Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province     

Bo Yang  Alan S. Collins  Grant M. Cox  Amber J. M. Jarrett  Steven Denyszyn  Morgan L. Blades  Juraj Farkaš  Stijn Glorie 《Basin Research》2020,32(6):1734-1750

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.  相似文献   

The Fall of the Košice Meteorite          下载免费PDF全文

Pavel P. Povinec  Juraj Tóth 《Meteoritics & planetary science》2015,50(5):851-852

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Heat capacity, entropy, and magnetic properties of jarosite-group compounds     

Juraj Majzlan  Peter Glasnák  Robert A. Fisher  Mary Anne White  Michel B. Johnson  Brian Woodfield  Juliana Boerio-Goates 《Physics and Chemistry of Minerals》2010,37(9):635-651

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:

Sample	Chemical composition	S o/(J mol−1 K−1)
K-jarosite	K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10	427.4 ± 0.7
Na-jarosite	Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00	436.4 ± 4.4
Rb-jarosite	RbFe2.98(SO4)2(OH)5.95(H2O)0.05	411.9 ± 4.1
NH4-jarosite	(NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00	447.2 ± 4.5
Defect jarosite	K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99	412.7 ± 4.1

There are additional configurational entropies of 13.14 and 8.23 J mol⁻¹ K⁻¹ in defect and NH₄-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak broadening for defect and NH₄-jarosite. The fits to the low-temperature (approx. <12 K) C _p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH₄-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H₃O-jarosite (studied previously) and the defect jarosite. H₃O- and defect jarosite are spin glasses and their low-T C _p was fit with the expression C _p = γT + ΣB _j T _j , where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C _p. Surprisingly, the C _p of the K-, Na-, Rb-, and NH₄-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below their Néel transition temperature.  相似文献   

Effect of cofactors of adjusted and unadjusted quantities on their functions     

Juraj Šütti  Reviewer L. Kubáčková 《Studia Geophysica et Geodaetica》1984,28(1):11-18

aamuam uu am a (m u naamuu n) u u (a) uu a uu mu uu. mam (19), (28) naam, m amua am mau u m ¶rt; am amu: a) na ¶rt;um am, n n a uu am u uu a uu; ) ma ¶rt;um am, m aam uu a uu.  相似文献   

The effect of initial data in adjusting conditional observations     

Juraj Šütti  Reviewer J. Kašpar 《Studia Geophysica et Geodaetica》1973,17(2):100-105

Summary In the introduction the effect of neglecting the accuracy of the initial data is mentioned in adjusting conditional observations, because this essentially causes the accuracy of the adjusted quantities to be overrated. The effect of changes (errors) of the initial data is investigated for two cases: a) when the initial data are given, unmeasured quantities; b) when the initial data are given and measured quantities which form the conditions of adjustment (e.g., gyrotheodolite directional angles). This effect was rejected in a change of the corrections, in the vrst case according to (14), and in the second according to (18). The effect of the changes (errors) of the initial data was also investigated with regard to the matrix of the co-factors of the adjusted quantities. This matrix, taking into account the errors of the initial data described by matrixQww, and the errors of the measurements themselves, described by matrix (26), is expressed by (31).Dedicated to 90th Birthday of Professor Frantiek Fiala  相似文献   

Displacement of points determined by spatial intersection     

Juraj Šütti  Reviewer B. Delong 《Studia Geophysica et Geodaetica》1976,20(4):329-337

Summary A procprocedure is presented for the direct determination of the components of the vector of spatial displacement of a point by spatial intersection. The horizontal, vertical and slope distances are determined by integrated surveying systems (electronic tacheometers), and the first survey is adjusted using conditional observations. The vector of displacement on the individual intervals of observation is determined by means of the matrix equation (33) into which it is only necessary to substitute the appropriate vectors of the observational differences.  相似文献   

Orbital Evolution of Příbram and Neuschwanstein     

Leonard Kornoš  Juraj Tóth  Peter Vereš 《Earth, Moon, and Planets》2008,102(1-4):59-65

The orbital evolution of the two meteorites Příbram and Neuschwanstein on almost identical orbits and also several thousand clones were studied in the framework of the N-body problem for 5,000 years into the past. The meteorites moved on very similar orbits during the whole investigated interval. We have also searched for photographic meteors and asteroids moving on similar orbits. There were five meteors found in the IAU MDC database and six NEAs with currently similar orbits to Příbram and Neuschwanstein. However, only one meteor 161E1 and one asteroid 2002 QG46 had a similar orbital evolution over the last 2,000 years.  相似文献   

Detection of smectites in ppm and sub-ppm concentrations using dye molecule sensors     

Marcel?Lofaj  Juraj?BujdákEmail author 《Physics and Chemistry of Minerals》2012,39(3):227-237

Methylene blue and rhodamine 6G were used as molecular sensors for the spectrophotometric titrations of the aqueous colloids of clay minerals (montmorillonite, illite and kaolinite). The dyes adsorbed on colloid particles form molecular aggregates, which exhibit spectral properties significantly different from those of dye solutions. Spectrophotometric titrations provide the most sensitive detection of smectites in aqueous colloids (sub-ppm concentrations); and the sensitivity further increases using second derivative spectroscopy. The endpoint of spectrophotometric titrations can be used for the determination of exchange capacity of the mineral in colloids and in this way to estimate its amount. The method is selective only to expandable clays, which was proven by experiments with kaolinite and illite. Spectrophotometric titrations have promising future in the analysis of clays and can be applied in many fields of geology, mineralogy, chemistry, material sciences or in industry. Its application may expand to the analysis of other nanomaterials built from charged particles and exhibiting metachromasy in the systems with organic dyes.  相似文献   

Isotopic Composition of Waters in the Dem?novská dolina Valley and Its Underground Hydrologic System During Winter and Spring of 2010/2011          下载免费PDF全文

Peter MALIK  Dagmar HAVIAROVA  Anton AUXT  Zuzana GROLMUSOVA  Juraj MICHALKO 《地下水科学与工程》2013,1(2):14-23

In the Dem?novská dolina Cave system (Slovakia) and its vicinity, 32 sampling places for regular observation (in 2-months interval) of δ18O and δ2H in water were established. This monitoring included precipitation waters, waters in the surface streams, waters of the underground hydrological system as well as the dripping seepage waters of the cave system. Altitudinal extent of the area was from 800 m a.s.l. (lowermost cave entrance) to 2024 m a.s.l. (Chopok Mt. on the top of the crystalline range). Initial results show some similarities but also differences within the analyzed water types. For precipitation, a high variability of isotopic composition was confirmed, from quite depleted up to more enriched waters (δ18O from -16.8‰ up to -5.7‰; δ2H from -121.6‰ to -32.7‰). During the recharge process and groundwater/surface water formation, precipitation water is homogenized, what is reflected in much more stable isotope content. The most depleted (δ18O ≈ -11.7‰ to -10.8‰; δ2H ≈ -78.9‰ to -73.4‰) were the waters of surface streams, running from the northern slopes of the Nízke Tatry Mts., formed by crystalline rocks, alochtonous to the under?ground hydrological system. Smaller autochtonous surface water streams (formed in the side valleys of the main karstic canyon) are slightly enriched (heavier, as δ18O ≈ -11.4‰ to -10.6‰; δ2H ≈ -78.3‰ to -71.5‰), what reflects lower altitudes of their watersheds. Interesting is the distribution of the isotope content of the underground streams in the cave system. The most depleted are the underground streams directly (visibly) communicating with surface waters (δ18O≈-11.33±0.13‰; δ2H≈-76.88±1.68‰). Extent of the relationship of underground streams to the autochtonous seepage waters (slow circulation through the fissures) is manifested by respective portion of iso?topically enriched waters–as the underground streams show different isotope composition. The combination of the alochtonous water components (from surface streams reaching the karstic area from the adjacent crystalline via swallow holes) and autochtonous water components (recharged directly in karstified limestones) is visible especially on the subsurface stream of Dem?novka. The most isotopically enriched (heaviest) of all water types are dripping seepage waters (δ18O ≈ -10.4‰ to -9.4‰; δ2H ≈ -71.6‰ to -65.0‰).  相似文献   

A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements     

Vladislav Chrastný  Jan Rohovec  Eva Čadková  Jan Pašava  Juraj Farkaš  Martin Novák 《Geostandards and Geoanalytical Research》2014,38(1):103-110

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.  相似文献