Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Upwelling, species, and depth effects on coral skeletal cadmium-to-calcium ratios (Cd/Ca)     

Kathryn A. Matthews  Andréa G. Grottoli  James E. Palardy 《Geochimica et cosmochimica acta》2008,72(18):4537-4550

Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ¹³C or δ¹⁸O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events.  相似文献   

Models of natural and human dynamics in forest landscapes: Cross-site and cross-cultural synthesis   总被引：1，自引：0，他引：1  

Miguel F. Acevedo  J. Baird Callicott  Donald Lyons  Judith Rosales  Magdiel Ablan  Giorgio Tonella  Emilio Vilanova 《Geoforum》2008,39(2):846-866

We synthesize the study of coupled natural and human systems across sites and cultures through a process of simplification and abstraction based on multiple dimensions of human-nature connectedness: satisfaction of basic needs, psycho-cultural connectedness and regulation of use of natural resources. We thus provide both a place-based and general understanding of value-driven anthropogenic environmental change and response. Two questions guide this research: what are the crucial stakeholder values that drive land use decisions and thus land cover change? And how can knowledge of these values be used to make decisions and policies that sustain both the human and natural systems in a place? To explore these questions we build simulation models of four study sites, two in the State of Texas, United States, and two in Venezuela. All include protected areas, though they differ in the specifics of vegetation and land use. In the Texas sites, relatively affluent individuals are legally converting forests to residential, commercial, and industrial uses, while in Venezuela landless settlers are extra-legally converting forests for purposes of subsistence agriculture. Contemporary modeling techniques now facilitate simulations of stakeholder and ecosystem dynamics revealing emergent patterns. Such coupled human and natural systems are currently recognized as a form of biocomplexity. Our modeling framework is flexible enough to allow adaptation to each of the study sites, capturing the essential features of the respective natural and anthropogenic land use changes and stakeholder reactions. The interactions between human stakeholders are simulated using multi-agent models that act on forest landscape models, and receive feedback of the effects of these actions on ecological habitats and hydrological response. The multi-agent models employ a formal logic-based method for the Venezuelan sites and a decision analysis approach using multi-attribute utility functions for the Texas sites, differing more in style and emphasis than in substance. Our natural-systems models are generic and can be tailored according to site-specific conditions. Similar models of tree growth and patch transitions are used for all the study sites and the differing responses to environmental variables are specified for each local species and terrain conditions.  相似文献   

Effect of zinc on regeneration in the fiddler crab Uca pugilator and its interactions with methylmercury and cadmium     

Judith Shulman Weis 《Marine environmental research》1980,3(4):249-255

After multiple autotomy (one chela and six walking legs) fiddler crabs (Uca pugilator) were exposed to zinc chloride, cadmium chloride, methylmercuric chloride or combinations of these metals. Zinc at 1, 3 and 5 ppm had a retarding effect on limb regeneration, which was amplified in water of reduced salinity. Methylmercury at 0·5 ppm and cadmium at 1·0 ppm have previously been found to retard regeneration. When crabs were exposed to meHg and Zn the effects were additive, both in sea water (30% salinity) and in water of reduced salinity (7–8%). However, when crabs were exposed to combinations of Zn and Cd the effects were antagonistic and the rate of regeneration was almost that of controls. In water of 7–8% salinity the Cd effect was greatly intensified and growth was almost totally prevented. The presence of Zn counteracted this and allowed growth and ecdysis to occur.  相似文献   

The Continuous Plankton Recorder: concepts and history, from Plankton Indicator to undulating recorders   总被引：1，自引：0，他引：1  

P. C. Reid  J. M. Colebrook  J. B. L. Matthews  J. Aiken  Continuous Plankton Recorder Team 《Progress in Oceanography》2003,58(2-4):117

Alister Hardy conceived the Continuous Plankton Recorder (CPR) survey in the 1920s as a means of mapping near-surface plankton in space and time, interpreting the changing fortunes of the fisheries and relating plankton changes to hydrometeorology and climatic change. The seed he planted has grown to become the most extensive long-term survey of marine organisms in the world and the breadth of his vision becomes ever more apparent. The survey has now run for over 70 years and its value increases with every passing decade. Operating from ‘ships of opportunity’ the machines used are robust, reliable and easy to handle. Wherever possible, all the sampling and analytical methods have not been changed to maintain the consistency of the time series. Computerisation and the development of new statistical approaches have increased our ability to handle the large quantities of information generated and enhance the sensitivity of the data analyses. This overview, based on almost 900 papers, recounts the various phases in the history of the survey. It starts with the Indicator Survey (1921–1934), the deployment of the first CPR on the Discovery Expedition (1924–1927) and the early CPR survey in the North Sea (1931–1939). The survey reopened in 1946 after the Second World War and expanded across the North Atlantic to North America from 1959. Taxonomic studies were initiated and an emphasis was placed on patterns of distribution, which were seen to reflect the varying oceanographic conditions. The years 1968–1976 saw further expansion with operations even in the American Great Lakes, publication of a Plankton Atlas and initial evidence for a downward trend in plankton biomass. At about this time electronic instrumentation was attached to CPRs to make additional measurements and work was started on the development of a new generation of undulating Continuous Plankton and Environmental Recorders (CPERs). In 1976 the survey moved to Plymouth. Scientific priorities in the UK changed in the subsequent decade and funding became more difficult to secure even though some of the CPR papers being published at the time are now regarded as classics in plankton ecology. In 1988 the UK Natural Environment Research Council (NERC) decided to close the survey. An international rescue operation led to the creation of the Sir Alister Hardy Foundation for Ocean Science (SAHFOS) in 1990, which has continued with consortium funding from a number of countries, and from 1999 again included NERC. The scientific rationale of the survey has gained credibility as concern over climate change and other anthropogenic effects has grown and as the key role that plankton plays as an indicator of large-scale environmental conditions becomes ever more apparent. Recently, the survey became an integral component of the Global Ocean Observation System (GOOS) and expanded into the North Pacific. It plays a complementary role in many large international and multidisciplinary projects and is providing inspiration, advice and support to daughter surveys elsewhere in the world. At the start of a new millennium, Hardy’s vision from the 1920s is a powerful driving force not just in international biological oceanography, but in global environmental science.  相似文献   

Monitoring the status of a mechanical cable while in operation by means of the acoustic emission method     

Patricio A.A. Laura  James R. Matthews 《Ocean Engineering》1985,12(3):211-219

The mechanical cable is an essential element in towing operations, remote control of equipment, salvage operations, civil engineering applications, etc.Failure of these cables can result in loss of life and loss of equipment worth hundreds of thousands of dollars. Obviously then, sensors that can indicate the condition of these cables so that the risk to their continued use and their remaining safe life can be determined when in operation are very important from the point of view of commercial and military interest.This paper presents a brief review of research into failure mechanisms of various cables and the acoustic emission signatures of the various cables under simulated loading. The development of a specific operational monitor for a towed cable system is also given.  相似文献   

Particle acceleration and the decay of soft X-ray non-thermal line broadening in solar flares     

David Alexander  Sarah A. Matthews 《Solar physics》1994,154(1):157-175

The relationship between the production of -ray emitting particles and non-thermal soft X-ray line broadening is investigated. A model of particle acceleration via the stochastic interaction with MHD turbulence is assumed and the time development of the wave energy density derived under the condition of energy conservation between waves and particles. The inferred numbers and energy distribution of accelerated protons for four -ray flares are used to define the wave energy density and its temporal development. The presence of Alfvén wave turbulence is considered as the source of the non-thermal motions in the ambient plasma. These motions are observed as excess widths in the soft X-ray line emission from these events. The decay of the waves via the particle acceleration process is compared with the observed decays of this non-thermal line broadening. Our results show that both the -ray emission and excess soft X-ray line widths in these flares can be explained by the single physical phenomenon of Alfvén wave turbulence.  相似文献   

The near infrared camera on the W.M. Keck telescope     

K. Matthews  B. T. Soifer 《Experimental Astronomy》1994,3(1-4):77-84

The near infrared camera (NIRC) was used for a science demonstration run on the Keck telescope during 16–24 March 1993. The camera used a 256×256 InSb array manufactured by Santa Barbara Research Corporation. Observations were obtained using narrowband and broad band filters from 1 to 2.4 microns, and grisms with a spectral resolution of 0.6 percent in the J, H and K atmospheric windows. The instrument was fully background limited over the entire wavelength range. The sky background was quite low, reaching 14.3 mag/square arc sec in the broadband K _s filter. The image quality of the camera + telescope was excellent, being seeing limited in the range 0.5–0.9.The science demonstration observations of the NIRC on the Keck Telescope included observations of the most distant galaxy known, 4C41.17 at a redshift z=3.8 and the most luminous object known, the IRAS source FSC10214+4724 at a redshift z=2.29. Observations of the radio galaxy address the problem of the alignment effect in high redshift radio galaxies as well as the environments of such systems. FSC10214+4724 appears to be a merging galaxy that is at least 5×10⁸ years old.Based on observations obtained at the W.M.Keck Observatory, which is operated jointly by the California Institute of Technology and the University of CaliforniaThe W.M. Keck Observatory is operated as a scientific partnership between the California Institute of Technology and the University of California. It was made possible by the generous gift of the W.M. Keck foundation and the support of its president, Howard Keck.  相似文献   

A remote unmanned ELF/VLF goniometer receiver in Antarctica     

J.P. Matthews  A.J. Smith  I.D. Smith 《Planetary and Space Science》1979,27(11):1391-1401

In March 1977 an unmanned ELF/VLF goniometer receiving station was deployed on the Antarctic plateau 110 km south south west of the British Antarctic Survey base at Halley. A UHF Telemetry link enabled the ELF and VLF signals to be monitored and recorded at Halley, simultaneously with data from an identical ELF/VLF receiver at Halley. The remote station was designed for unattended operation with a wind driven generator to recharge its battery. Design considerations and problems encountered are discussed and some preliminary results are presented.  相似文献   

Near-infrared spectrophotometry of the satellites and rings of Uranus     

B.T. Soifer  G. Neugebauer  K. Matthews 《Icarus》1981,45(3):612-617

New spectrophotometry from 1.5 to 2.5 μm is reported for the Uranian satellites Titania, Oberon, and Umbriel. A spectrum of the rings of Uranus from 2.0 to 2.4 μm is also reported. No evidence is found for frost covering the surface of the ring material, consistent with the low albedo of the rings (P_K = 0.03) previously reported by Nicholson and Jones (1980). The surfaces of the satellites are found to be covered by dirty water frost. Assuming albedos of the frost and gray components covering the Uranian satellites to be the same as the light and dark faces of Iapetus, radii are derived that are roughly twice those inferred from the assumption of a visual albedo of 0.5.  相似文献