Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating     

Mirta Garrido  Fernando Barra  Eduardo Domínguez  Joaquin Ruiz  Victor A. Valencia 《Mineralium Deposita》2008,43(5):591-597

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.  相似文献   

Reliability of a model based on a short fishery statistics survey: application to the Northeast Atlantic monkfish fishery     

Rocha  Francisco; Gracia  Joaquin; Gonzalez  Angel F; Jardon  Carlos M; Guerra  Angel 《ICES Journal of Marine Science》2004,61(1):25-34

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Zooplankton variability and climatic anomalies from 1994 to 2001 in the Balearic Sea (Western Mediterranean)     

Fernandez de Puelles  M. Luz; Valencia  Joaquin; Vicente  Laura 《ICES Journal of Marine Science》2004,61(4):492-500

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Distribution and Trophic Importance of Anthropogenic Nitrogen in Narragansett Bay: An Assessment Using Stable Isotopes     

Autumn Oczkowski  Scott Nixon  Kelly Henry  Peter DiMilla  Michael Pilson  Stephen Granger  Betty Buckley  Carol Thornber  Richard McKinney  Joaquin Chaves 《Estuaries and Coasts》2008,31(1):53-69

Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ¹⁵N) and carbon (δ¹³C). The δ¹⁵N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ¹⁵N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ¹⁵N values in macroalgae there reflected preferential uptake of ¹⁴N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ¹³C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ¹⁵N (13.2 ± 0.54‰ SD) and δ¹³C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ¹⁵N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.  相似文献   

A Re–Os study of sulfide minerals from the Bagdad porphyry Cu–Mo deposit, northern Arizona, USA     

Fernando Barra  Joaquin Ruiz  Ryan Mathur  Spencer Titley 《Mineralium Deposita》2002,38(5):585-596

Rhenium and osmium isotopes in sulfide minerals from the Bagdad porphyry Cu–Mo deposit have been used to determine timing of mineralization and the source of osmium and, by inference, ore metals. Molybdenite, chalcopyrite and pyrite were analyzed mainly from the quartz monzonite and porphyritic quartz monzonite units, which are characterized by moderate to strong potassic alteration (secondary biotite and K-feldspar). Rhenium concentrations in molybdenite are between 330 and 642 ppm. Four Re–Os analyses of two molybdenite samples from the quartz monzonite and porphyritic quartz monzonite yield a weighted average age of 71.8±0.2 Ma (2s). Analyses of a third sample from a molybdenite vein in Precambrian rocks, outside of the main ore zone, yield a weighted average age of 75.9±0.2 Ma (2s), and provide evidence of two separate mineralization episodes. Chalcopyrite samples contain 6 to 12 ppt Os and 1.7 to 4.1 ppb Re; ¹⁸⁷Os/ ¹⁸⁸Os initial ratios are between 0.1 and 0.8. Pyrite samples have osmium and rhenium concentrations varying in the range 8–17 ppt and 3.9–6.8 ppb, respectively. Analyses from these pyrite samples yield an eight-point isochron with an age of 77±15 Ma (2s) and an initial ¹⁸⁷Os/ ¹⁸⁸Os ratio of 2.1±0.8 (MSWD=0.90). The results presented here add to the growing body of work indicating that porphyry-type mineralization is produced by long-term, multiple episodes of magmatism and associated mineralization. The data also support the hypothesis that a significant part of the metals and magmas may have a crustal source, as has been suggested for other copper deposits and districts in Arizona.  相似文献   

Roof-rock contamination of magma along the top of the reservoir for the Bishop Tuff     

Wendell A. Duffield  Joaquin Ruiz  James D. Webster 《Journal of Volcanology and Geothermal Research》1995,69(3-4)

The Bishop Tuff, a well known Quaternary high-silica rhyolite in east-central California, is widely considered the type example of a vertically and monotonically zoned pyroclastic deposit that represents zoning in the source magma reservoir, inverted during the process of pyroclastic emplacement. However, the deposit of plinian pumice, which forms the base of the Bishop Tuff and represents the initial 10% or so of all magma erupted during the event that produced the Bishop Tuff, contains features at odds with monotonie zoning for the reservoir. Relative to overlying ignimbrite, the plinian deposit contains a reversal in trace-element zoning. Moreover, the ⁸⁷Sr/⁸⁶Sr is significantly higher than that in overlying ignimbrite (about 0.7084 vs 0.7064), and melt inclusions trapped in quartz phenocrysts exhibit notable variability of trace-element concentrations, even within a single host crystal (e.g., U: 10.77 to 8.91 ppm).These data have been previously interpreted as due to processes of chemical fractionation and evolution operating within a magma system closed to chemical interactions with its roof rocks. For example, the reversal in trace-element zoning has been explained by the first-erupted magma being erupted from somewhat below the top of a monotonically zoned reservoir. However, we submit that the reversed zoning and other above-noted features can be explained equally well as consequences of minor assimilation of roof rocks into a magma reservoir that was erupted from the top down.The basal part of the Bishop Tuff exhibits extreme concentrations and depletions of trace elements, relative to the average composition of crustal rocks. For example, the upward decrease of Sr in the Bishop magma reservoir (downward decrease in the ignimbrite) results in concentrations as low as 2–4 ppm. Because of the attendant ‘chemical leverage’, assimilation of < 1 wt.% of Sierra Nevada batholith rocks typical of the area could readily reverse an ‘uncontaminated’ Sr (and other trace elements) trend of zoning and could also substantially raise ⁸⁷Sr/⁸⁶Sr. Small-scale trace-element variability in the uppermost part of the Bishop magma reservoir, as recorded by the above-mentioned melt inclusions, may simply reflect melt heterogeneity produced by the process of assimilation.  相似文献   

The Byers Basin: Jurassic-Cretaceous tectonic and depositional evolution of the forearc deposits of the South Shetland Islands and its implications for the northern Antarctic Peninsula     

Joaquin Bastias  Mauricio Calderón  Lea Israel  Francisco Hervé  Richard Spikings  Robert Pankhurst 《International Geology Review》2020,62(11):1467-1484

ABSTRACT

This paper addresses the Jurassic–Cretaceous stratigraphic evolution of fore-arc deposits exposed along the west coast of the northern Antarctic Peninsula. In the South Shetland Islands, Upper Jurassic deep-marine sediments are uncomformably overlain by a Lower Cretaceous volcaniclastic sequence that crops out on Livingston, Snow and Low islands. U-Pb zircon ages are presented for the upper Anchorage Formation (153.1 ± 1.7 Ma) and the Cape Wallace granodiorite of Low Island (137.1 ± 1.7 Ma) as well as ⁴⁰Ar/³⁹Ar ages of 136–139 Ma for Low Island andesites. Data are also presented for a U-Pb age of 109.0 ± 1.4 Ma for the upper volcanic succession of Snow Island. In combination with published stratigraphy, these data provide a refined chrono- and litho-stratigraphic framework for the deposits herein referred to as the Byers Basin. Tentative correlation is explored with previously described deposits on Adelaide and Alexander islands, which could suggest further continuation of the Byers Basin towards the south. We also discuss possible correlation of the Byers Basin with the Larsen Basin, a sequence that shows the evolution of foreland to back-arc deposits more or less contemporaneously with the fore-arc to intra-arc evolution of the Byers Basin.  相似文献   

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems     

Wendell A. Duffield  Joaquin Ruiz   《Journal of Volcanology and Geothermal Research》1998,87(1-4)

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.  相似文献   

On final evolutions in the restricted planar parabolic three-body problem     

Martha Alvarez  Josep Maria Cors  Joaquin Delgado 《Celestial Mechanics and Dynamical Astronomy》2006,95(1-4):173-200

In this paper, we prove the existence of special type of motions in the restricted planar parabolic three-body problem, of the type exchange, emission–capture, and emission–escape with close passages to collinear and equilateral triangle configuration, among others. The proof is based on a gradient-like property of the Jacobian function when equations of motion are written in a rotating–pulsating reference frame, and the extended phase space is compactified in the time direction. Thus a phase space diffeomorphic to -coordinates (θ, ζ, ζ′) is obtained with the boundary manifolds θ = ± π/2 corresponding to escapes of the binaries when time tends to ± ∞. It is shown there exists exactly five critical points on each boundary, corresponding to classic homographic solutions. The connections of the invariant manifolds associated to the collinear configurations, and stable/unstable sets associated to binary collision on the boundary manifolds, are obtained for arbitrary masses of the primaries. For equal masses extra connections are obtained, which include equilateral configurations. Based on the gradient-like property, a geometric criterion for capture is proposed and is compared with a criterion introduced by Merman (1953b) in the fifties, and an example studied numerically by Kocina (1954).  相似文献   

Constraining Holocene sea levels using U‐Th ages of phreatic overgrowths on speleothems from coastal caves in Mallorca (Western Mediterranean)     

Paola Tuccimei  Michele Soligo  Joaquin Ginés  Angel Ginés  Joan Fornós  Jan Kramers  Igor Maria Villa 《地球表面变化过程与地形》2010,35(7):782-790

Phreatic overgrowths on speleothems (POS) are carbonate formations deposited at the water table of caves in unique karstic coastal settings having morphologies that can be directly related to sea level at the time of formation. The U‐Th ages of calcite and aragonite overgrowths collected from the modern water table in coastal caves on Mallorca (Cova de Cala Varques A and Cova des Pas de Vallgornera) were determined using high‐precision MC‐ICPMS techniques. U‐Th ages indicate that phreatic carbonate deposition occurred between ca 2·8 and at least 0·6 ka BP and are in accord with an archeologically estimated age of 3·7–3·0 ka BP for a drowned prehistoric construction at a depth of 1 m below current sea level in a cave from the same area. Speleothem δ¹³C and δ¹⁸O and chemical composition of cave pools provide supportive evidence that POS reflect mixing between seawater and brackish water table. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献