Mussels document loss of bioavailable polycyclic aromatic hydrocarbons and the return to baseline conditions for oiled shorelines in Prince William Sound, Alaska     

Page DS  Boehm PD  Brown JS  Neff JM  Burns WA  Bence AE 《Marine environmental research》2005,60(4):422-436

Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.  相似文献   

Major element chemistry of Galapagos Rift Zone magmas and their phenocrysts     

Martin R. Fisk  A.E. Bence  J.-G. Schilling 《Earth and Planetary Science Letters》1982,61(1):171-189

Basalts dredged from the Galapagos Rift Zone between 85°W and 100°W were analyzed by electron microprobe to determine the chemistry of the glass exteriors and included phenocrysts, microphenocrysts and quench minerals. The basalts come from both “normal” mid-ocean ridge segments and from ridge segments that cross the Galapagos Platform. The basalts fall into two chemical and geographical groups. Group A basalts come from outside the central region of the Galapagos Platform (i.e., outside 89–92.5°W) and are chemically similar to basalts from “normal” ocean ridge segments. Group B basalts come from the center of the Galapagos Platform (89–92.5°W) and are enriched in incompatible elements like “plume-influenced” basalts from the Mid-Atlantic Ridge. The spinel, olivine, plagioclase and clinopyroxene phenocrysts in both groups of basalts are low-pressure, equilibrium phases, but the chemical difference among basalts from within each group indicates high-pressure fractional crystallization is also responsible for the chemical evolution of some of these basalts. Presently, no crystallization or partial melting model can relate the chemistry of the two groups of basalts and the compositional influence of a large-ion-lithophile elements and water-rich mantle beneath the Galapagos Platform is a viable alternate hypothesis. The eruption temperature of magmas from the “normal” ridge segments, as determined by olivine-liquid thermometry is 1217±10°C, suggesting steady-state conditions but on the Galapagos Platform the eruption temperatures are lower and more variable than on the “normal” ridge (1186°C±30°C) suggesting a more complex plumbing system and the absence of a steady-state magma chamber beneath the platform.  相似文献   

Petrogenesis of basalts from the project FAMOUS area: experimental study from 0 to 15 kbars   总被引：1，自引：0，他引：1  

J.F. Bender  F.N. Hodges  A.E. Bence 《Earth and Planetary Science Letters》1978,41(3):277-302

Tholeiitic basalt glasses from the FAMOUS area of the Mid-Atlantic Ridge are among the most primitive basaltic liquids reported from the ocean basins. One of the more primitive of these[Mg/(Mg+Fe²⁺) = 0.68;Ni= 232ppm;TiO₂ = 0.61] glasses (572-1-1) was selected for an experimental investigation. This study found olivine to be the liquidus phase from 1 atm to 10.5 kbar where it is replaced by clinopyroxene. The sequence of appearance of phases at 1 atm pressure is olivine (1268°C), plagioclase (1235°C) and clinopyroxene (1135°C). The sample is multiply saturated at 10.5 kbar with olivine (Fo₈₈), clinopyroxene (Wo₃₂En₆₀Fs₉), and orthopyroxene (Wo₅En₈₃Fs₁₂). From the 1-atm data we have measured (FeO/MgO) olivine/(FeO*/MgO) liquid (K′_D) for olivine-melt pairs equilibrated at 12 temperatures in the range 1268–1205°C.K′_D varies from 0.30 at 1205°C to 0.27 at 1268°C. Analysis of high-pressure olivine melt pairs indicates a systematic increase inK′_D with pressure.Evaluation of the 1-atm experiments reveals that fractionation of olivine followed by olivine + plagioclase can generate much of the variation in major element chemistry observed in the FAMOUS basalt glasses. However, it cannot account for the entire spectrum of glass compositions — particularly with respect to TiO₂ and Na₂O. The variations in these components are such as to require different primary liquids.Comparison of clinopyroxene microphenocrysts/xenocrysts found in oceanic tholeiites with experimental clinopyroxenes reveal that the majority of those in the tholeiites may have crystallized from the magma at pressures greater than ～ 10 kbar and are not accidental xenocrysts. Clinopyroxene fractionation at high pressures may be a viable mechanism for fractionating basaltic magmas.The major and minor element mineral/meltK′_d's from our experiments have been used to model the source region residual mineralogy for given percentages of partial melting. These data suggest that ～20% partial melting of a lherzolite source containing 0–10% clinopyroxene can generate the major and minor element concentrations in the parental magmas of the Project FAMOUS basalt glasses.  相似文献   

Chemical characteristics of island-arc basalts: Implications for mantle sources   总被引：3，自引：0，他引：3  

M.R. Perfit  D.A. Gust  A.E. Bence  R.J. Arculus  S.R. Taylor 《Chemical Geology》1980,30(3):227-256

Major-element, trace-element and isotopic compositions of approximately 1200 basalts (< 53 wt. % SiO₂) from intra-oceanic island arcs have been compiled to assess the nature and possible sources of primitive island-arc basalts (IAB). The chemical characteristics of IAB are examined with reference to those of mid-ocean ridge basalts (MORB) and intraplate oceanic basalts (IPB). Major-element compositions of primitive [$\text{Mg}\text{(}\text{Mg +Fe}{}^{\mathrm{2+}}\text{)}\text{> 65}$] IAB and MORB are similar, but differ significantly from IPB. In general, IAB do not have higher Al₂O₃, lower TiO₂ or a lack of Fe enrichment compared to primitive MORB but many do have greater K₂O contents. Differences in major- and minor-element contents between more evolved IAB and MORB result from the dominance of plagioclase + olivine crystal fractionation in MORB magmas vs. clinopyroxene + olivine controlled fractionation in IAB suites. This difference in crystallization history may be related to the higher P_H2O or greater depth of crystallization of IAB magmas compared to those inferred for MORB.IAB are characteristically enriched in large-ion-lithophile (LIL) elements and depleted in high-field-strength ions (e.g., Zr, Nb and Hf) relative to normal MORB (N-type) and IPB. The enrichment of some LIL elements (e.g., Sr, Rb, Ba and Pb) relative to the rare-earth elements in IAB is difficult to explain by simple partial melting alone and suggests a multistage petrogenesis involving an LIL-enriched component. Low abundances of high-field-strength ions in evolved IAB are explicable in terms of fractional crystallization, but the cause for consistently low abundances in primitive IAB remains problematic.Island-arc lavas contain greater concentrations of volatiles and have higher $\text{CO}{}_2\text{H}{}_2\text{O}$ and Cl/F ratios than either MORB or IPB, suggesting involvement of a slab-derived volatile component. However, this is not consistent with ${}^3\text{He}{}^4\text{He}$ data which indicate that only near-trench volcanics have been significantly affected by dehydration of the oceanic crust.Sr-, Nd-, Pb- and O-isotopic data, in conjunction with the trace-element data, clearly indicate that IAB are derived from heterogeneous, LIL-depleted mantle sources most similar to those which give rise to enriched MORB (E-type). The marked shift towards higher ${}^{87}\text{Sr}{}^{86}\text{Sr}$ in IAB compared to oceanic lavas with similar ${}^{143}\text{Nd}{}^{144}\text{Nd}$ values cannot be explained simply by the addition of radiogenic Sr from the slab. Variable degrees of contamination from a crustally-derived sedimentary component is consistent with the isotopic and trace-element data from a number of arcs. However, the lack of correlation between LIL/REE ratios and more radiogenic isotopic ratios suggests that this enrichment/contamination process is complex. A multi-stage petrogenetic model involving subducted oceanic crust (± sediments), dehydration/volatile transfer, and partial melting of metasomatized mantle beneath island arcs is considered the most reasonable, although least constrained, method to generate a variety of primitive IAB.  相似文献   

Periastron precession measurements in transiting extrasolar planetary systems at the level of general relativity     

András Pál  Bence Kocsis 《Monthly notices of the Royal Astronomical Society》2008,389(1):191-198

Transiting exoplanetary systems are surpassingly important among the planetary systems since they provide the widest spectrum of information for both the planet and the host star. If a transiting planet is on an eccentric orbit, the duration of transits T _D is sensitive to the orientation of the orbital ellipse relative to the line of sight. The precession of the orbit results in a systematic variation in both the duration of individual transit events and the observed period between successive transits,   P _obs  . The periastron of the ellipse slowly precesses due to general relativity and possibly the presence of other planets in the system. This secular precession can be detected through the long-term change in   P _obs  (transit timing variations, TTV) or in T _D (transit duration variations, TDV). We estimate the corresponding precession measurement precision for repeated future observations of the known eccentric transiting exoplanetary systems (XO-3b, HD 147506b, GJ 436b and HD 17156b) using existing or planned space-borne instruments. The TDV measurement improves the precession detection sensitivity by orders of magnitude over the TTV measurement. We find that TDV measurements over a approximately 4 yr period can typically detect the precession rate to a precision well exceeding the level predicted by general relativity.  相似文献   

A study of the geophysical response of distributed fibre optic acoustic sensors through laboratory‐scale experiments          下载免费PDF全文

Bence Papp  Daniela Donno  James E. Martin  Arthur H. Hartog 《Geophysical Prospecting》2017,65(5):1186-1204

In the past few years, distributed acoustic sensing has gained great interest in geophysics. This acquisition technology offers immense improvement in terms of efficiency when compared with current geophysical acquisition methods. However, the fundamentals of the measurement are still not fully understood because direct comparisons of fibre data with conventional geophysical sensors are difficult during field tests. We present downscaled laboratory experiments that enabled us to characterise the relationship between the signals recorded by conventional seismic point receivers and by distributed fibre optic sensors. Interrogation of the distributed optical fibre sensor was performed with a Michelson interferometer because this system is suited to compact test configurations, and it requires only a very simple data processing workflow for extracting the signal outputs. We show acoustic data that were recorded simultaneously by both the fibre optical interferometer and conventional three‐component accelerometers, thus enabling the comparison of sensor performance. We present results focused on the directionality of fibre measurements, on the amplitude variation with angle of incidence, and on the transfer function that allows accelerometer signals to be transformed into optical fibre signals. We conclude that the optical fibre response matches with the array of the displacement differences of the inline accelerometers deployed along the fibre length. Moreover, we also analysed the influence of various types of coupling and fibre cable coating on the signal responses, emphasising the importance of these parameters for field seismic acquisitions when using the distributed fibre optic technology.  相似文献   

A hierarchical approach measures the aerial extent and concentration levels of PAH-contaminated shoreline sediments at historic industrial sites in Prince William Sound, Alaska     

Page DS  Brown JS  Boehm PD  Bence AE  Neff JM 《Marine pollution bulletin》2006,52(4):367-379

A field study was conducted in 2003 to estimate the areal distribution and concentrations of polycyclic aromatic hydrocarbons (PAH) in intertidal sediments at sites of past human and industrial activity (HA sites) in Prince William Sound (PWS), Alaska, the site of the 1989 Exxon Valdez oil spill. More than 50 HA sites, primarily in western PWS, were identified through analysis of historic records and prior field studies, and nine sites were selected for detailed surveys. The areal assessment process consisted of seven steps: (1) identify site from historic records and field surveys; (2) locate visual evidence of surface oil/tar at a site; (3) prepare a site map and lay out a sampling grid over the entire site with 10-m grid spacing; (4) excavate pits to 50 cm depth on the grid; (5) perform a field colorimetric test to estimate total PAH (TPAH) in sediments from the wall of each pit and record the results in the ranges <1 ppm; 1-10 ppm; >10 ppm TPAH; (6) expand grid size if necessary if elevated PAH levels are detected colorimetrically; (7) select 20 samples from each site for same-day shipboard PAH analysis by immunoassay (SDI RaPID PAH) and, based on these results, select sediment samples from each site for full PAH analysis in the laboratory to identify PAH sources. A total of 416 pits were dug at the nine sites. Nine acres of sediments with TPAH >2500 ppb dry wt. were mapped at the nine sites. TPAH concentrations obtained by immunochemical analysis of 181 samples from the nine sites ranged from 20 to 1,320,000 ppb (wet wt.). The contaminants are mixtures of petroleum products (2-3 ring PAH) and combustion products (4-6 ring PAH) unrelated to the 1989 Exxon Valdez oil spill. Mussels and clams collected at these sites have elevated levels of PAH that are compositionally similar to the PAH in the sediments. These findings indicate that at least a portion of the sediment PAH is bioavailable. The PAH sources at these historic industrial sites are chronic. They include relict fuel oil tanks and works located above and within the intertidal zone, with contamination at some locations extending into nearshore sub-tidal sediments. This study shows how a hierarchical approach can be used to quickly and successfully map, quantify, and subsequently, identify sources of PAH in shoreline sediments.  相似文献   

Apollo 12 clinopyroxenes: Exsolution and epitaxy     

J.J. PapikeA.E. Bence  G.E. BrownC.T. Prewitt  C.H. Wu 《Earth and Planetary Science Letters》1971

Clinopyroxenes from rocks 12021, 12037, and 12052 have been studied by electron microprobe and single-crystal X-ray diffraction techniques in order to characterize the crystal-chemical aspects of pyroxene epitaxy and exsolution. The combined chemical and crystallographic data plotted on a Di-Hed-En-Fs data display, based on the unit-cell parameters b and β, suggest a large miscibility gap at low temperature between Ca-rich augite and Ca-poor pigeonites over a large range of Fe/Mg ratios. We also find that in rocks 12021 and 12037 primary pigeonites exsolved augites on both (001) and (100) while primary augites exsolved pigeonite on (001). In rock 12052 the common plane shared by pigeonite cores and epitaxial augite rims is approximately parallel to (100) and little subsolidus exsolution is indicated.  相似文献   

Basalts as probes of planetary interiors: Constraints on the chemistry and mineralogy of their source regions     

A.E. Bence  T.L. Grove  J.J. Papike 《Precambrian Research》1980,10(3-4)

Basalt magmas, derived by the partial melting of planetary interiors, have compositions that reflect the pre-accretionary history of the material from which the planet formed, the planets, subsequent evolutionary history, the chemistry and mineralogy of the source regions, and the intensive thermodynamic parameters operating at the source and emplacement sites. Studies of basalt suites from the Earth, its Moon, and the eucrite parent body reveal compositional differences intrinsic to their source regions which are, in turn, a characteristic of the planet and its formational and evolutionary history.Major interplanetary differences are observed in iron, , TiO₂, Al₂O₃, Na₂O, Cr, Ni, and in volatile element abundances. The most primitive mare basalts have Mg#s 0.6, on the Earth they are 0.70–0.72 for mid-ocean ridge basalts (MORBs) and up to 0.9 for Archean peridotitic komatiites. Eucrites have Mg#s approaching 0.5 (excepting Binda). These differences reflect inherent differences in of their sources. Striking differences in the TiO₂ abundances of the planetary basalts reflect both inter- and intra-planetary variations in source chemistry. Primitive MORBs and primitive oceanic intraplate tholeiites have a factor of 2–3 difference in TiO₂ at comparable Mg# (0.7–1.2 vs 2–3 wt.% respectively). Three major titania groups are recognized in the mare suite; high TiO₂ (8–13 wt.%), low TiO₂ (2–5 wt.%) and very low TiO₂ (<1 wt.%). The eucrites have TiO₂ contents <1 wt.%.The mare basalts and eucrites have pronounced Na₂O depletion relative to all terrestrial basalts. This is a consequence of the preplanetary accretion loss of volatiles from the material that formed the Moon and the eucrite parent bodies.Mare basalts have consistently lower Al₂O₃ contents than the terrestrial basalts. This may be due either to an inherently lower content of Al₂O₃ in the mare sources or it may reflect Al₂O₃ retention in an aluminous phase.The transition metals are fractionated in all three basalt suites. For terrestrial basalts this may reflect core-separation; however, in the case of the Moon and eucrite parent bodies pre-accretionary separation of metal and silicates is a more reasonable explanation. A pronounced Cr anomaly is observed in terrestrial MORBs but not in the mare basalts. This appears to be related to f_O2 differences in the respective mantles.Overall rare earth element abundances are comparable between all three objects. Mare basalts have a pronounced negative Eu anomaly which is inherited from their source region and is record of plagioclase removal from crystallizing magma ocean early in lunar history (4.4–4.6 Ga). Early separation of plagioclase on the Earth appears to have been a relatively unimportant process.  相似文献   

Cosmological physics with black holes (and possibly white dwarfs)     

Kristen Menou  Zoltan Haiman  Bence Kocsis 《New Astronomy Reviews》2008,51(10-12):884

The notion that microparsec-scale black holes can be used to probe gigaparsec-scale physics may seem counterintuitive, at first. Yet, the gravitational observatory LISA will detect cosmologically-distant coalescing pairs of massive black holes, accurately measure their luminosity distance and help identify an electromagnetic counterpart or a host galaxy. A wide variety of new black hole studies and a gravitational version of Hubble’s diagram become possible, if host galaxies are successfully identified. Furthermore, if dark energy is a manifestation of large-scale modified gravity, deviations from general relativistic expectations could become apparent in a gravitational signal propagated over cosmological scales, especially when compared to the electromagnetic signal from a same source. Finally, since inspirals of white dwarfs into massive black holes at cosmological distances may permit pre-merger localizations, we suggest that careful monitoring of these events and any associated electromagnetic counterpart could lead to high-precision cosmological measurements with LISA.  相似文献