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Research interest in speciation of arsenic stems from its species dependent behavior in the environment and in living organisms. The complexity of the matrix to be analyzed and low concentrations of target arsenic species that may be labile or difficult to chromatogram, indicate that a suitable pre‐treatment methodology is required. This study investigated the usefulness of chelation solvent extraction – high performance liquid chromatography (CSE‐HPLC) for the speciation of arsenic in water. It involved reacting arsenic with the chelant known for its affinity towards arsenic, followed by extraction, separation, and identification of the arsenic‐chelant‐arsenic complex. Arsenic species having different physicochemical properties were investigated. Species, such as, As2O3, As3O5, KH2AsO4, Na2HAsO4, and NaAsO2 were detected as a group of closely eluted peaks with different retention times and spectral properties, whereas, the organic arsenic species CH3Na2AsO3, o‐arsanilic acid, roxarson and triphenyl arsine separated quite well on the EnviroseP‐CM HPLC column. Key method parameters, such as, type of HPLC column, composition of mobile phase and organic solvents affecting peak resolution and sensitivity were optimized. Real environmental matrices contaminated with arsenic were analyzed under varying wavelengths (λmax = 190, 210, 220, 234, 244, and 282 nm), with good precision. Different arsenic species were detected in these samples with excellent background and signal‐to‐noise ratios demonstrating the robustness of the method. The detection limit, reproducibility, selectivity, accuracy, and dynamic range of the calibration curves were evaluated.  相似文献   
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Stock assessments based on fitting sex‐and size‐structured population dynamics models, combined with projections of the future implications for available biomass and egg production, currently form the basis for scientific management advice for rock lobster, Jasus edwardsii, off Victoria, Australia. Traditionally, assessments have been conducted for two “zones” (east and west) off Victoria. However, recent analyses indicate finer‐scale spatial resolution in growth and the probability of being mature as a function of size. Assessments were therefore conducted for six regions, as well as for the two conventional zones, and Bayesian model selection criteria were used to compare alternative model formulations. The results suggest that better fits to the data can be obtained by conducting assessments by region than by zone. The general qualitative conclusion of past stock assessments is that the rock lobster populations off Victoria are depleted to below the target reference point of 40% of the available biomass in 1951 and this conclusion is robust to how the data are treated spatially. However, the time‐trajectories of egg production and available biomass differ among the regions, with the areas in the centre of Victoria being more depleted than those at the extremes.  相似文献   
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Since 2002, 5.3% of the Victorian coastal waters have been declared as Marine Protected Areas (MPAs). These are aimed at safeguarding important marine habitats and species, significant natural features, and areas of cultural heritage and aesthetic value. However, MPAs impact the fishery for southern rock lobster (Jasus edwardsii), as total allowable catches (TACs) were previously set to allow the biomass to recover to pre‐specified target levels. The model on which assessments and risk analyses are based is extended to include the impact of MPAs. The MPAs and the area open to fishing are modelled as subpopulations with different levels of mortality and consequently different density and population size‐structure. A range for the probability of a lobster moving from a MPA to the fished area from 0 to 15% is considered, based on the results of tagging studies. The reduction of biomass available to the commercial fishery because of the introduction of MPAs is estimated to be 8% and 16% (Western and Eastern Zones) respectively. The results of a risk assessment show that if the current TACs are maintained, the time to increase the biomass available to the commercial fishery by 50% would be delayed 5–9 years in the Western Zone and 1–4 years in the Eastern Zone because of the impact of displaced effort. In contrast, spawning biomass in the Eastern Zone is currently below the agreed limit reference point, and the introduction of MPAs would enhance the rate of recovery, although only marginally initially, faster than the absence of the MPAs.  相似文献   
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The Australian Victorian Western Zone rock lobster fishery is assessed using standardised catch-per-unit-effort (CPUE). Nominal CPUE declined over 1978–2009, but this underrepresents the estimated decline in abundance, and since 2009 standardised CPUE rose notably less than nominal CPUE. This study identified vessel as a key factor that explains the discrepancy between nominal and standardised CPUE. The composition of the fleet changed since 2009, under the pressure of constraining total allowable catch quotas, with vessels exiting the fishery having substantially lower estimated catchability, which increased the average catchability of the remaining fleet. New diagnostic indices were constructed to quantify discrepancies between trends in nominal and standardised CPUE that assisted in identifying periods during which both catchability and fleet composition changed.  相似文献   
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The management strategy evaluation (MSE) approach was used to evaluate management strategies based on the current method of stock assessment for rock lobster (Jasus edwardsii) off Victoria, Australia, and decision rules inferred from the management plan for Victorian rock lobster and past practice when selecting total allowable catches, TACs. The results are expressed in terms of whether it is possible to keep stocks above limit reference points with high probability and recover over‐exploited stocks to the target level. Three categories of management strategy were examined using the MSE, which differed in whether assessments were conducted, and TACs set, by management zone or by region within management zone. A management strategy based on conducting assessments and setting TACs by management zone is most similar to the way assessments are currently conducted and management regulations implemented for rock lobster off Victoria. However, this management strategy performed poorest in recovering stocks to target levels. Alternative management strategies which involved conducting assessments and setting TACs by region performed better, but may have practical limitations. The assessment method was found to be generally relatively accurate and precise, although estimation performance was poor/imprecise on occasion.  相似文献   
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