南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义     

黄式庭  于晓飞  吕志成  刘家军  李永胜  杜泽忠  吕鑫  孙海瑞  杜轶伦 《吉林大学学报(地球科学版)》2020,50(5):1387-1403

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一，其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征，将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主，粒度为0.50~1.50 mm，贫As、Au；毒砂含量极少，呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出，含砷黄铁矿多为立方体、五角十二面体，粒度为0.30~1.00 mm，富As、Au；该阶段矿化最为强烈，毒砂主要形成于此时期，多呈棱柱状、柱状、放射状集合体，显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出，黄铁矿多呈长条状，以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱，毒砂、黄铁矿含量极少，为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰，均值为-3.3‰；Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰，均值为-3.3‰；Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间，均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆，混入了部分地层硫。综合前人研究成果，认为成矿早期至晚期，成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境，硫源充足；Ⅱ阶段为贫S富As的高氧逸度环境，由于大气降水对地层的淋滤渗透，混入富As流体，Au可能与As结合形成Au-As络合物，在成矿有利部位富集沉淀；Ⅲ阶段成矿元素种类丰富，体系为富S贫As的弱还原环境，Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。  相似文献   

2007-2017年中国沙尘气溶胶的三维分布特征及输送过程     

贾瑞  刘玉芝  吴楚樵  祝清哲  汪兵 《中国沙漠》2019,39(6):108-117

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。  相似文献   

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例     

赵艳红  包金哲  王树波  翟浩  魏建民  杨智升  张晖  赵铁锁  苏日亚  王磊  王鑫  贾昕晔  刘芳 《震灾防御技术》2019,14(3):662-676

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。  相似文献   

Temporal and Spatial Dynamics Analysis of Grassland Ecosystem Pressure in Kazakhstan     

WEN Xin  YAN Huimin  XIE Xiaoping  DU Wengpeng  LAI Chenxi  ZHEN Lin 《资源与生态学报(英文版)》2019,10(6):667-675

Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.  相似文献   

Effect of spatially variable saturated hydraulic conductivity with non-stationary characteristics on the stability of reservoir landslides     

Xue  Yang  Wu  Yiping  Miao  Fasheng  Li  Linwei  Liao  Kang  Ou  Guangzhao 《Stochastic Environmental Research and Risk Assessment (SERRA)》2020,34(2):311-329

Stochastic Environmental Research and Risk Assessment - Conventional landslide analyses, based on deterministic methods or simple random variable methods, cannot consider the spatial variability...  相似文献   

Mantle transition zone structure beneath the Central Asian Orogenic Belt     

Jing HE  Qingju WU 《中国科学:地球科学(英文版)》2020,63(4):548-560

Over the past decades, there have been hot debates in the geodynamic community regarding to the deep evolution mechanisms of Cenozoic volcanism in the Central Asian Orogenic Belt(CAOB). Of all the constraints available, high resolution structure of upper mantle discontinuities, especially the discontinuities at depths of 410 km(D410) and 660 km(D660), is of the most important, which may provide reliable clues on the magma channel as well as its evolution. In this work, we adopt the common conversion point stacking technique with teleseismic radial P-wave receiver functions to examine the D410 and D660 discontinuities. The primary results exhibit that the major characteristics of the mantle transition zone(MTZ) obtained by different velocity models are largely consistent. Obviously elevated D410 and slightly depressed D660 are observed beneath the Hannuoba Volcano, suggesting possible delamination of the local lithosphere deposited at the D410. This process may induce upwelling of the asthenospheric materials filling the space left by the delaminated lithosphere, and subsequently trigger volcanic eruptions. Strong depressions are observed at both D410 and D660 depths beneath west of the Dariganga Volcano, and the depression of D660 is more pronounced. It leads to the apparently thickened MTZ, indicating the presence of cold material at the D660. This cold material is speculated as a stagnant slab from the subducted Pacific Plate or the remains of a detached island arc system from the collision and formation of the CAOB. Slightly thinner MTZ is found beneath the Hentey Mountains and the Middle Gobi Volcano. Apparently, this thinner MTZ is not significant enough to support the existence of high thermal anomalies,which may rule out the possibility of large-scale hot material upwelling from either the local MTZ or even the lower mantle.  相似文献   

Metallogenesis and major challenges of porphyry copper systems above subduction zones   总被引：1，自引：0，他引：1  

Chen  Huayong  Wu  Chao 《中国科学:地球科学(英文版)》2020,63(7):899-918

Porphyry copper±molybdenum±gold deposits(PCDs) are the most representative magmatic-hydrothermal metallogenic system above subduction zones with important economic value. Previous studies revealed that large PCDs are generally formed from initial arc magmas(from subduction-induced partial melting of the mantle wedge), which eventually ascend to the shallow crust(3–5 km) for mineralization after a series of complex evolution processes. These processes include(1) the dehydration or partial melting of subducting slab, which induces partial melting of the metasomatized mantle wedge;(2)the ascent of mantle-derived magma to the bottom of the lower crust, which subsequently undergoes crustal processes such as assimilation plus fractional crystallization(AFC) or melting, assimilation, storage and homogenization(MASH);(3) the magma chamber formation at the bottom of the lower, middle and upper crust;(4) the final emplacement and volatilization of porphyry stocks; and(5) the accumulation of ore-forming fluids and metal precipitation. Despite the many decades of research, many issues involving the PCD metallogenic mechanism still remain to resolve, such as(1) the tectonic control on the geochemical characteristics of ore-forming magma;(2) the reason for the different lifespans of the long-term magmatic arc evolution and geologically "instantaneous" mineralization processes;(3) the source of ore-forming materials;(4) the relative contributions of metal pre-enrichment to mineralization by the magma source and by magmatic evolution; and(5) the decoupling behaviors of Cu and Au during the pre-enrichment. These issues point out the direction for future PCD metallogenic research, and the resolution to them will deepen our understanding of the metallogenesis at convergent plate boundaries.  相似文献   

汶川MS8.0大震前后鲜水河断裂带滑动及其西部地壳形变的动态变化     

陈欣  杨国华 《华北地震科学》2020,38(3):27-31,37

基于鲜水河断裂带及邻近区域GPS资料,以发生汶川MS8.0大震的2008年为时间节点,利用视错动变形系统分析模型研究了鲜水河断裂带及邻区不同时段的滑动与区域形变活动特征,结果表明:汶川大震前后鲜水河断裂带构造活动的动态变化是显著的,其西部地区地壳形变的动态变化也较清晰,这些不仅说明了汶川大震的孕育在较大的空间范围存在不同特征的形变与构造活动,同时其西部地区也存在着疑似断裂带形变中心的地壳动态变化,这可能与特定的构造和动力环境密切相关,为我们识别大震前兆提供了更多的可能。  相似文献