The HNCO ring in the Sgr B2 region     

Y.C. Minh  W.M. Irvine   《New Astronomy》2006,11(8):594-599

The large-scale structure associated with the 2′N HNCO peak in Sgr B2 [Minh, Y.C., Haikala, L., Hjalmarson, Å., Irvine, W.M., 1998. ApJ 498, 261 (Paper I)] has been investigated. A ring-like morphology of the HNCO emission has been found; this structure may be colliding with the Principal Cloud of Sgr B2. This “HNCO Ring” appears to be centered at (l,b) = (0.7°,−0.07°), with a radius of 5 pc and a total mass of 1.0 × 10⁵ to 1.6 × 10⁶ M. The expansion velocity of the Ring is estimated to be 30–40 km s⁻¹, which gives an expansion time scale of 1.5 × 10⁵ year. The morphology suggests that collision between the Ring and the Principal Cloud may be triggering the massive star formation in the Sgr B2 cloud sequentially, with the latest star formation taking place at the 2′N position. The chemistry related to HNCO is not certain yet, but if it forms mainly via reaction with the evaporated OCN⁻ from icy grain mantles, the observed enhancement of the HNCO abundance can be understood as resulting from shocks associated with the collision between the Principal Cloud and the expanding HNCO Ring.  相似文献   

Roughness of the lunar soil     

Kari Lumme  Hannu Karttunen  William M. Irvine 《Earth, Moon, and Planets》1985,33(1):19-29

In situ measurements at the lunar surface at millimeter resolution by the Apollo astronauts have been analyzed. Several statistical parameters have been determined for the landing site. The surface roughness has been found to be very nearly gaussian. The root-mean-square slopes have been obtained over scales between 0.5 mm and 5 cm. They steadily decrease with increasing scale length from 58° to 2° and are in reasonable agreement with radar-measured values. The autocorrelation coefficient of the height distribution has also been obtained. It has a scale-length of 0.7 mm.Adjunct Professor at the University of Massachusetts.Visiting Scholar at the University of Massachusetts.  相似文献   

Observations of interstellar HOCO+: abundance enhancements toward the galactic center     

Minh YC  Irvine WM  Ziurys LM 《The Astrophysical journal》1988,334(1):175-181

A survey of the 4(04)-3(03) and 1(01)-0(00) transitions of HOCO+ has been made toward several molecular clouds. The HOCO+ molecule was not observed in any sources except Sgr B2 and Sgr A. The 5(05)-4(04) and 4(14)-3(13) transitions were also detected toward Sgr B2. The results indicate that gas phase CO2 is not a major carbon reservoir in typical molecular clouds. In Sgr B2, the HOCO+ antenna temperature exhibits a peak approximately 2' north of the Sgr B2 central position (Sgr B2[M]) and the 4(04)-3(03) line emission is extended over a approximately 10' x 10' region. The column density of HOCO+ at the northern peak in Sgr B2 is approximately 3 x 10(14) cm-2, and the fractional abundance relative to H2 > or = 3 x 10(-10), which is about 2 orders of magnitude greater than recent predictions of quiescent cloud ion-molecule chemistry.  相似文献   

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Variations in the HCN/HNC abundance ratio in the Orion molecular cloud     

Goldsmith PF  Irvine WM  Hjalmarson A  Elldér J 《The Astrophysical journal》1986,310(1):383-391

We have used observations of the rare isotopes of HCN and HNC to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio [HCN]/[HNC] decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. We determine the kinetic temperature in the regions we have studied from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways than those in the general interstellar cloud material.  相似文献   

Detection of a new interstellar molecular ion, H2COH+ (protonated formaldehyde)     

Ohishi M  Ishikawa SI  Amano T  Oka H  Irvine WM  Dickens JE  Ziurys LM  Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64

A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+.  相似文献   

Nitrogen sulfide in quiescent dark clouds     

McGonagle D  Irvine WM  Ohishi M 《The Astrophysical journal》1994,422(2):621-625

We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models.  相似文献   

Chemical abundances in cold, dark interstellar clouds     

Irvine WM  Ohishi M  Kaifu N 《Icarus》1991,91(1):2-6

The Sun may well have formed in the type of interstellar cloud currently referred to as a cold, dark cloud. We present current tabulations of the totality of known interstellar molecules and of the subset which have been identified in cold clouds. Molecular abundances are given for two such clouds which show interesting chemical differences in spite of strong physical similarities, Taurus Molecular Cloud 1 (TMC-1) and Lynd's 134N (L134N, also referred to as L183). These regions may be at different evolutionary stages.  相似文献   

Treatment of Malting Wastewater in a Granular Sludge Sequencing Batch Reactor (SBR)     

Norbert Schwarzenbeck  Ron Erley  Belinda S. Mc Swain  Peter A. Wilderer  Robert L. Irvine 《洁净——土壤、空气、水》2004,32(1):16-24

Aerobic granular sludge was successfully cultivated in a sequencing batch reactor (SBR) treating wastewater from the malting process with a high content of particulate organic matter. At an organic loading rate of 3.2 kg/(m³ d) COD_total and an influent particle concentration of 0.95 g/L MLSS an average removal of 50% in COD_total and 80% in COD_dissolved could be achieved. A comparison of granular and flocculent sludge grown under the same operating conditions showed no significant difference in removal efficiency although granules exhibited a higher metabolic activity in terms of specific oxygen uptake rate (r_{O2, X}). Two distinct mechanisms of particle removal were observed for granular sludge: during initial granule formation, particles were incorporated into the biofilm matrix. For mature granules, a high level of protozoa growth on the granule surface accounted for the ability to remove particulate COD. Combined evaluation of the development in MLSS content and sludge bed settling rate (i.e., mean derivative of the normalized sludge volume) was found to be an adequate method for monitoring the characteristic settling properties of a granulizing sludge bed. By means of this method, a distinct substrate gradient out of several operating conditions was concluded to have the biggest impact on the formation of aerobic granular sludge.  相似文献   

Supraglacial weathering crust dynamics inferred from cryoconite hole hydrology          下载免费PDF全文

Joseph Mitchell Cook  Andy J. Hodson  Tristram D. L. Irvine‐Fynn 《水文研究》2016,30(3):433-446

Water levels in cryoconite holes were monitored at high resolution over a 3‐week period on Austre Brøggerbreen (Svalbard). These data were combined with melt and energy balance modelling, providing insights into the evolution of the glacier's near‐surface hydrology and confirming that the hydrology of the near‐surface, porous ice known as the ‘weathering crust’ is dynamic and analogous to a shallow‐perched aquifer. A positive correlation between radiative forcing of melt and drainage efficiency was found within the weathering crust. This likely resulted from diurnal contraction and dilation of interstitial pore spaces driven by variations in radiative and turbulent fluxes in the surface energy balance, occasionally causing ‘sudden drainage events’. A linear decrease in water levels in cryoconite holes was also observed and attributed to cumulative increases in near‐surface ice porosity over the measurement period. The transport of particulate matter and microbes between cryoconite holes through the porous weathering crust is shown to be dependent upon weathering crust hydraulics and particle size. Cryoconite holes therefore yield an indication of the hydrological dynamics of the weathering crust and provide long‐term storage loci for cryoconite at the glacier surface. This study highlights the importance of the weathering crust as a crucial component of the hydrology, ecology and biogeochemistry of the glacier ecosystem and glacierized regions and demonstrates the utility of cryoconite holes as natural piezometers on glacier surfaces. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献