Iron oxidation state in the Fe‐rich layer and silica matrix of Libyan Desert Glass: A high‐resolution XANES study     

Gabriele Giuli  Eleonora Paris  Giovanni Pratesi  Christian Koeberl  Curzio Cipriani 《Meteoritics & planetary science》2003,38(8):1181-1186

Abstract— Libyan Desert Glass (LDG) is an enigmatic type of glass that occurs in western Egypt in the Libyan Desert. Fairly convincing evidence exists to show that it formed by impact, although the source crater is currently unknown. Some rare samples present dark‐colored streaks with variable amounts of Fe, and they are supposed to contain a meteoritic component. We have studied the iron local environment in an LDG sample by means of Fe K‐edge highresolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain quantitative data on the Fe oxidation state and coordination number in both the Fe‐poor matrix and Fe‐rich layers. The pre‐edge peak of the high‐resolution XANES spectra of the sample studied displays small but reproducible variations between Fe‐poor matrix and Fe‐rich layers, which is indicative of significant changes in the Fe oxidation state and coordination number. Comparison with previously obtained data for a very low‐Fe sample shows that, while iron is virtually all trivalent and in tetrahedral coordination (^[4]Fe³⁺) in the low‐Fe sample, the sample containing the Fe‐rich layers display a mixture of tetra‐coordinated trivalent iron (^[4]Fe³⁺) and penta‐coordinated divalent iron (^[5]Fe²⁺), with the Fe in the Fe‐rich layer being more reduced than the matrix. From these data, we conclude the following: a) the significant differences in the Fe oxidation state between LDG and tektites, together with the wide intra‐sample variations in the Fe‐oxidation state, confirm that LDG is an impact glass and not a tektite‐like glass; b) the higher Fe content, coupled with the more reduced state of the Fe, in the Fe‐rich layers suggests that some or most of the Fe in these layers may be directly derived from the meteoritic projectile and that it is not of terrestrial origin.  相似文献   

Mineralogy and geochemistry of platinum-group elements in the Aguablanca Ni-Cu deposit (SW Spain)     

R. Piña  F. Gervilla  L. Ortega  R. Lunar 《Mineralogy and Petrology》2008,92(1-2):259-282

Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral (PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic hydrothermal fluids after the sulphide crystallisation. Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid, Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002 Granada, Spain  相似文献   

Response of the barrier island coastal region of southwestern Nigeria to climate and non-climate forcing     

IB Danladi  M Gül  E Ateş 《African Journal of Marine Science》2020,42(1):43-51

Despite threats emanating from the influence of climate and non-climate forcing on the barrier island coastal region of southwestern Nigeria, the extent of the coastal erosion is poorly understood. We report evidence of coastal erosion and sediment accumulation in the region over a 34-year period (1973–2017), using Landsat imagery at intervals of approximately six years. Landsat image corrections and various water-extraction algorithms were used to systematically delineate coastal erosion and accumulation in the area. The region was subdivided into western and eastern subregions separated by Lagos Harbour. In the west, erosion took place during the periods 1973–1979, 1979–1984, 1990–1999 and 2005–2011, whereas in the east, erosion occurred during 1973–1979, 1990–1999 and 1999–2005. Coastal sediment accumulation occurred in the east during 1979–1984, 1984–1990, 2005–2011 and 2011–2017, whereas gains in the west occurred during 1984–1990, 1999–2005 and 2011–2017. The study revealed substantial net erosion of 1 228.1 ha in the region as a whole, over the full period. Sediment accumulation accompanying the coastal erosion appears to be linked to longshore drift. Erosion between 1973 and 2011 was probably attributable to climate change (storms and tidal conditions), longshore drift, the inflow and outflow of water at Lagos Harbour, coastal morphology and, possibly, human impacts. However, the coastal changes between 2011 and 2017 were more obviously associated with human activities, such as development of the Eko Atlantic construction project. Coastal surveillance, together with the use of environmentally sensitive protective measures, could possibly help to reduce coastal erosion in the region. Careful coastal management practices, including artificial nourishing and the installation of resilient structures (e.g. seawalls), should be undertaken to protect human settlements that are already at risk from sea-level rise.  相似文献   

Threshold condition of sand particles under codirectional combined wave and current flow     

M. S. Kapdaşli 《Geo-Marine Letters》1990,10(1):45-49

Flume experiments were carried out to determine the threshold of movement of sand on rippled surface and flat beds under the codirectional combined flows due to waves and currents. The results indicate that Shields's curve can be used to determine the threshold condition under combined flows, provided that the maximum bed shear stress is used.  相似文献   

Quaternary evolution of the Gulf of İzmit (NW Turkey): a sedimentary basin under control of the North Anatolian Fault Zone     

Erdal Dolu  Erkan Gökaşan  Engin Meriç  Mustafa Ergin  Tolga Görüm  Hüseyin Tur  Berkan Ecevitoğlu  Niyazi Avşar  Muhittin Görmüş  Fatmagül Batuk  Buğser Tok  Oktay Çetin 《Geo-Marine Letters》2007,27(6):355-381

The Quaternary evolution of the Gulf of İzmit, situated on the tectonically active North Anatolian Fault Zone (NAFZ), was investigated using seismic reflection, paleontologic, and sediment textural data. On the basis of seismic stratigraphic and sedimentologic-paleontologic interpretations, four depositional units were distinguished within the Plio-Quaternary sequence of the Gulf of İzmit. According to these data, Plio-Quaternary deposits supplied from the northern terrestrial area started to accumulate during a progradational phase, in a south-facing half-graben. A coarse-grained sedimentary unit prograding into the gulf from the south since 200 ka b.p. indicates a dramatic variation in the evolution of the gulf, with the initiation of a new strike-slip fault of the NAFZ and a corresponding uplift of the Armutlu Peninsula in the south of the gulf. During the evolution of this fault from a wide shear zone consisting of right-stepped strike-slip faults and pull-apart basins to a localized principal fault zone, sediments were deposited under the influence of northerly prograding terrestrial and shallow-marine conditions due to relative sea-level fluctuations in the Marmara Sea. During this period, the Gulf of İzmit was invaded mainly by Mediterranean and partly by Black Sea waters. In the latest glacial period, shallow areas in the gulf became subaerially exposed, whereas the central and western sub-basins of the gulf turned into lakes. The present evolution of the Gulf of İzmit is controlled by the after effects of the new rupture of the NAFZ and the estuarine nature of the gulf environment.  相似文献   

Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties   总被引：1，自引：0，他引：1  

Elena Piñero  Eulàlia Gràcia  Francisca Martínez-Ruiz  Juan Cruz Larrasoaña  Alexis Vizcaino  Gemma Ercilla 《Geo-Marine Letters》2007,27(2-4):279-288

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.  相似文献   

Stratigraphy of the sediment infill in Bosphorus Strait: water exchange between the Black and Mediterranean Seas during the last glacial Holocene     

O. Algan  N. Çağatay  A. Tchepalyga  D. Ongan  C. Eastoe  E. Gökaşan 《Geo-Marine Letters》2001,20(4):209-218

The sediment infill over the Paleozoic bedrock in the Bosphorus Strait consists of four sedimentary units which were deposited in the last 26,000 ¹⁴C years B.P. The stratigraphy of these units suggests that this part of the Bosphorus was a freshwater lake between 26,000 and 5,300 ¹⁴C years B.P., depositing sands with a freshwater mollusc fauna of Black Sea neo-euxinian affinity (Dreissena rostriformis, Dreissena polymorpha, and Monodacna pontica). The first appearance of euryhaline Mediterranean molluscs (e.g., Ostrea edulis, Mytilus edulis) was observed at 5,300 ¹⁴C years B.P. in this part of the Bosphorus. Deposition of coarse Mytilus-bank and Ostrea-bank units suggests that the establishment of the present dual-flow regime in the Bosphorus took place at about 4,400 ¹⁴C years B.P.  相似文献   

Fluid inclusion and stable isotope characteristics of the Karalar (Gazipaşa,Antalya) barite-galena deposits,Southern Turkey     

A. Gökşe  G. Bozkaya 《Geology of Ore Deposits》2008,50(2):145-154

The Karalar galena-barite deposits are typical examples of the carbonate-hosted barite-galena deposits widely occurring in the Central Tauride Belt. These deposits are located in Permian limestones as ore veins along fault zones that are discordant to the bedding planes and as thin veinlets within hardly brecciated bottom zones of Permian limestones. The ore deposits contain mainly barite and galena and small amounts of sphalerite, pyrite, fahlore, limonite, quartz, and calcite. Barites occur during the earlier episode of mineralization and were mylonitized before the formation of galena. Galena and other minerals occur epigenetically with barite along porous zones between brecciated barite crystals and are especially abundant in the hardly mylonitized zones. Fluid inclusion studies indicate that the ore deposits of the area were developed by hydrothermal fluids with following characteristics: they contained NaCl, CaCl₂, and MgCl₂; the salinity of the fluids was relatively high and their temperature was low during the crystallization of barites in the earlier episode of mineralization; and the salinity of the fluids decreased and their temperature increased during the crystallization of sulfide minerals through the later episode of mineralization. δ₁₈O and the δD results indicate that the water in the mineralizing fluid was of meteoric origin. The deposits were formed by deep meteoric water circulating through marine sediments. Shallow circulating and slightly warmed fluids dissolved Ba and sulfate from marine sediments of the basement and transported them to the mineralization environment during the early episode, while deep circulating and more heated fluids dissolved Pb, Zn, and other elements from the basement and reached the environment during the later episode of mineralization. The text was submitted by the authors in English.  相似文献   

On the elliptic restricted three-body problem     

Jaume Llibre  Conxita Piñol 《Celestial Mechanics and Dynamical Astronomy》1990,48(4):319-345

The main goal of this paper is to show that the elliptic restricted three-body problem has ejection-collision orbits when the mass parameter µ is small enough. We make use of the blow up techniques. Moreover, we describe the global flow of the elliptic problem when µ = 0 taking into account the singularities due to collision and to infinity.  相似文献   

Periodic orbits of an electric charge in a magnetic dipole field     

Lidia Jiménez-Lara  Eduardo Piña 《Celestial Mechanics and Dynamical Astronomy》1990,49(4):327-345

Periodic orbits in the Stormer problem are studied using the symmetry lines of the Poincaré map introduced by De Vogelaere. Many known facts are explained by mean of these lines. The dynamics of four special symmetry lines when the Stormer parameter ₁ changes is presented, and we obtain a clear global view of the structure of the simple periodic orbits and their bifurcations, including the asymmetrical ones. New asymmetrical multiple periodic orbits are obtained.  相似文献