Impact of sediment organic matter quality on the fate and effects of fluoranthene in the infaunal brittle star Amphiura filiformis     

Selck H  Granberg ME  Forbes VE 《Marine environmental research》2005,59(1):19-45

Hydrophobic contaminants, such as polycyclic aromatic hydrocarbons (PAHs) readily adsorb to organic matter. The aim of this study was to determine the importance of the quality of sedimentary organic matter for the uptake, biotransformation and toxicity of the PAH, fluoranthene (Flu), in the infaunal brittle star Amphiura filiformis. Brittle stars were exposed to a base sediment covered by a 2 cm Flu-spiked top layer (30 microg Flu/g dry wt. sed.), enriched to the same total organic carbon content with either refractory or labile organic matter. The labile carbon source was concentrated green flagellate: Tetraselmis spp. The refractory carbon source was lignin from a paper mill. Tissue concentrations of Flu both in disk and arm-fractions were determined as total Flu, parent Flu (i.e. untransformed), aqueous Flu-metabolites, polar Flu-metabolites and tissue residue Flu (i.e. unextractable). Our results showed that sediment particle ingestion is a pathway by which Flu can enter benthic food webs. Flu toxicity (measured as arm-regeneration), but not net accumulation, was dependent on the nutritional quality of the ingested sediment particles. Flu bioaccumulation could not be attributed solely to equilibrium partitioning between organism lipid content and organic content of the sediment. Biotransformation of Flu by brittle stars was very limited and unaffected by organic matter quality. A. filiformis contributed to the downward transport of Flu from the surface sediment to the burrow lining. The limited breakdown of parent Flu by brittle stars and/or microorganisms was relatively higher in burrows compared to surface sediment, and highest in the presence of labile organic matter. Tissue concentrations were higher in disk than in arms, but the proportion of metabolic products relative to parent Flu was higher in arms than in the disk fraction. We estimate that the yearly mobilization of sediment-associated Flu by arm-regeneration in A. filiformis is in the range of 3.8-29.4 microg total Flu eq. m(-2) year(-1) at a sediment concentration of 30 microg Flu/g dry wt. sed.  相似文献   

Evidence for compressionally induced high subsidence rates in the Kurile Basin (Okhotsk Sea)   总被引：1，自引：0，他引：1  

Boris V. Baranov  Reinhard Werner  Kaj A. Hoernle  Ira B. Tsoy  Paul van den Bogaard  Igor A. Tararin 《Tectonophysics》2002,350(1)

A combined volcanological, geochemical, paleo-oceanological, geochronological and geophysical study was undertaken on the Kurile Basin, in order to constrain the origin and evolution of this basin. Very high rates of subsidence were determined for the northeastern floor and margin of the Kurile Basin. Dredged volcanic samples from the Geophysicist Seamount, which were formed under subaerial or shallow water conditions but are presently located at depths in excess of 2300 m, were dated at 0.84±0.06 and 1.07±0.04 Ma with the laser ⁴⁰Ar/³⁹Ar single crystal method, yielding a minimum average subsidence rate of 1.6 mm/year for the northeast basin floor in the Quaternary. Trace element and Sr–Nd–Pb isotope data from the volcanic rocks show evidence for contamination within lower continental crust and/or the subcontinental lithospheric mantle, indicating that the basement presently at 6-km depth is likely to represent thinned continental crust. Average subsidence rates of 0.5–2.0 mm/year were estimated for the northeastern slope of the Kurile Basin during the Pliocene and Quaternary through the determination of the age and paleo-environment (depth) of formation of sediments from a canyon wall. Taken together, the data from the northeastern part of the Kurile Basin indicate that subsidence began in or prior to the Early Pliocene and that subsidence rates have increased in the Quaternary. Similar rates of subsidence have been obtained from published studies on the Sakhalin Shelf and Slope and from volcanoes in the rear of the Kurile Arc. The recent stress field of the Kurile Basin is inferred from the analysis of seismic activity, focal mechanism solutions and from the structure of the sedimentary cover and of the Alaid back-arc volcano. Integration of these results suggests that compression is responsible for the rapid subsidence of the Kurile Basin and that subsidence may be an important step in the transition from basin formation to its destruction. The compression of the Kurile Basin results from squeezing of the Okhotsk Plate between four major plates: the Pacific, North American, Eurasian and Amur. We predict that continued compression could lead to subduction of the Kurile Basin floor beneath Hokkaido and the Kurile Arc in the future and thus to basin closure.  相似文献   

Geochemistry of oceanic carbonatites compared with continental carbonatites: mantle recycling of oceanic crustal carbonate   总被引：11，自引：2，他引：11  

Kaj Hoernle  George Tilton  Mike J. Le Bas  Svend Duggen  Dieter Garbe-Schönberg 《Contributions to Mineralogy and Petrology》2002,142(5):520-542

Major and trace element and Sr-Nd-Pb-O-C isotopic compositions are presented for carbonatites from the Cape Verde (Brava, Fogo, Sáo Tiago, Maio and Sáo Vicente) and Canary (Fuerteventura) Islands. Carbonatites show pronounced enrichment in Ba, Th, REE, Sr and Pb in comparison to most silicate volcanic rocks and relative depletion in Ti, Zr, Hf, K and Rb. Calcio (calcitic)-carbonatites have primary (mantle-like) stable isotopic compositions and radiogenic isotopic compositions similar to HIMU-type ocean island basalts. Cape Verde carbonatites, however, have more radiogenic Pb isotope ratios (e.g. ²⁰⁶Pb/²⁰⁴Pb=19.3-20.4) than reported for silicate volcanic rocks from these islands (18.7-19.9; Gerlach et al. 1988; Kokfelt 1998). We interpret calcio-carbonatites to be derived from the melting of recycled carbonated oceanic crust (eclogite) with a recycling age of ~1.6 Ga. Because of the degree of recrystallization, replacement of calcite by secondary dolomite and elevated ‘¹³C and ‘¹⁸O, the major and trace element compositions of the magnesio (dolomitic)-carbonatites are likely to reflect secondary processes. Compared with Cape Verde calcio-carbonatites, the less radiogenic Nd and Pb isotopic ratios and the negative Ɨ/4 of the magnesio-carbonatites (also observed in silicate volcanic rocks from the Canary and Cape Verde Islands) cannot be explained through secondary processes or through the assimilation of Cape Verde crust. These isotopic characteristics require the involvement of a mantle component that has thus far only been found in the Smoky Butte lamproites from Montana, which are believed to be derived from subcontinental lithospheric sources. Continental carbonatites show much greater variation in radiogenic isotopic composition than oceanic carbonatites, requiring a HIMU-like component similar to that observed in the oceanic carbonatites and enriched components. We interpret the enriched components to be Phanerozoic through Proterozoic marine carbonate (e.g. limestone) recycled through shallow, subcontinental-lithospheric-mantle and deep, lower-mantle sources.  相似文献   

Phytoplankton, nutrients, and transparency in Danish coastal waters     

Søren Laurentius Nielsen  Kaj Sand-Jensen  Jens Borum  Ole Geertz-Hansen 《Estuaries and Coasts》2002,25(5):930-937

We present a comparative analysis of 1400 data series of water chemistry (particularly nitrogen and phosphorus concentrations), phytoplankton biomass as chlorophylla (chla) concentrations, concentrations of suspended matter and Secchi depth transparency collected from the mid-1980s to the mid-1990s from 162 stations in 27 Danish fjords and coastal waters. The results demonstrate that Danish coastal waters were heavily eutrophied and had high particle concentrations and turbid waters. Median values were 5.1 μg chla 1⁻¹, 10.0 mg DW 1⁻¹ of suspended particles, and Secchi depth of 3.6 m. Chlorophyll concentration was strongly linked to the total-nitrogen concentration. The strength of this relationship increased from spring to summer as the concentration of total nitrogen declined. During summer, total nitrogen concentrations accounted for about 60% of the variability in chlorophyll concentrations among the different coastal systems. The relationship between chlorophyll and total phosphorus was more consistant over the year and correlations were much weaker than encountered for total nitrogen. Secchi depth could be predicted with good precision from measurements of chlorophyll and suspended matter. In a multiple stepwise regression model with In-transformed values the two variables accounted for most of the variability in water transparency for the different seasons and the period March–October as a whole (c. 80%). We were able to demonstrate a significant relationship between total nitrogen and Secchi depth, with important implications for management purposes.  相似文献   

Imaging the ramp–décollement geometry of the Chelungpu fault using coseismic GPS displacements from the 1999 Chi-Chi, Taiwan earthquake     

Kaj M. Johnson  Paul Segall 《Tectonophysics》2004,378(1-2):123-139

We use coseismic GPS data from the 1999 Chi-Chi, Taiwan earthquake to estimate the subsurface shape of the Chelungpu fault that ruptured during the earthquake. Studies prior to the earthquake suggest a ramp–décollement geometry for the Chelungpu fault, yet many finite source inversions using GPS and seismic data assume slip occurred on the down-dip extension of the Chelungpu ramp, rather than on a sub-horizontal décollement. We test whether slip occurred on the décollement or the down-dip extension of the ramp using well-established methods of inverting GPS data for geometry and slip on faults represented as elastic dislocations. We find that a significant portion of the coseismic slip did indeed occur on a sub-horizontal décollement located at 8 km depth. The slip on the décollement contributes 21% of the total modeled moment release. We estimate the fault geometry assuming several different models for the distribution of elastic properties in the earth: homogeneous, layered, and layered with lateral material contrast across the fault. It is shown, however, that heterogeneity has little influence on our estimated fault geometry. We also investigate several competing interpretations of deformation within the E/W trending rupture zone at the northern end of the 1999 ground ruptures. We demonstrate that the GPS data require a 22- to 35-km-long lateral ramp at the northern end, contradicting other investigations that propose deformation is concentrated within 10 km of the Chelungpu fault. Lastly, we propose a simple tectonic model for the development of the lateral ramp.  相似文献   

Drastic shift in lava geochemistry in the volcanic-front to rear-arc region of the Southern Kamchatkan subduction zone: Evidence for the transition from slab surface dehydration to sediment melting   总被引：2，自引：0，他引：2  

Svend Duggen  Maxim Portnyagin  Joel Baker  Kaj Hoernle  Nathalie Grassineau 《Geochimica et cosmochimica acta》2007,71(2):452-480

The shift of lava geochemistry between volcanic front to rear-arc volcanoes in active subduction zones is a widespread phenomenon. It is somehow linked to an increase of the slab surface depth of the subducting oceanic lithosphere and increasing thickness of the mantle wedge and new constraints for its causes may improve our understanding of magma generation and element recycling in subduction zones in general. As a case study, this paper focuses on the geochemical composition of lavas from two adjacent volcanic centres from the volcanic front (VF) to rear-arc (RA) transition of the Southern Kamchatkan subduction zone, with the aim to examine whether the shift in lava geochemistry is associated with processes in the mantle wedge or in the subducted oceanic lithosphere or both. The trace element and O-Sr-Nd-Hf-Pb (double-spike)-isotopic composition of the mafic Mutnovsky (VF) and Gorely (RA) lavas in conjunction with geochemical modelling provides constraints for the degree of partial melting in the mantle wedge and the nature of their slab components. Degrees of partial melting are inferred to be significantly higher beneath Mutnovsky (∼18%) than Gorely (∼10%). The Mutnovsky (VF) slab component is dominated by hydrous fluids, derived from subducted sediments and altered oceanic crust, eventually containing minor but variable amounts of sediment melts. The composition of the Gorely slab component strongly points to a hydrous silicate melt, most likely mainly stemming from subducted sediments, although additional fluid-contribution from the underlying altered oceanic crust (AOC) is likely. Moreover, the Hf-Nd-isotope data combined with geochemical modelling suggest progressive break-down of accessory zircon in the melting metasediments. Therefore, the drastic VF to RA shift in basalt chemistry mainly arises from the transition of the nature of the slab component (from hydrous fluid to melt) in conjunction with decreasing degrees of partial melting within ∼15 km across-arc. Finally, systematic variations of key inter-element with high-precision Pb-isotope ratios provide geochemical evidence for a pollution of the Mutnovsky mantle source with Gorely melt components but not vice versa, most likely resulting from trench-ward mantle wedge corner flow. We also present a geodynamic model integrating the location of the Mutnovsky and Gorely volcanic centres and their lava geochemistry with the recently proposed thermal structure of the southern Kamchatkan arc and constraints about phase equilibria in subducted sediments and AOC. Herein, the slab surface hosting the subducted sediments suffers a transition from dehydration to melting above a continuously dehydrating layer of AOC. Wider implications of this study are that an onset of (flush-) sediment melting may ultimately be the main trigger for the VF to RA transition of lava geochemistry in subduction zones.  相似文献   

A study of the spatial structure of the atmospheric boundary layer with a Doppler-Sodar network     

I. G. Granberg  V. F. Kramar  R. D. Kuznetsov  O. G. Chkhetiani  M. A. Kallistratova  S. N. Kulichkov  M. S. Artamonova  D. D. Kuznetsov  V. G. Perepelkin  V. V. Perepelkin  F. A. Pogarskii 《Izvestiya Atmospheric and Oceanic Physics》2009,45(5):541-548

The studies conducted in 1991–2004 by scientists of the A.M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences, and the Karpov Institute of Physical Chemistry yielded data on the structures of the surface air layer (to a height of 20 m) and both subinversion and inversion layers (to heights of from 800 m to 1 km), where arid aerosol is transported. One of the main objectives of the 2007 experiment was to record the space-vortex structures within a layer of 30–700 m that directly provide the removal and long-range transport of fine-dispersed (<5 µm) desert aerosol. This paper describes the organization of the Khar-Gzyr 2007 experiment (Black Lands, 2007) to study the convective removal of arid aerosol from desertificated lands, and it presents some data obtained from the remote sensing of the atmospheric boundary layer with a sodar network in the course of this experiment. The sodar network, which was developed to study a spatial structure of coherent vortices, included three identical minisodars (with carrier frequencies of 3.8 kHz) located at the apices of a triangle, each side of which was about 3.5 km, and a sodar (with a carrier frequency of 1.7 kHz). The vertical profiles of the three wind-velocity components and the characteristics of air temperature fluctuations were determined. The procedure of identifying coherent vortex structures is described. The variations in the vertical and horizontal wind-velocity components and the scales characteristic of such structures are estimated.  相似文献   

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia     

Christian Timm  Kaj Hoernle  Reinhard Werner  Folkmar Hauff  Paul van den Bogaard  James White  Nick Mortimer  Dieter Garbe-Schönberg 《Earth》2010,98(1-2):38-64

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.  相似文献   

A major element,PGE and Re–Os isotope study of Middle Atlas (Morocco) peridotite xenoliths: Evidence for coupled introduction of metasomatic sulphides and clinopyroxene     

Nadine Wittig  D. Graham Pearson  Joel A. Baker  Svend Duggen  Kaj Hoernle 《Lithos》2010,115(1-4):15-26

We present major element and PGE (platinum-group-element) abundances in addition to Re–Os isotope data for 11 spinel-facies whole rock peridotites from a single maar from the Middle Atlas Mountains, Morocco.Major element systematics of these xenoliths are generally correlated with indices of depletion. FeO–MgO systematics appear to suggest spinel-facies melting in the range of 5 to 25%. However, Al₂O₃ abundances in these xenoliths appear elevated relative to primitive mantle (Prima). The Al₂O₃ abundances in conjunction with other major elements require distinct re-enrichment of the Middle Atlas continental mantle root due to melt/rock reaction and precipitation of amphibole and/or clinopyroxene from passing silicate melts akin to MORB or OIB that evolved in reverse direction along the melting curves in e.g. FeO–MgO space. Sc and V confirm the range of apparent depletion and also indicate that the currently preserved fO₂ in these peridotites is distinctly different from fO₂ conditions observed in subduction zones.The majority of these xenoliths have low Os and Ir (I-PGEs) concentrations relative to Prima and modelled sulphide- and clinopyroxene-depleted residues of mantle melting under low fO₂, mid-ocean ridge-like conditions. Moreover, Pt and Pd (P-PGE) abundances are elevated when compared to their expected abundances after substantial melt extraction. Importantly, the systematically low Ir abundances in the majority of samples show well-correlated trends with Al₂O₃, MgO and Cu that are inconsistent with established melting trends. Os isotopes in the Middle Atlas xenoliths range from ¹⁸⁷Os/¹⁸⁸Os = 0.11604 to 0.12664 although most samples are close to chondritic. The Os isotope ratios are decoupled from ¹⁸⁷Re/¹⁸⁸Os but, together with Re abundances, also exhibit a good correlation with Al₂O₃, MgO and Cu.The major element, I-PGE and Os isotope correlations suggest that the initial melt depletion led to the exhaustion of sulphide and clinopyroxene (20 to 30%) without significant stabilization of I-PGE-rich alloys. During later modal metasomatism of the refractory Middle Atlas continental mantle root with silicate melts akin to MORB or OIB the introduction of clinopyroxene/amphibole reduced the volume of the melt inducing sulphur saturation in these melts causing precipitation of secondary sulphides. This coupled crystallization of pyroxenes and sulphides (chalcopyrite) resulted in the two-component mixing systematics exhibited by I-PGEs, Os isotopes with major elements and Cu preserved in the Middle Atlas continental mantle root.  相似文献   

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland     

Björn S. Frengstad  Kaj Lax  Timo Tarvainen  Øystein Jæger  Börge J. Wigum 《Journal of Geochemical Exploration》2010

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.  相似文献