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1.
为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律,选取了徐闻南山镇红树林为研究对象,通过测定红树林沉积物及红树植物不同部位(根、茎、叶)的重金属质量分数,运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明:1)红树林沉积物重金属质量分数表现为铬(Cr)>锌(Zn)>镍(Ni)>铜(Cu)>铅(Pb)>砷(As)>汞(Hg)>镉(Cd),为中等变异程度;除了镍(Ni)元素外,其余7种重金属未超过国家一级标准,除了铅(Pb)元素外,其余7种重金属均超过广东省土壤环境背景值,说明研究区沉积物中重金属具有一定的积累效应。2)沉积物中砷(As)、铜(Cu)、锌(Zn)、汞(Hg)、镍(Ni)、铬(Cr)富集因子值均>1.5,说明受到轻微人为活动影响;各站位镍(Ni)富集因子值均>5,结合研究区背景,反映了镍(Ni)受到自然和人为输入的共同影响。3)白骨壤体内重金属主要集中在根部,而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄,说明白骨壤对重金属的吸附能力比红海榄强。汞(Hg)集中分布在植物的叶片部位,且与其他重金属之间相关性不明显;推测汞(Hg)主要通过叶片吸收进入植物体内,与交通运输污染有关。4)不同红树植物对不同重金属富集能力各异,白骨壤对重金属的富集能力表现为:镉(Cd)>砷(As)>铜(Cu)>锌(Zn)>汞(Hg)>铅(Pb)>镍(Ni)>铬(Cr),红海榄表现为:镉(Cd)>铜(Cu)>汞(Hg)>锌(Zn)>铅(Pb)>砷(As)>镍(Ni)>铬(Cr)。白骨壤和红海榄对汞(Hg)的运移能力都较强;红海榄对镉(Cd)的富集能力和转运能力都较强,而白骨壤对镉(Cd)富集能力较强,转运能力却较弱,这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。  相似文献   
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The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li2CO3 (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   
4.
基于正交匹配追踪的声层析方法   总被引:2,自引:0,他引:2  
声速剖面的变化会对声传播产生较大的影响,经验正交函数模型经常用来实现对声速剖面数据的简化描述。然而在内波、湍流等海水不均匀性存在时,这种正则化操作会造成声速重构精度的大幅降低。本文利用字典学习生成声速剖面的非正交原子,在稀疏编码时采用正交匹配追踪(OMP,Orthogonal Matching Pursuit)算法,更新字典则使用KSVD (Kernel Singular Value Decomposition)的字典更新算法。由于字典学习不需要强制使用正交条件,对于训练数据更加灵活,从而可以使用少数的原子组合达到更高的重构精度。利用一次浅海声学实验多次测量的声速剖面研究了海水声速剖面的经验正交函数表示和字典学习,研究表明:相比于正交函数表示,学习字典可以利用少数原子(甚至一个原子)更好的解释声速剖面扰动。字典学习可以提高声速剖面的稀疏性,从而提高声速剖面的反演精度。  相似文献   
5.
We present optical luminosity functions(LFs) of galaxies in the~(0.1) g,~(0.1) r,~(0.1) i bands, calculated using data in~40 deg~2 sky area of the LAMOST Complete Spectroscopic Survey of Pointing Area(LaCoSSPAr) in the Southern Galactic Cap. Redshifts for galaxies brighter than r = 18.1 were obtained mainly with LAMOST. In each band, LFs derived using both parametric and non-parametric maximum likelihood methods agree well with each other. In the0.1 r band, our fitting parameters of the Schechter function are φ_*=(1.65 ± 0.36) × 10~(-2) h~3 Mpc~(-3), M_*=-20.69 ± 0.06 mag and α =-1.12 ± 0.08,which agree with previous studies. Separate LFs are also derived for emission line galaxies and absorption line galaxies. The LFs of absorption line galaxies show a dip at~(0.1) r ~18.5 and can be fitted well by a double-Gaussian function, suggesting a bimodality in passive galaxies.  相似文献   
6.
对潜艇装备作战能力评估问题进行了研究,发现运用定量评估方法的过程中存在指标评价所需数据无法完全获取的问题。结合美弗吉尼亚潜艇改进情况,分析了影响潜艇作战能力的一些关键因素,重点基于潜艇武器装载能力,对国外典型潜艇进行了作战能力比较分析,最后对分析结果进行了评价,并讨论了未来潜艇作战能力评估方法的发展方向。  相似文献   
7.
随着海洋生态系统模型的发展,生态变量增多,众多生物过程参数量值的确定成为制约生态环境模拟的瓶颈问题,生态系统结构区域性要求模型中的生态参数具有区域差异。为探究不同海区的关键参数及参数敏感度的空间差异,本研究在渤、黄海建立了ROMS-CoSiNE物理–生物耦合的高分辨率生态系统模型,并对13种生态参数的敏感度空间分布进行分析。结果表明:南黄海中部与渤海及近岸海域的敏感度差异较大。渤海敏感度最大的参数为决定光合速率的浮游植物P-I曲线初始斜率,其次为浮游动物捕食半饱和常数和浮游动物最大捕食率。而南黄海中部敏感度最大的参数为浮游动物最大捕食率,其次为浮游植物死亡率和浮游植物P-I曲线初始斜率。结合敏感度分布及浮游植物生物量收支得出,渤海水体透明度较南黄海偏低、浮游植物生长光限制较强,是引起浮游植物P-I曲线初始斜率敏感度在渤海高于黄海的主要原因。浮游动物最大捕食率及浮游植物死亡率的敏感度空间差异,受渤、黄海浮游植物生物量差异的影响,与生态系统中的高度非线性特征有关。  相似文献   
8.
Increasing concentrations of atmospheric carbon dioxide are causing oceanic pH to decline worldwide, a phenomenon termed ocean acidification. Mounting experimental evidence indicates that near-future levels of CO2 will affect calcareous invertebrates such as corals, molluscs and gastropods, by reducing their scope for calcification. Despite extensive research into ocean acidification in recent years, the effects on non-calcifying anthozoans, such as sea anemones, remain little explored. In Western Europe, intertidal anemones such as Actinia equina are abundant, lower trophic-level organisms that function as important ecosystem engineers. Changes to behaviours of these simple predators could have implications for intertidal assemblages. This investigation identified the effects of reduced seawater pH on feeding and contest behaviour by A. equina. Video footage was recorded for A. equina feeding at current-day seawater (pH 8.1), and the least (pH 7.9) and most (pH 7.6) severe end-of-century predictions. Footage was also taken of contests over ownership of space between anemones exposed to reduced pH and those that were not. No statistically significant differences were identified in feeding duration or various aspects of contest behaviour including initiating, winning, inflating acrorhagi, inflicting acrorhagial peels and contest duration. Multivariate analyses showed no effect of pH on a combination of these variables. This provides contrast with other studies where anemones with symbiotic algae thrive in areas of natural increased acidity. Thus, novel experiments using intraspecific contests and resource-holding potential may prove an effective approach to understand sub-lethal consequences of ocean acidification for A. equina, other sea anemones and more broadly for marine ecosystems.  相似文献   
9.
In this paper, we study an interacting holographic dark energy model in the framework of fractal cosmology. The features of fractal cosmology could pass ultraviolet divergencies and also make a better understanding of the universe in different dimensions. We discuss a fractal FRW universe filled with the dark energy and cold dark matter interacting with each other. It is observed that the Hubble parameter embraces the recent observational range while the deceleration parameter demonstrates an accelerating universe and a behavior similar to \(\Lambda \mbox{CDM}\). Plotting the equation of state shows that it lies in phantom region for interaction mode. We use \(\mathit{Om}\)-diagnostic tool and it shows a phantom behavior of dark energy which is a condition of avoiding the formation of black holes. Finally we execute the StateFinder diagnostic pair and all the trajectories for interacting and non-interacting state of the model meet the fixed point \(\Lambda \mbox{CDM}\) at the start of the evolution. A behavior similar to Chaplygin gas also can be observed in statefinder plane. We find that new holographic dark energy model (NHDE) in fractal cosmology expressed the consistent behavior with recent observational data and can be considered as a model to avoid the formation of black holes in comparison with the main model of NHDE in the simple FRW universe. It has also been observed that for the interaction term varying with matter density, the model generates asymptotic de-Sitter solution. However, if the interaction term varies with energy density, then the model shows Big-Rip singularity. Using our modified CAMB code, we observed that the interacting model suppresses the CMB spectrum at low multipoles \(l<50\) and enhances the acoustic peaks. Based on the observational data sets used in this paper and using Metropolis-Hastings method of MCMC numerical calculation, it seems that the best value with \(1\sigma \) and \(2\sigma \) confidence interval are \(\Omega _{m0}=0.278^{+0.008~+0.010} _{-0.007~-0.009}\), \(H_{0}=69.9^{+0.95~+1.57}_{-0.95~-1.57}\), \(r_{c}=0.08^{+0.02~+0.027}_{-0.002~-0.0027}\), \(\beta =0.496^{+0.005~+0.009} _{-0.005~-0.009}\), \(c= 0.691^{+0.024~+0.039}_{-0.025~-0.037}\) and \(b^{2}=0.035\) according to which we find that the proposed model in the presence of interaction is compatible with the recent observational data.  相似文献   
10.
Solar activity behaviour on the eve of the Maunder minimum may provide important information on the period of further suppression of sunspot population. We analyse sunspot positions and areas in the 1630s extracted from rare drawings published by Pierre Gassendi in Opera Omnia. This work was published in two different editions, the first in Lyon and the second almost 70 years later in Florence. The drawings published in Lyon are found to be slightly different from those published in Florence, which produces a discrepancy in the position of spots of a few degrees, while sunspot group areas may differ by a factor of two. We reveal that the orientation of the drawings in the book is not always the same as might be seen in the telescope. We conjecture that the time of Gassendi’s observations covers the beginning of a new Schwabe cycle in the southern hemisphere. The differential rotation rate in the 1630s is also assessed and discussed.  相似文献   
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