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Molybdenum concentrations in Icelandic geothermal waters lie in the range 1–70 ppb. Warm waters and dilute high-temperature waters which contain high concentrations of sulphide are lowest in molybdenum. No correlation is otherwise observed between molybdenum concentrations and temperature. Surface waters and cold ground waters do not contain detectable molybdenum (<1 ppb). It seems likely that leaching rate is the prime factor in limiting molybdenum levels in these waters. Within individual geothermal fields molybdenum concentrations are either approximately constant or they vary regularly across the field. This regular variation may often be correlated with variations in other solute concentrations and subsurface temperatures and is taken to indicate a control of molybdenum mobility by a temperature dependent equilibrium. The evidence suggests that the solubility of molybdenite is responsible. Molybdenite has not been found in active geothermal systems in Iceland but is known to occur in some New Zealand geothermal systems and it has been identified in hydrothermally altered Tertiary basalt formations at Reydarártindur in southeast Iceland. Boiling and mixing with cold water leads to molybdenite undersaturation and thus these processes favour leaching of molybdenum from the rock. On the other hand, conductive cooling leads to supersaturation which favours removal of molybdenum from solution. 相似文献
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Stefán Arnórsson 《Geochimica et cosmochimica acta》1984,48(12):2489-2502
Germanium concentrations in geothermal waters in Iceland lie mostly in the range 2–30 ppb. There is an overall positive relation between the germanium content of the water and its temperature. Most of the germanium occurs as Ge(OH)?5in solution but Ge(OH)4 may also be present in significant amounts in saline waters when above 200°C. Evidence indicates that aqueous germanium concentrations are controlled by exchange reactions where it substitutes for silica in silicates and iron in sulphides. It is the rate of dissolution and the relative abundance of the alteration minerals which take up germanium to a variable extent that ultimately fix Ge(OH)4 concentrations in the water. This, together with water pH, fixes total dissolved germanium. It is mostly the primary rock composition that dictates the relative abundance of the alteration minerals. Conductive cooling in upflow zones favours removal of germanium from solution. During the initial stages of boiling of rising hot water dissolution is enhanced but precipitation at later stages.Thermodynamic data of various aqueous germanium species and several minerals are summarized and dissociation constants and solubilities estimated at elevated temperatures using available predictive methods. 相似文献
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Kristín Vala Ragnarsdóttir John V Walther Stefán Arnórsson 《Geochimica et cosmochimica acta》1984,48(7):1535-1553
The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm3 is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO2, 10 gm H2S and 4 gm Na2O and a release of 57 gm SiO2, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K2O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous. 相似文献
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Stefán Arnórsson Einar Gunnlaugsson Hördur Svavarsson 《Geochimica et cosmochimica acta》1983,47(3):567-577
New data from geothermal wells in Iceland have permitted empirical calibration of the chalcedony and geothermometers in the range of 25–180°C and 25–250°C respectively. The temperature functions are: Concentrations are expressed in ppm. These temperature functions correspond well with the chalcedony solubility data of Fournier (1973) and the thermodynamic data for low-albite/microcline/solution equilibria of Heloeson (1969).A new CO2 geothermometer is proposed which is considered to be useful in estimating underground temperatures in fumarolic geothermal fields. Its application involves analysis of CO2 concentrations in the fumarole steam. The temperature function which applies in the range 180?300°C is: logCO2 = 37.43 + 73192/T- 11829· 103/T2 + 0.18923T- 86.187·logT where T is in °K and CO2 in moles per kg of steam. 相似文献
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Dimitrova Reneta Sharma Ashish Fernando Harindra J. S. Gultepe Ismail Danchovski Ventsislav Wagh Sandeep Bardoel Stef L. Wang Sen 《Boundary-Layer Meteorology》2021,181(2-3):443-472
Boundary-Layer Meteorology - We evaluate the efficacy of microphysics and planetary-boundary-layer (PBL) parametrizations of the Weather Research and Forecasting (WRF) model for simulation of the... 相似文献
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Grachev Andrey A. Krishnamurthy Raghavendra Fernando Harindra J. S. Fairall Christopher W. Bardoel Stef L. Wang Sen 《Boundary-Layer Meteorology》2021,181(2-3):395-422
Boundary-Layer Meteorology - Measurements of atmospheric turbulence at a site in Ferryland (Newfoundland) during the C-FOG (Coastal-Fog) field campaign in September–October 2018 are used to... 相似文献
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Marius Visarion Serban Veliciu Mihai StefĂnescu Reviewer V. Čermák 《Studia Geophysica et Geodaetica》1978,22(2):196-200
Summary Using heat flow and heat generation measurements together with deep seismic sounding and gravity data, a reasonable geothermal model has been constructed for the Romanian Carpathian Bend. At the level of the MOHO discontinuity the calculated temperatures exhibit conspicuous differences between inner and outer border of the Carpathian Bend and a horizontal gradient of 200–300 °C/100 km in the region is not to be excluded.Paper presented at the KAPG Symposium on Geothermics in Liblice, November 1976. 相似文献
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Stefán Arnórsson 《Contributions to Mineralogy and Petrology》1978,66(1):21-28
Unflashed geothermal waters in Iceland are invariably just saturated with calcite. Upon flashing the water always becomes supersaturated, especially during the early stages of flashing. Thus flashing will lead to calcite precipitation. It is believed that the rate of precipitation bears a positive relation to the degree of supersaturation and the water temperature. Accordingly, precipitation will always be most pronounced at the beginning of flashing. The degree of calcite supersaturation, which is produced by flashing, only depends on the temperature and the ionic strength of the unflashed water. Strongest supersaturation is produced at low temperature and at a high ionic strength of the water. Calcite precipitation is known to be troublesome for the exploitation of many geothermal fields in the world. The study of the factors which control the magnitude of this precipitation is therefore of interest to those engaged in the exploitation of geothermal fluids. 相似文献