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1.
Edward P. F. Rose 《Geology Today》2019,35(3):107-114
During the Second World War, the Allied invasion of the French coast of Normandy on D‐Day, 6 June 1944, was the greatest amphibious assault in world history. An article in Geology Today (v.11, for 1995, pp.58–63) marked the 50th anniversary of the end of the war in Europe, on 8 May 1945, by describing how British military geologists had participated in planning for D‐Day and in the NW Europe campaign that followed it. The work of these geologists provides a classic case history, revealing that ‘military geology’ has many potential applications. Geological factors influenced site selection for temporary airfields, predictions of trafficability for the Normandy beaches, the development of potable water supplies, and quarrying for road metal—and more besides. This new article helps to mark the 75th anniversary of D‐Day by further details of how geologists and geology contributed to Allied victory. 相似文献
2.
Steven J. Ostro Lance A. M. Benner Christopher Magri Jon D. Giorgini Randy Rose Raymond F. Jurgens Donald K. Yeomans Alice A. Hine Michael C. Nolan Daniel J. Scheeres Stephen B. Broschart Mikko Kaasalainen Jean‐Luc Margot 《Meteoritics & planetary science》2005,40(11):1563-1574
Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object. 相似文献
3.
P. A. M. Van Hoof M. E. Foord R. F. Heeter J. E. Bailey H.-K. Chung M. E. Cuneo W. H. Goldstein V. Jonauskas F. P. Keenan R. Kisielius D. A. Liedahl C. Ramsbottom S. J. Rose P. T. Springer R. S. Thoe 《Astrophysics and Space Science》2005,298(1-2):147-153
In experiments at the high-power Z-facility at Sandia National Laboratory in Albuquerque, New Mexico, we have been able to
produce a low density photoionized laboratory plasma of Fe mixed with NaF. The conditions in the experiment allow a meaningful
comparison with X-ray emission from astrophysical sources. The charge state distributions of Fe, Na and F are determined in
this plasma using high resolution X-ray spectroscopy. Independent measurements of the density and radiation flux indicate
unprecedented values for the ionization parameter ξ = 20–25 erg cm s−1 under nearly steady-state conditions. First comparisons of the measured charge state distributions with X-ray photoionization
models show reasonable agreement, although many questions remain. 相似文献
4.
David M. Sherman Caroline L. Peacock Christopher G. Hubbard 《Geochimica et cosmochimica acta》2008,72(2):298-310
Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)2UO2(H2O)n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO2-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)2UO2(H2O)3 which can form on the dominant {101} surface. However, in the presence of CO2, we find an enhancement of UO2 sorption at low pH and attribute this to a (>FeO)CO2UO2 ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)2UO2CO3. The three proposed surface complexes, (>FeOH)2UO2(H2O)3, >FeOCO2UO2, and (>FeOH)2UO2CO3 are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO2-OH-CO3 aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO2 environments at surface loadings of 0.02-2.0 wt% U. 相似文献
5.
Martin R. Lee Mark E. Hodson Maureen MacKenzie Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975
Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction. 相似文献
6.
7.
The prevalence of dermal neoplasia among neotenic tiger salamanders (Ambystoma tigrinum) collected from the Reese Air Force Base sewage lagoon far exceeded that among salamanders from nearby uncontaminated lagoons. Perylene was the predominant pglycyclic aromatic hydrocarbon contaminant in this lagoon. Perylene was shown to be a substrate for monooxygenases in skin and liver homogenates and formed DNA-binding metabolites. Perylene exposure appeared to augment subsequent perylene metabolism by dermal enzymes but it was not a strong inducer of hepatic monooxygenases. Aroclor 1254 induced benzo(a)pyrene and perylene metabolism by both skin and liver enzymes. However, perylene apparently was not activated by salamander enzymes, as suggested by its lack of in vitro mutagenicity and failure to induce tumors. 相似文献
8.
Geologic relations indicate that silica phases transformed in the Monterey Formation in two zones that persist over a narrow
depth/temperature range and do not stratigraphically overlap. The wide and overlapping range of reported temperatures of these
transformations is mainly a result of the many uncertainties inherent in the different methods used to estimate temperature
and does not indicate that phases transform throughout these ranges. Our approach to a reliable temperature scale for silica
diagenesis combines as empirical zonation of silica phases with temperature calibration from a sequence at maximum temperature
and depth of burial. 相似文献
9.
10.