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1.
A method for the determination of barium in sea water was investigated using inductively coupled plasma emission spectrometry, and sea water samples from the Japan Sea and the Pacific Ocean were directly analyzed by this method. Artificial sea water was used to prepare matrix matched standard solutions to overcome the problem of physical interference. The detection limit (signal/noise ratio=2) for barium in deionized and distilled water was 0.08µg l?1 and in sea water, 0.12µg l?1. The reproducibilities in the purified water and in the sea water at the 10µg l?1 level were 0.7% a#FFFFFFnd 0.5%, respectively. The barium concentration in both the Japan Sea and the Pacific Ocean increased with depth and ranged between 5.5–10.0µg l?1 and 4.1–18.4µg l?1, respectively.  相似文献   
2.
Near inertial motion excited by wind change in a margin of the Typhoon 9019   总被引:1,自引:0,他引:1  
An excitation of inertial oscillation in the upper layer east of course of Typhoon 9019 was fortuitously observed at three surface buoys deployed during the Ocean Mixed Layer Experiment (OMLET). The observed inertial oscillation was compared with wind fluctuation measured at Ocean Weather Station T (29°N, 135°E) which was placed at the center of a triangle with three vertexes occupied by the respective surface buoys. Inertial oscillation is effectively excited in the mixed layer at the eastern margin of the typhoon by a rapid decrease of wind rather than by prevailing strong wind. It is shown by means of a least square deviation that the inertial oscillation observed in the mixed layer has a period of 23.9 hours shorter than the local inertial period of 24.7 hours. This shorter period suggests that the inertial oscillation has the finite velocities of phase and group as an inertial internal wave. A theoretically obtained ratio of vertical component of group velocity to that of phase velocity, approximately agrees with observed value. The inertial internal wave is excited by fluctuation of divergence with near inertial period in the mixed layer.  相似文献   
3.
We carried out observations of sea-level fluctuations simultaneously at three stations on the coast of Heda Bay, Honshu, Japan, using supersonic-type water level gauges controlled by a personal computer. Analyses of the obtained data showed predominant spectral peaks at periods of 7.6, 2.0 and 1.3 minutes for all three stations. Comparison of the observed data with numerically calculated normal oscillation modes of the bay indicates that these three spectral peaks correspond to the theoretical first, third and seventh normal modes of the basin respectively, judging from the results of cross-spectral analyses. The reason for the absence of the remaining normal modes, especially of the second or the lateral first mode of the basin, is briefly considered.  相似文献   
4.
Very few studies have conducted long-term observations of methane (CH4) flux over forest canopies. In this study, we continuously measured CH4 fluxes over an evergreen coniferous (Japanese cypress) forest canopy throughout 1?year, using a micrometeorological relaxed eddy accumulation (REA) system with tuneable diode laser spectroscopy (TDLS) detection. The Japanese cypress forest, which is a common forest type in warm-temperate Asian monsoon regions with a wet summer, switched seasonally between a sink and source of CH4 probably because of competition by methanogens and methanotrophs, which are both influenced by soil conditions (e.g., soil temperature and soil moisture). At hourly to daily timescales, the CH4 fluxes were sensitive to rainfall, probably because CH4 emission increased and/or absorption decreased during and after rainfall. The observed canopy-scale fluxes showed complex behaviours beyond those expected from previous plot-scale measurements and the CH4 fluxes changed from sink to source and vice versa.  相似文献   
5.
We used time-series sediment trap data for four major components, organic matter and ballast minerals (CaCO3, opal, and lithogenic matter) from 150, 540, and 1000 m in the western subarctic Pacific (WSAP), where opal is the predominant mineral in sinking particles, to develop four simple models for settling particles, including the “ballast model”. The ballast model is based on the concept that most of the organic matter “rain” in the deep sea is carried by the minerals. These four models are designed to simultaneously reproduce the flux of each major component of settling particles at 540 and 1000 m by using the data for each component at 150 m as initial values. Among the four models, the ballast model, which considers the sinking velocity increase with depth, was identified as the best using the Akaike information criterion as a measure of the model fit to data. This model successfully reproduced the flux of organic matter at 540 and 1000 m, indicating that the ballast model concept works well in the shallow zone of the WSAP on a seasonal timescale. This also suggests that ballast minerals not only physically protect the organic matter from degradation during the settling process but also enhance the sinking velocity and reduce the degree of decomposition.  相似文献   
6.
Absorption of photosynthetically active radiation (PAR) by vegetation was observed in two burned black spruce forests, one and seven years after wildfire, in interior Alaska along with several vegetation properties. This study considered PAR absorption by mosses by examining the relationship between PAR transmittance and fractional coverage of green vegetation. Our results suggest that mosses absorbed a considerable fraction of incoming PAR in the burned forests, which cannot be neglected in evaluating the fraction of absorbed PAR (FPAR). The relationships between FPAR and vegetation indices revealed that enhanced vegetation index (EVI) may be suitable for expressing the spatial and temporal variation of FPAR, regardless of stand age after wildfire. The comparison between the observed in situ FPAR and FPAR derived from Moderate Resolution Imaging Spectroradiometer (MODIS FPAR) clearly showed that MODIS FPAR was highly overestimated. The most likely reason for the overestimation was identified as misclassification of land cover type. The current regional estimation of photosynthesis in boreal region based on the light-use efficiency approach and MODIS FPAR is probably overestimated, and an accurate distribution of FPAR is desired for clarifying the regional carbon exchange in boreal forests.  相似文献   
7.
The flux–gradient relationships in the unstable roughness sublayer (RSL) over an open canopy of black spruce forest were examined using long-term observations from an instrumented tower. The observed gradients normalised with the surface fluxes and height above the zero-plane displacement showed differences from a universal function established in the surface layer. The magnitude of differences was not constant throughout the year even at the same observation height. Also the magnitude of the differences was different for each scalar, and scalar similarity in the context of the flux–gradient relationship did not always hold. The variation of the differences was explained by the relative contribution of overstorey vegetation to the total flux from the entire ecosystem. This suggests that a mismatch of the vertical source/sink distributions between scalars leads to a different strength of the near-field dispersion effect for each scalar, and this resulted in inequality of eddy diffusivity among scalars in the RSL. An empirical method that predicts the magnitude of differences is proposed. With this method, it is possible to estimate the eddy diffusivity of scalars provided that the relative contribution of overstorey vegetation to the total flux from the ecosystem is known. Also this method can be used to estimate the eddy diffusivity for scalars whose primary sources are at ground level, such as methane and nitrous oxide.  相似文献   
8.
We have measured inorganic nitrogen (IN) content and the isotope ratio of IN (δ15NIN) in a sediment core covering the last 145 kyr in the western subarctic Pacific (WSAP). IN content was generally high during glacial periods and shows positive correlations with both eolian dust content and the ratio of organic carbon (C) to organic nitrogen (ON) (C/ON) found in our previous studies. This means that IN was transported from continental areas to the WSAP together with eolian dust and that the IN was not contaminated by volcanic materials, because the eolian dust content was reconstructed using metal components to remove contaminating volcanic materials. Therefore, IN content in the WSAP sediments, the clay fraction of which is not greatly affected by drift deposits seen at the other sites in this region, may potentially be an effective proxy for eolian dust, without the need to consider contamination by volcanic materials. δ15NIN was generally low during glacial periods and shows negative correlations with IN, eolian dust, and C/ON. The possible causes of the observed variations in δ15NIN are as follows: (1) authigenic fixation of NH4 + in water-column and pore water of sea-floor sediments to clay minerals; (2) contamination of measured IN by highly resistant organic matter; or (3) variations in the continental source region of the eolian dust supplied to the WSAP and climatically induced changes in δ15N of soil organic matter there. The last mechanism shows the potential for δ15NIN to be used as a proxy for climate change on land, and is consistent with other published explanations of the spatial distribution of δ15NIN in modern sea-floor sediments.  相似文献   
9.
Abstract Dolomite marble from the Kumdy–Kol area of the Kokchetav Massif contains abundant microdiamond, mainly in garnet and a few in diopside. The mineral assemblage at peak metamorphic condition consists of dolomite + diopside + garnet (+ aragonite) ± diamond. Inclusions of very low MgCO3 calcite and almost pure calcite occur in diopside and are interpreted as aragonite and/or aragonite + dolomite. Single-phase Mg–calcite in diopside with a very high MgCO3 component (up to 21.7 mol%) was also found in diamond-free dolomitic marble, and is interpreted as a retrograde product from aragonite + dolomite to Mg–calcite. The dolomite stability constrains the maximum pressure (P) at < 7 GPa using previous experimental data, whereas the occurrence of diamond yields the minimum peak pressure–temperature (P–T) condition at 4.2 GPa and 980 °C at X co 2 = 0.1. The highest MgCO3 in Mg–calcite constrains the minimum P–T condition higher than 2.5 GPa and 800 °C for the exhumation stage. As these marbles were subjected to nearly identical P–T metamorphic conditions, the appearance of diamond in some carbonate rocks was explained by high X co 2. A low X co 2 condition refers to high oxidized conditions and diamond (and/or graphite) becomes unstable. Difference in X co 2 for marble from the same area suggests local heterogeneity of fluid compositions during ultrahigh-pressure metamorphism.  相似文献   
10.
Precise polarization measurements in the vacuum ultraviolet (VUV) region are expected to be a new tool for inferring the magnetic fields in the upper atmosphere of the Sun. High-reflectivity coatings are key elements to achieving high-throughput optics for precise polarization measurements. We fabricated three types of high-reflectivity coatings for a solar spectropolarimeter in the hydrogen Lyman-\(\upalpha \) (Ly\(\upalpha \); 121.567 nm) region and evaluated their performance. The first high-reflectivity mirror coating offers a reflectivity of more than 80 % in Ly\(\upalpha \) optics. The second is a reflective narrow-band filter coating that has a peak reflectivity of 57 % in Ly\(\upalpha \), whereas its reflectivity in the visible light range is lower than 1/10 of the peak reflectivity (\(\sim 5~\%\) on average). This coating can be used to easily realize a visible light rejection system, which is indispensable for a solar telescope, while maintaining high throughput in the Ly\(\upalpha \) line. The third is a high-efficiency reflective polarizing coating that almost exclusively reflects an s-polarized beam at its Brewster angle of 68° with a reflectivity of 55 %. This coating achieves both high polarizing power and high throughput. These coatings contributed to the high-throughput solar VUV spectropolarimeter called the Chromospheric Lyman-Alpha SpectroPolarimeter (CLASP), which was launched on 3 September, 2015.  相似文献   
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