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1.
Fluoro-sodalite was synthesized for the first time at temperatures of 400–800°C and H2O pressures of 1–2 kbar in the Si–Al–Na–H–O–F system. X-ray diffraction and infrared spectroscopic investigations showed that fluorine is incorporated in the sodalite structure as anionic octahedral groups, [AlF6]3–, the number of which can vary from 0 to 1. Correspondingly, the end-members of the F-sodalite series are Na7(H2O)8[Si5Al7O24] and Na8(AlF6)(H2O)4[Si7Al5O24]. Depending on the composition of the system, F-sodalite associates at 500–650°C with nepheline, albite, cryolite, and villiaumite, which are joined by analcime below 500°C and aluminosilicate melt above 650°C. Fluorine-bearing sulfate–chlorine-sodalite was found for the first time in a pegmatite sample from the Lovozero massif. The highest fraction of the fluorine end-member in natural sodalite is 0.2. The incorporation of F into the sodalite structure requires much more energy compared with Cl and SO 4 2- , because it is accompanied by a structural rearrangement and a transition from tetrahedral Al to octahedral Al.  相似文献   
2.
The rock bream, Oplegnathus fasciatus, is a common rocky reef game fish in East Asia and recently has become an aquaculture species. Despite its commercial importance, the population genetic structure of this fish species remains poorly understood. In this study, 163 specimens were collected from 6 localities along the coastal waters of Korea and China and their genetic variation was analyzed with mtDNA COI sequences. A total of 34 polymorphic sites were detected which determined 30 haplotypes. The genetic pattern reveals a low level of nucleotide diversity (0.04 ± 0.003) but a high level of haplotype diversity (0.83 ± 0.02). The 30 haplotypes are divided into two major genealogical clades: one that consists of only Zhoushan (ZS, East China Sea) specific haplotypes from the southern East China Sea and the other that consists of the remaining haplotypes from the northern East China Sea, Yellow Sea, Korea Strait, and East Sea/Sea of Japan. The two clades are separated by approximately 330~435 kyBP. Analyses of AMOVA and Fst show a significant population differentiation between the ZS sample and the other ones, corroborating separation of the two genealogical clades. Larval dispersal and the fresh Yangtze River plume are invoked as the main determining factors for this population genetic structure of O. fasciatus. Neutrality tests and mismatch distribution analyses indicate late Pleistocene population expansion along the coastal waters of Korea and China approximately 133–183 kyBP during which there were periodic cycles of glaciations and deglaciations. Such population information needs to be taken into account when stock enhancement and conservation measures are implemented for this fisheries species.  相似文献   
3.
Heejun Suk 《Ground water》2016,54(4):508-520
MT3DMS, a modular three‐dimensional multispecies transport model, has long been a popular model in the groundwater field for simulating solute transport in the saturated zone. However, the method of characteristics (MOC), modified MOC (MMOC), and hybrid MOC (HMOC) included in MT3DMS did not treat Cauchy boundary conditions in a straightforward or rigorous manner, from a mathematical point of view. The MOC, MMOC, and HMOC regard the Cauchy boundary as a source condition. For the source, MOC, MMOC, and HMOC calculate the Lagrangian concentration by setting it equal to the cell concentration at an old time level. However, the above calculation is an approximate method because it does not involve backward tracking in MMOC and HMOC or allow performing forward tracking at the source cell in MOC. To circumvent this problem, a new scheme is proposed that avoids direct calculation of the Lagrangian concentration on the Cauchy boundary. The proposed method combines the numerical formulations of two different schemes, the finite element method (FEM) and the Eulerian–Lagrangian method (ELM), into one global matrix equation. This study demonstrates the limitation of all MT3DMS schemes, including MOC, MMOC, HMOC, and a third‐order total‐variation‐diminishing (TVD) scheme under Cauchy boundary conditions. By contrast, the proposed method always shows good agreement with the exact solution, regardless of the flow conditions. Finally, the successful application of the proposed method sheds light on the possible flexibility and capability of the MT3DMS to deal with the mass transport problems of all flow regimes.  相似文献   
4.
This study presents the correlations between quantified shape parameters and geotechnical properties for nine sand specimens. Four shape parameters, sphericity, convexity, elongation and slenderness, were quantified with two-dimensional microscopic images with the aid of image processing techniques. An instrumented oedometer cell is used to measure compressibility, thermal conductivity and shear wave velocity during loading, unloading and reloading stages. As the particle shape inherently determines the initial loose packing condition, initial void ratio and shape parameters are well correlated with compressibility. The applied stress in soils increases the interparticle contact area and contact quality; round particles tend to achieve higher thermal conductivity and shear wave velocity during stress-induced volume change. Multiple linear regression is implemented to capture the relative contributions of involved variables, revealing that the thermal evolution is governed by the initial packing density and particle shape. The experimental observations underscore the predominant effect that particle shape has on the geomechanical and physical properties upon stress-induced soil behavior.  相似文献   
5.
利用宽频带流动台站(YSBSN)记录的远震波形数据和远震接收函数方法,反演了黄海东、西两侧地壳上地幔的S波速度结构.结果表明,莫霍面深度在30~38 km之间变化,位于中方一侧的JNN台下方地壳厚度最大,可以归因于华北板块和扬子板块的碰撞;韩方一侧的地壳厚度自北向南逐渐变厚,但仍然难以厘定朝鲜半岛南部潜在碰撞带的位置,这些问题的解决需要更大范围的流动台站观测.由于部分台站位于巨厚的沉积层和多孔的火山岩之上,与浅部构造的相关性使得接收函数表现出较大振幅的混响,从而影响了来自深部结构的转换震相.  相似文献   
6.
We identified a total of 101 species and two subspecies of radiolarians belonging to 56 genera from 95 samples collected from the Hagjeon and Duho Formations in the Pohang Basin of the southeastern Korean Peninsula. On the basis of the biostratigraphic range of Cyrtocapsella cornuta and Theocorys redondoensis, the depositional period of the upper Hagjeon and lowest Duho Formations was determined to be early to late Middle Miocene. The occurrence of deep-dwelling radiolarians indicates that the paleobathymetry seems to become gradually progressing toward an upper bathyal environment in the middle part of the Hagjeon Formation. However, we prefer to accept another interpretation for the occurrence of deep-sea indicators in the Hagjeon and the lowest part of the Duho Formations, and consider the presence of a region of upwelling cold water that might have simulated a deep-water environment in relatively shallow water. This interpretation is based on the present upwelling of a cold-water mass off the southeast coast of Korea, the occurrence of upwelling microfossils from the Pohang Basin, and the effect of the closing of the Korea Strait approximately 15 Ma. We also considered that the uppermost part of the studied section represents a shallow-water environment.  相似文献   
7.
Climate change has the potential to increase the challenge of preventing and controlling outbreaks of infectious diseases. An adaptation assessment is an important aspect of designing and implementing policies and measures to avoid, prepare for, and effectively respond to infectious diseases outbreaks. The main steps in conducting an adaptation assessment include: 1) evaluating the effectiveness of policies and measures that address the burden of climate-sensitive infectious diseases; 2) identifying options to manage the health risks of current and projected climate change; 3) evaluating and prioritizing the options; 4) identifying human and financial resources needs, and possible barriers, constraints, and limits to implementation; and 5) developing monitoring and evaluation programs to ensure continued effectiveness of policies and measures in a changing climate. Optimally, relevant stakeholders are optimally included throughout the adaptation assessment. Although the process of conducting an assessment is similar across nations and regions, the context and content will vary depending on local circumstances, socioeconomic conditions, legal and regulatory frameworks, and other factors. The European Centers for Disease Prevention and Control developed guidelines for conducting assessments, with sufficient consistency to facilitate learning lessons across assessments.  相似文献   
8.
This paper presents a computational microstructure model to estimate the progressive moisture damage of multiphase asphaltic paving mixtures. Moisture damage because of water transport is incorporated with mechanical loading through a finite element method. To simulate nonlinear damage evolution in the mixtures, the model includes Fickian moisture diffusion, a cohesive zone model to simulate the gradual fracture process, and a degradation characteristic function to represent the reduction of material properties because of moisture infiltration. With the model developed, various parametric analyses are conducted to investigate how each model parameter affects the material‐specific moisture damage mechanism and damage resistance potential of the mixtures. Analysis results clearly demonstrate the significance of physical and mechanical properties of mixture components and geometric characteristics of microstructure for the better design of asphaltic paving mixtures and roadway structures. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
9.
We studied loparite-containing rocks (lujaurites, juvites, foyaite-juvites, etc.) sampled from a complex of differentiated rocks and, partly, from a complex of eudialytic lujaurites of the Lovozero alkaline massif. Zoned crystals of loparite (the zoning is due to variations in Ti, Nb, REE, Sr, and Th contents) were examined by microprobing. We also carried out experimental studies of loparite formation in complex silicate–salt systems including sodium carbonate, chloride, fluoride, or sulfate at 400–1200 °C and 1–2 kbar. They show that the composition of loparites depends on the physicochemical conditions of their formation (fluid composition) and that natural loparite can crystallize in a wide range of temperatures. The produced loparite crystals are zoned as a result of variations in Ti, Nb, La, Ce, Y, Ca, and Sr contents, which is probably related to the kinetic specifics of crystallization. Their zoning is similar to that of loparites of the Lovozero massif.  相似文献   
10.
The investigation of abyssal bedforms and sediment drifts as a tool for understanding the deep flow characteristics allows us to interprete that a benthic storm is primarily related to sediment distribution, development of longitudinal ripple marks, and concentration of suspended particulate matter. There explicitly exists a strong and periodical bottom flow which is called the benthic storm having a current speed of over 15 cm sec?1 and duration of more than two days. Hydrodynamic regime has been thought to affect underlying sediment textural natures which can be used to distinguish between bottom currents with different velocities. Therefore, concentration of medium silt mode (0.010–0.017 mm in size) delineates a high-velocity core of the benthic storm in the deep sea bottom. Bottom current measurements in most of the North Pacific Ocean indicate that present bottom current speeds are generally less than 10 cm sec?1. It appears likely, therefore, that significant erosion is not taking place today. However, at current passages, bases of sea mounts, and other topographic obstructions locally accelerated current flows are recognized to affect bottom configuration. While, it is concluded from bottom echo-characteristics and bottom current measurements that widespread occurrences of echo type 3 (sediment-drift deposit facies) recognized at 22°N and 42°N in the Northwest Pacific are associated with the North Equatorial current and the North Pacific current respectively, and can best be interpreted to be originated from benthic storms, the source of which were come from those surface currents.  相似文献   
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