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1.
Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.  相似文献   
2.
Some species of sulphate‐reducing bacteria (SRB) are known to mediate the formation of dolomite and Mg‐calcite. However, their exact role in the mineralization process remains elusive. Here, we present the result of a laboratory experiment that was designed to test whether formation of carbonate minerals by SRB can occur in the absence of living cells, through passive mineralization of their exopolymeric substances (EPS). SRB capable of mediating dolomite were cultivated in the laboratory, allowing them to secrete EPS. Microbial activity within the cultures was subsequently inhibited with antibiotics. Only after this step, Ca2+ and Mg2+ were added to the solution and carbonate minerals could form. Mg‐calcite and disordered Ca‐dolomite precipitated in association with EPS. The mol.% of Mg2+ in the crystals increased with longer incubation times. This result demonstrates that organic compounds produced by SRB can mediate the formation of Ca‐Mg carbonates in the absence of an active metabolism.  相似文献   
3.
This paper resolves the origin of clay hummock micro-topography in seasonal wetlands of the Drakensberg Foothills, providing a review and appraisal of previously-suggested mechanisms of hummock formation in the context of new field and laboratory data. Field surveys revealed neo-formation of clay hummocks in a river channel that had been abandoned in c.1984. Fresh earthworm castings were located atop hummocks protruding from inundated abandoned channel margins. Earthworm castings, and sediment cores taken in hummocks and adjacent hollows, were analysed for soil-adsorbed carbon and nitrogen using an HCN analyser, and for 210Pb activity using alpha-geochronology. 210Pb activity profiles suggest relative enrichment of the isotope in hummocks, and relative depletion in adjacent hollows. Earthworm castings are characterised by very high 210Pb activity, as well as high C and N contents. Hummocks have significantly higher C and N contents than adjacent hollows. Results suggest that it is the foraging activity of earthworms in litter-rich seasonal wetland hollows, and repeated excretion of castings atop adjacent hummocks, that is responsible for the elemental enrichment observed. The paper presents a conceptual model of hummock formation in wetlands through interactions between hydrogeomorphology and earthworm activity, and illustrates a mechanism of biogeomorphic inheritance through which ordered patterns of preferential flow can emerge in ecosystems. Further implications of hummock formation and nodal accumulation of nutrients are considered in relation to wetland resilience and regulatory ecosystem service provision.© 2018 John Wiley & Sons, Ltd.  相似文献   
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The waning stage(s) of the Tethyan ocean(s) in the Balkans are not well understood. Controversy centres on the origin and life‐span of the Cretaceous Sava Zone, which is allegedly a remnant of the last oceanic domain in the Balkan Peninsula, defining the youngest suture between Eurasia‐ and Adria‐derived plates. In order to investigate to what extent Late‐Cretaceous volcanism within the Sava Zone is consistent with this model we present new age data together with trace‐element and Sr–Nd–Pb isotope data for the Klepa basaltic lavas from the central Balkan Peninsula. Our new geochemical data show marked differences between the Cretaceous Klepa basalts (Sava Zone) and the rocks of other volcanic sequences from the Jurassic ophiolites of the Balkans. The Klepa basalts mostly have Sr–Nd–Pb isotopic and trace‐element signatures that resemble enriched within‐plate basalts substantially different from Jurassic ophiolite basalts with MORB, BAB and IAV affinities. Trace‐element modelling of the Klepa rocks indicates 2%–20% polybaric melting of a relatively homogeneously metasomatised mantle source that ranges in composition from garnet lherzolite to ilmenite+apatite bearing spinel–amphibole lherzolite. Thus, the residual mineralogy is characteristic of a continental rather than oceanic lithospheric mantle source, suggesting an intracontinental within‐plate origin for the Klepa basalts. Two alternative geodynamic models are internally consistent with our new findings: (1) if the Sava Zone represents remnants of the youngest Neotethyan Ocean, magmatism along this zone would be situated within the forearc region and triggered by ridge subduction; (2) if the Sava Zone delimits a diffuse tectonic boundary between Adria and Europe which had already collided in the Late Jurassic, the Klepa basalts together with a number of other magmatic centres represent volcanism related to transtensional tectonics.  相似文献   
8.
Iron oxide–apatite (IOA) deposits, often referred to as Kiruna-type iron ore deposits, are known to have formed from the Proterozoic to the Tertiary. They are commonly associated with calc–alkaline volcanic rocks and regional- to deposit-scale metasomatic alteration. In the Bafq District in east Central Iran, economic iron oxide–apatite deposits occur within felsic volcanic tuffs and volcanosedimentary sequences of Early Cambrian age. In order to constrain the age of formation of these ores and their relationship with the Early Cambrian magmatic event, we have determined the U–Pb apatite age for five occurrences in the Bafq District. In a 206Pb/238U vs. 207Pb/235U diagram, apatite free of or poor in inclusions of other minerals plots along the Concordia between 539 and 527 Ma with four out of five samples from one deposit clustering at the upper end of this range. For this deposit, we interpret this cluster to represent the age of apatite formation, whereas the spread towards younger ages may reflect either minor Pb loss or several events of IOA formation. Apatite with inclusions of monazite (±xenotime) yields disturbed systems with inclusions having developed after formation of the iron ore–apatite deposits, possibly as late as 130–140 Ma ago. Obtained apatite ages confirms that (IOA) and the apatite-rich rocks (apatites) of the Bafq district formed coevally with the Early Cambrian magmatic (-metasomatic) events.  相似文献   
9.
Our ability to adapt to changes in groundwater quality, arising from a changing climate and/or local pressures, is dependent on comprehension of the governing controls of spatial variation in groundwater chemistry. This paper presents results of an assessment of dominant hydro-geochemical processes controlling groundwater chemical composition, using an integrated application of hierarchical cluster analysis (HCA) and principal component analysis (PCA) of a major ion dataset of groundwater from lower Shire River valley, Malawi. The area is in the southernmost part of the western section of the East African Rift System (EARS) and has localised occurrence of saline groundwater. HCA classified samples into three main clusters (C1-C3) according to their dominant chemical composition: C1 (dominant composition: Na-Cl; median TDS: 3436 mg L−1), C2 (dominant composition: Na-HCO3; median TDS: 966 mg L−1) and C3 (dominant composition: alkali earths-HCO3; median TDS: 528 mg L−1). These clusters were in turn described by the principal components PC1, PC3 and PC2, respectively, resulting from the PCA. The results of the PCA and geochemical interpretation suggest that the spatial variation of groundwater quality in the area is influenced by the following processes: C3 samples result mainly from H2CO3 weathering of aluminosilicate minerals by percolating water supersaturated with CO2. In addition to aluminosilicate weathering, C2 samples are influenced by the processes of cation exchange of Ca2+ and Mg2+ in the water for Na+ on clay minerals, and carbonate precipitation. The increase in ionic strength of C2 samples is attributed to mixing with high TDS groundwater in proximity with C2 samples. The saline/brackish C1 groundwater results from the processes of evaporation (for samples with high water table close to the Shire marshes) and dissolution of Cl and SO4-evaporative salts followed by mineralised seep from sedimentary Karoo and Cretaceous Lupata sandstones.  相似文献   
10.
The thermal impact of several kilometre-thick magmatic underplating in the lower continental crust is studied with analytical and numerical methods. Simple analytical solutions are derived for the thermal transient in the case of an infinite depth below the underplate and also for the case of a finite depth (down to the asthenosphere). It is shown that these solutions lead to simple approximations for when the transient surface heat flow is at its maximum, what the maximum is, and for how long the transient lasts. Even though these solutions assume that the underplate is emplaced instantaneously, they are useful in the interpretation of underplating over finite time spans. A numerical scheme is suggested for the modelling of underplating that handles both short time intervals as well as long intervals. The scheme treats magmatic underplating in a mass and energy conservative manner, and it is compared against the analytical solutions. Finally, the analytical and numerical results for thermal transients are applied to a transect from the Vøring margin (NE Atlantic), with respect to various degrees of early Cenozoic magmatic intrusion. It appears that more than half of the lower crustal body (LCB) in the Vøring margin must be magmatic underplating for the vitrinite reflectance to be substantially higher than for the non-magmatic case, where the LCB is assumed to comprise Caledonian crust.  相似文献   
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