the Environment and the forest cover data by Swiss Federal Statistical Office. We compared data on the peak gust and maximum average wind speed, with data on the spatially related forest area and forest damage area, and found some clear differences in the correlations between the different wind data and forest damage. Our results point generally to the damage-causing role of near-surface gusts at maximum wind speeds during the storm. These tended to be spatially distributed on a fine scale. In only a few cases were the results statistically significant. However, these results could probably be improved with better wind data. For example, gust measurements spatially closer to forests or simulations of gusts at maximum wind speed could be produced with a spatially higher resolution.  相似文献