Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry     

Elisa Lopez Capel  Jos Maria de la Rosa Arranz  Francisco J. Gonzlez-Vila  Jos Antonio Gonzlez-Perez  David A.C. Manning 《Organic Geochemistry》2006,37(12):1983

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.  相似文献   

Sliding fragility of block‐type non‐structural components. Part 1: Unrestrained components     

D. Lopez Garcia  T. T. Soong 《地震工程与结构动力学》2003,32(1):111-129

Motivated by the development of performance‐based design guidelines with emphasis on both structural and non‐structural systems, this paper focuses on seismic vulnerability assessment of block‐type unrestrained non‐structural components under sliding response on the basis of seismic inputs specified by current seismic codes. Two sliding‐related failure modes are considered: excessive relative displacement and excessive absolute acceleration. It is shown that an upper bound for the absolute acceleration response can be assessed deterministically, for which a simple yet completely general equation is proposed. In contrast, fragility curves are proposed as an appropriate tool to evaluate the excessive relative displacement failure mode. Sample fragility curves developed through Monte‐Carlo simulations show that fragility estimates obtained without taking into account vertical base accelerations can be significantly unconservative, especially for relatively large values of the coefficient of friction. It is also found that reasonable estimates of relative displacement response at stories other than the ground in multistorey buildings cannot in general be obtained by simply scaling the ground acceleration to the peak acceleration at the corresponding storey. Failure modes considered in this study are found to be essentially independent of each other, a property that greatly simplifies assessment of conditional limit states. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Why chromatic imaging matters     

Joel Sanchez-Bermudez  Florentin Millour  Fabien Baron  Roy van Boekel  Laurent Bourgès  Gilles Duvert  Paulo J. V. Garcia  Nuno Gomes  Karl-Heinz Hofmann  Thomas Henning  Jacob W. Isbell  Bruno Lopez  Alexis Matter  J-Uwe Pott  Dieter Schertl  Eric Thiébaut  Gerd Weigelt  John Young 《Experimental Astronomy》2018,46(3):457-473

During the last two decades, the first generation of beam combiners at the Very Large Telescope Interferometer has proved the importance of optical interferometry for high-angular resolution astrophysical studies in the near- and mid-infrared. With the advent of 4-beam combiners at the VLTI, the u ? v coverage per pointing increases significantly, providing an opportunity to use reconstructed images as powerful scientific tools. Therefore, interferometric imaging is already a key feature of the new generation of VLTI instruments, as well as for other interferometric facilities like CHARA and JWST. It is thus imperative to account for the current image reconstruction capabilities and their expected evolutions in the coming years. Here, we present a general overview of the current situation of optical interferometric image reconstruction with a focus on new wavelength-dependent information, highlighting its main advantages and limitations. As an Appendix we include several cookbooks describing the usage and installation of several state-of-the art image reconstruction packages. To illustrate the current capabilities of the software available to the community, we recovered chromatic images, from simulated MATISSE data, using the MCMC software SQUEEZE. With these images, we aim at showing the importance of selecting good regularization functions and their impact on the reconstruction.  相似文献   

Absorption and desorption of dichloromethane vapor by water drops in air. An experimental test of scavenging theory     

S. Lopez  J. H. Topalian  S. K. Mitra  D. C. Montague 《Journal of Atmospheric Chemistry》1989,8(2):175-188

An experimental study of the scavenging of dichloromethane vapor by water drops falling at terminal velocity, has been carried out in the UCLA precipitation shaft, in order to test the predictions of theoretical washout models. Whereas good agreement between theory and experiment was found for drops of radius 0.332 mm, computed gas uptake rates for 1.253 and 2.21 mm radius drops were much slower than those measured, just as reported previously for the washout of both sulfur dioxide and acetaldehyde. An analysis shows that theory can be reconciled with all of the experimental data by replacing the compound specific aqueous phase Fickian molecular diffusion coefficient used in the theory, by an effective diffusivity, having a constant value, (3×10^-4 cm² s^-1), independent of the physical and chemical nature of the absorbed species, for all drops of equivalent radii greater than 0.9 mm.  相似文献   

Geochemistry of Los Humeros Caldera,Puebla, Mexico     

S. P. Verma  M. Lopez 《Bulletin of Volcanology》1982,45(1):63-79

Geochemistry of Pliocene to recent volcanic rocks from Los Humeros caldera (19°30′ N – 19°50′ N and 97°15° W – 97°35′ W) in East-Central mexico is described. The volcanic rocks from this area seem to represent both alkali and high-alumina basalt series, or both calcalkaline and high-K calc-alkaline sequences. The available bulk-chemical analyses (23 this study and 18 from unpublished literature) show that the entire sequence of rocks from basalts to rhyolites are present in this area. Different degrees of partial melting of the source region followed by extensive shallow-level crystal differentiation seem to have taken place before most volcanic eruptions. These processes are perhaps the most important mechanisms for magma genesis in Los Humeros caldera. Geophysical studies in this area are not sufficient and more detailed geophysical surveys and a better geological interpretation are needed in order to delimit the underlying magma chamber.  相似文献   

Water status in winter wheat grown under salt stress     

M Larry Lopez C~  WANG Rong~  MAO Xue-sen~  Takahashi Hidenori~ 《地理学报(英文版)》2001,11(2):202-208

1 IntroductionSalinization is one of the major problems in arid and semi-arid regions in relation to land use and in particular to agricultural production[1]. Excessive salinity leads to toxicity in crops and reduction of the availability of water to crops, by reducing the osmotic potential of the soil solution[2]. Movement of soil water induces solute transport, and solutes are transferred towards the ground surface by the upward soil-water movement caused by evaporation, resulting in an accu…  相似文献   

Thermochronology and exhumation rates of granitic intrusions at Mesa Central,Mexico     

Angel F. Nieto-Samaniego  María de Jesús Paulina Olmos-Moya  Gilles Levresse  Susana A. Alaniz-Alvarez  Fanis Abdullin  Alexis del Pilar-Martínez 《International Geology Review》2020,62(3):311-319

ABSTRACT

The Mesa Central of Mexico (MC) is an elevated plateau located 2000 m above sea level in central Mexico, where intrusions outcrop that register the history of exhumation-erosion occurring during the Late Cretaceous-Paleogene. The tectonic history of the region records formation of the Late Cretaceous-Paleogene ‘Mexican orogen’; this was followed by extension of the entire region and several plutons were then exhumed. The age and magnitude of the crustal uplift and erosion occurring during exhumation has not been addressed to date. Therefore, this study reports the crystallization and cooling ages of two plutons, the Tesorera Granodiorite and the Comanja Granite, and estimates their emplacement depths. Based on these data, the exhumation age of the Tesorera Granodiorite is estimated to be between ~73 Ma and ~63 Ma at an exhumation rate of ~528 m/m. y. and that of the Comanja Granite is 52 Ma and 48 Ma at an exhumation rate of ~2500 m/m. y. Exhumation-erosion event of the Tesorera Granodiorite was located on the trace of the San Luis-Tepehuanes Fault System and that of the Comanja Granite on the a trace of the El Bajío Fault System. Furthermore, the high exhumation rate in the Comanja Granite suggests that gravitational collapse played an important role during exhumation.  相似文献   

Alteration patterns and structural controls of the El Espino IOCG mining district,Chile     

G. P. Lopez  M. W. Hitzman  E. P. Nelson 《Mineralium Deposita》2014,49(2):235-259

The El Espino IOCG mining district is characterized by several mineralized bodies the largest of which is the El Espino deposit, which has an estimated geologic resource of 123 Mt at 0.66 % Cu and 0.24 g/t Au. Mineralized bodies are distributed in a 7?×?10 km² area throughout a 1,000-m vertical section. They range from single veins to stockworks and breccias to manto-type deposits. The ore bodies are hosted primarily by volcanic, volcaniclastic, and sedimentary rocks of the Early Cretaceous Arqueros and Quebrada Marquesa formations, with a few mineralized zones within Late Cretaceous dioritic intrusions. The fault and vein architecture shows that El Espino IOCG system was localized within a dilatational jog along a major transtensional dextral fault system. Sodic alteration (albite) is the most extensive style of alteration in the district, and it is bounded by major NS–NNE trending faults. Sodic–calcic (epidote–albite) alteration occurs at deep to medium elevations (1,000–500 m) and grades inward into calcic alteration. Calcic alteration surrounds dioritic intrusions of the Llahuin plutonic suite. Significant iron oxides are associated with later calcic alteration associations (actinolite–epidote–hematite). The upper portions of the alteration system (0–500 m) display hydrolytic alteration associations with abundant hematite. Hydrolytic veins are feeders to zones of manto-type alteration and mineralization within favorable volcano-sedimentary lithologies that formed El Espino deposit. Sulfides are largely confined to calcic and hydrolytic alteration associations. Hydrothermal fluids responsible for hematite and sulfide mineralization had salinities between 32 and 34 wt% NaCl_eq and temperature of approximately 425 °C at an estimated depth of 3–4 km. Geochronological U–Pb and ⁴⁰Ar/³⁹Ar data indicate that hydrothermal alteration was coeval with magmatic intrusive activity. One particular dioritic intrusion (88.5 Ma) preceded the calcic stage (88.4 Ma), which was accompanied by iron oxide copper and gold mineralization. Hydrolytic alteration, related to economic iron oxide copper and gold mineralization, came immediately after at 87.9 Ma.  相似文献   

北喀斯喀特边缘IODP 311航次断面的地震结构、天然气水合物含量和滑塌构造   总被引：1，自引：0，他引：1  

George Spence  Caroll Lopez  Tao He  杨传胜 《海洋地质前沿》2008,24(11):44-47

北喀斯喀特活动边缘的增生楔沉积物中含有分布广泛的天然气水合物一直延伸到海底下几百米的深度。为了评估天然气水合物的长期能源潜力和它在全球气候变化及边坡稳定性中的作用，2005年9月IODP311航次建立了一个详细的地质模型来解释水合物的形成与分解以及它与穿过大陆边缘流体流的伴生关系。在考察前，先在大陆坡上进行地震试验以提供支持钻井的地球物理信息。  相似文献   

Colour-differential interferometry for the observation of extrasolar planets     

M. Vannier  R. G. Petrov  B. Lopez  F. Millour 《Monthly notices of the Royal Astronomical Society》2006,367(2):825-837

We present the high angular resolution technique of colour-differential interferometry for direct detection of extrasolar giant planets (EGPs). The measurement of differential phase with long-baseline ground-based interferometers in the near-infrared could allow the observation of several hot giant extrasolar planets in tight orbit around the nearby stars, and thus yield their low- or mid-resolution spectroscopy, complete orbital data set and mass. Estimates of potentially achievable signal-to-noise ratios are presented for a number of planets already discovered by indirect methods. The limits from the instrumental and atmospheric instability are discussed, and a subsequent observational strategy is proposed.  相似文献