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The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra.  相似文献   
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Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.  相似文献   
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Many Perseid meteors were photographed in the Czech part of the European Fireball Network during the activity of the new strong and sharp maximum on August 12, 1993. Basic data on many of them were evaluated and radiants, atmospheric trajectories and some orbital elements are presented here and compared with atmospheric and orbital data of regular Perseids, which were photographed outside the new activity in 1993 and preceding years. No substantial difference between these two groups of Perseid meteors was found.  相似文献   
6.
Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:
  1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
  2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
  3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.
Then the problems stated are shown to be easily solvable.  相似文献   
7.
The hydraulic behaviour of the karst aquifer in the Hubelj spring catchment area (SW Slovenia) was studied by using an indirect research method based on natural tracers. The variations of natural tracers (in precipitation and in groundwater) during the storm event made possible the separation of the Hubelj spring storm hydrograph by the three-component separation technique. The results produced information on the aquifer recharge, storage and discharge processes, as well as on the mechanisms that affected them. They verified the so-called epikarst hypothesis presuming that an important part of a karst aquifer recharge reaches rapidly and intensively from the epikarst zone. It was demonstrated that epikarst water could occupy up to 50% of the spring discharge during precipitation events. This phenomenon could have important consequences on protection and management of the problems of karst aquifers, including engineering problems in karst areas. With this respect the results could give way to new engineering ideas.  相似文献   
8.
Ultramafic xenoliths from a veined mantle wedge beneath the Kamchatka arc have non-chondritic, fractionated chondrite-normalized platinum-group element (PGE) patterns. Depleted (e.g., low bulk-rock Al2O3 and CaO contents) mantle harzburgites show clear enrichment in the Pd group relative to the Ir group PGEs and, in most samples, Pt relative to Rh and Pd. These PGE signatures most likely reflect multi-stage melting which selectively concentrates Pt in Pt–Fe alloys while strongly depleting the sub-arc mantle wedge in incompatible elements. Elevated gold concentrations and enrichment of strongly incompatible enrichment (e.g., Ba and Th) in some harzburgites suggest a late-stage metasomatism by slab-derived, saline hydrous fluids. Positive Pt, Pd, and Au anomalies coupled with Ir depletions in heavily metasomatized pyroxenite xenoliths probably reflect the relative mobility of the Pd and Ir groups (especially Os) during sub-arc metasomatism which is consistent with Os systematics in arc mantle nodules. Positive correlations between Pt, Pd, and Au and various incompatible elements (Hf, U, Ta, and Sr) also suggest that both slab-derived hydrous fluids and siliceous melts were involved in the sub-arc mantle metasomatism beneath the Kamchatka arc.  相似文献   
9.
Optimal Model for Geoid Determination from Airborne Gravity   总被引:2,自引:0,他引:2  
Two different approaches for transformation of airborne gravity disturbances, derived from gravity observations at low-elevation flying platforms, into geoidal undulations are formulated, tested and discussed in this contribution. Their mathematical models are based on Green's integral equations. They are in these two approaches defined at two different levels and also applied in a mutually reversed order. While one of these approaches corresponds to the classical method commonly applied in processing of ground gravity data, the other approach represents a new method for processing of gravity data in geoid determination that is unique to airborne gravimetry. Although theoretically equivalent in the continuous sense, both approaches are tested numerically for possible numerical advantages, especially due to the inverse of discretized Fredholm's integral equation of the first kind applied on different data. High-frequency synthetic gravity data burdened by the 2-mGal random noise, that are expected from current airborne gravity systems, are used for numerical testing. The results show that both approaches can deliver for the given data a comparable cm-level accuracy of the geoidal undulations. The new approach has, however, significantly higher computational efficiency. It would be thus recommended for real life geoid computations. Additional errors related to regularization of gravity data and the geoid, and to accuracy of the reference field, that would further deteriorate the quality of estimated geoidal undulations, are not considered in this study.  相似文献   
10.
Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.  相似文献   
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