Effects on UDP glucuronosyl transferase, glutathione transferase, DT-diaphorase and glutathione reductase activities in rainbow trout liver after long-term exposure to PCB     

Lars Frlin  Sonja Blom  Malin Celander  Joachim Sturve 《Marine environmental research》1996,42(1-4)

In the present study, long-term exposure to PCB resulted in marked induction of the xenobiotic biotransformation enzymes UDP glucuronosyl transferase, glutathione transferase and DT-diaphorase (measured as menadione reductase and DCPIP reductase) in rainbow trout 15 or 20 weeks post-injection during the experimental period. The increase of the phase II enzymes were paralleled by a marked increase of the glutathione reductase activity. These results indicate that prolonged exposure to PCB results in increased production of organo-radicals.  相似文献   

Land management impacts on runoff sources in small Amazon watersheds     

Joaquín Chaves  Christopher Neill  Sonja Germer  Sérgio Gouveia Neto  Alex Krusche  Helmut Elsenbeer 《水文研究》2008,22(12):1766-1775

Forest clearing and conversion to cattle pasture in the lowland Amazon region has been linked to soil compaction and increased soil water storage, which combine to diminish soil infiltration, enhance quick lateral flows and increase the stream flow response to precipitation. Quantifying the importance of quick surficial flow in response to this land use change requires identification of water sources within catchments that contribute to stream flow. Using an end member mixing analysis approach, potential contributing sources of stream flow were evaluated during an entire rainy season in a forest and a pasture watershed drained by ephemeral‐to‐intermittent streams in the south‐western Amazon. Water yield was 17% of precipitation in the pasture and 0·8% of precipitation in the forest. During the early rainy season, throughfall, groundwater, and soil water contributed 79%, 18%, and 3%, respectively, to total forest stream flow. Over the entire rainy season, throughfall, groundwater, and shallow soil water provided 57%, 24%, and 19%, respectively, of stream flow. In the pasture watershed, overland flow dominated stream flow both in the early (67%) and late (57%) rainy season, with a mean contribution of 60% overland flow, 35% groundwater, and 5% soil water. The uncertainty associated with those estimates was studied using a Monte Carlo approach. In addition to large changes in total surface flow, marked differences were found in the proportions of total stream flow in the second half of the rainy season between the forest and pasture watershed. These results suggest that (1) there is great potential for alteration of the hydrological budgets of larger watersheds as the proportion of deforested land in the Amazon increases, and (2) as more rainfall is diverted into fast flowpaths to streams in established pastures, the potential to deliver water with higher solute concentrations generated by erosion or by bypassing sites of solute removal increases. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Vanadium and niobium behavior in rutile as a function of oxygen fugacity: evidence from natural samples   总被引：1，自引：0，他引：1  

Lei?Liu  Yilin?XiaoEmail author  Sonja?Aulbach  Dongyong?Li  Zhenhui?Hou 《Contributions to Mineralogy and Petrology》2014,167(6):1026

Vanadium occurs in multiple valence states in nature, whereas Nb is exclusively pentavalent. Both are compatible in rutile, but the relationship of V–Nb partitioning and dependence on oxygen fugacity (expressed as fO₂) has not yet been systematically investigated. We acquired trace-element concentrations on rutile grains (n = 86) in nine eclogitic samples from the Dabie-Sulu orogenic belt by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) and combined them with published results in order to assess the direct and indirect effects of oxygen fugacity on the partitioning of V and Nb into rutile. A well-defined negative correlation between Nb (7–1,200 ppm) and V concentrations (50–3,200 ppm) was found, documenting a competitive relationship in the rutile crystal that does not appear to be controlled by bulk rock or mineral compositions. Based on the published relationship of ^RtD_V and V valence with ?QFM, we suggest that the priority order of V incorporation into rutile is V⁴⁺ > V³⁺ > V⁵⁺. The inferred Nb–V competitive relationship in rutile from the Dabie-Sulu orogenic belt could be explained by decreasing fO₂ due to dehydration reactions involving loss of oxidizing fluids during continental subduction: The increased proportion of V³⁺ (expressed as V³⁺/∑V) and attendant decrease in ^RtD_V is suggested to lead to an increase in rutile lattice sites available for Nb⁵⁺. A similar effect may be observed under more oxidizing conditions. When V⁵⁺/∑V increases, ^RtD_V shows a dramatic decline and Nb concentration increases considerably. This is possibly documented by rutile in highly metasomatized and oxidized MARID-type (MARID: mica–amphibole–rutile–ilmenite–diopside) mantle xenoliths from the Kaapvaal craton, which also show a negative V–Nb covariation. In addition, their Nb/Ta covaries with V concentrations: For V concentrations <1,250 ppm, Nb/Ta ranges between 35 and 45, whereas for V > 1,250 ppm, Nb/Ta is considerably lower (5–15). This relationship is mainly controlled by a change in Nb concentrations, suggesting that the indirect dependence of ^RtD_Nb on fO₂, which is not mirrored in ^RtD_Ta, can exert considerable influence on rutile Nb–Ta fractionation.  相似文献   

Accretion stream mapping of HU Aquarii     

Sonja Vrielmann  Axel D. Schwope 《Monthly notices of the Royal Astronomical Society》2001,322(2):269-279

We present a new mapping algorithm, the Accretion Stream Mapping (ASM), which uses the full phase-coverage of a light curve to derive spatially resolved intensity distributions along the accretion stream in magnetic cataclysmic variables of AM Herculis type (polars). The surface of the accretion stream is approximated as a 12-sided (duodecadon-shaped) tube. After successfully testing this method on artificial data we applied it to emission-line light curves of H β , H γ and He  ii λ 4686 of the bright eclipsing polar HU Aqr. We find hydrogen and helium line emission bright in the threading region of the stream where the stream couples on to magnetic field lines. It is particularly interesting that the stream is bright on the irradiated side facing the white dwarf, which highlights the interplay of collisional and radiative excitation/ionization.  相似文献   

Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait)   总被引：3，自引：2，他引：1  

Sonja Aulbach  Roberta L. Rudnick  William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92

Lithium concentrations and isotopic compositions of olivine and ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both δ⁷Li and Li concentrations. Olivines in iron-rich peridotites (Fo_85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ⁷Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively light δ⁷Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas. A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has a ⁸⁷Sr/⁸⁶Sr of 0.7029 and ¹⁴³Nd/¹⁴⁴Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared to previous estimates of the plume that were based on rift basalts. Although elevated δ⁷Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics in Sr, Nd and Li isotope composition. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

An initial scoping of transitional justice for global climate governance     

Sonja Klinsky 《Climate Policy》2018,18(6):752-765

Geopolitical changes combined with the increasing urgency of ambitious climate action have re-opened debates about justice and international climate policy. Tensions about historical responsibility have been particularly difficult and could intensify with increased climate impacts and as developing countries face mounting pressure to take mitigation action. Climate change is not the only time humans have faced historically rooted, collective action challenges involving justice disputes. Practices and tools from transitional justice have been used in over 30 countries across a range of conflicts at the interface of historical responsibility and imperatives for collective futures. Central to this body of theory and experience is the need to reflect both backwards- and forwards-oriented elements in efforts to build social solidarity. Lessons from transitional justice theory and practice have not been systematically explored in the climate context. This article conceptually examines the potential of transitional justice practices to inform global climate governance by looking at the structural similarities and differences between the global climate regime and traditional transitional justice contexts. It then identifies a suite of common transitional justice practices and assesses their potential applicability in the climate context.

POLICY RELEVANCE

• Justice disputes, including about historical responsibility and future climate actions, are long-standing in the climate context and could intensify with increased climate impacts and broadened mitigation pressures.

• Lessons from efforts to use transitional justice mechanisms could provide insight into strategies for balancing recognition of harms rooted in the past, while creating stronger future-oriented collective action.

• Several areas of transitional justice practice including: the combination of amnesties and litigation, truth commissions, reparations and institutional change could provide useful insights for the climate context.

  相似文献   

High energy phenomena in eta carinae     

Roberto F. Viotti  Lucio Angelo Antonelli  Sonja Rebecchi  Corinne Rossi 《Journal of Astrophysics and Astronomy》2002,23(1-2):19-22

We have investigated with BeppoSAX the long term behaviour of the harder X-ray component of the supposed supermassive binary system η Car along its 5.52 year cycle. We have found that in March 1998 during egress from the last December 1997 eclipse, this component was the same as outside eclipse, but for a large (×3.5) increase of NH _h , that can be attributed to the presence or formation of opaque matter in front of the source near periastron. Unexpectedly, at that time the iron 6.7 keV emission line was 40% stronger. BeppoSAX has for the first time found ahard X-ray tail extending to at least 50 keV, that cannot be adequately fitted with an additional hotter thermal component. The 2–100 keV spectrum of η Car is instead well fitted with an absorbed powerlaw spectrum with photon index 2.53, suggesting non-thermal emission as an alternative model for the core source.  相似文献   

Substrate-specific macroinvertebrate diversity patterns following stream restoration     

Sonja C. Jähnig  Armin W. Lorenz 《Aquatic Sciences - Research Across Boundaries》2008,70(3):292-303

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Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers   总被引：1，自引：1，他引：1  

Daniel H. Doctor  E. Calvin Alexander Jr  Metka Petrič  Janja Kogovšek  Janko Urbanc  Sonja Lojen  Willibald Stichler 《Hydrogeology Journal》2006,14(7):1171-1191

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.  相似文献   

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?     

Sonja Aulbach  William L. Griffin  Norman J. Pearson  Suzanne Y. O’Reilly  Buddy J. Doyle 《Contributions to Mineralogy and Petrology》2007,154(4):409-427

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).  相似文献