The use of principle component analyses in characterising trace and major elemental distribution in a 55 kyr peat deposit in tropical Australia: Implications to paleoclimate     

Joanne Muller  Malin Kylander  Antonio Martinez-Cortizas  Dominik Weiss  Kevin Blake  Raquel Garcia-Sanchez 《Geochimica et cosmochimica acta》2008,72(2):449-463

The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands.  相似文献   

Effects on UDP glucuronosyl transferase, glutathione transferase, DT-diaphorase and glutathione reductase activities in rainbow trout liver after long-term exposure to PCB     

Lars Frlin  Sonja Blom  Malin Celander  Joachim Sturve 《Marine environmental research》1996,42(1-4)

In the present study, long-term exposure to PCB resulted in marked induction of the xenobiotic biotransformation enzymes UDP glucuronosyl transferase, glutathione transferase and DT-diaphorase (measured as menadione reductase and DCPIP reductase) in rainbow trout 15 or 20 weeks post-injection during the experimental period. The increase of the phase II enzymes were paralleled by a marked increase of the glutathione reductase activity. These results indicate that prolonged exposure to PCB results in increased production of organo-radicals.  相似文献   

Moment-tensor statistics of the 1997 Long Valley microearthquake swarm     

A. Stroujkova  P.E. Malin 《Journal of Seismology》2002,6(1):69-85

Abstract. A simple, fast, moment-tensor inversion method using bandpass-filtered P-amplitudes was used to study the moment-tensor statistics of Long Valley caldera microearthquakes. The events were recorded in the summer of 1997, during a swarm in the caldera. The swarm was associated with geodetic extension, uplift, and subsequent moderate earthquake activity. The moment tensor solutions for 1,993 events were calculated using the new method. The majority of the resulting focal mechanisms appear to be explained in terms of double couple mechanisms. Since some events did exhibit considerable deviation from double-couples, the moment data were studied for their statistical significance. The moments of the actual data were compared to the moments of synthetic data with varying degrees of random noise in their spectra. The results of this study suggested that unless data from more than 20 stations are used and the earthquake epicenter is located inside or very close to the network area, moment-tensor inversion does not correctly resolve the non-double-couple components of microearthquakes. Analysis of the inversion residuals shows that the average noise in the P-wave spectra was close to 20%. The fluctuations of the volumetric components of the moment-tensor are in good agreement with those of the synthetic pure double-couples with 20% of added noise. Thus the moment-tensor statistics suggests that little if any volume change is required to explain the observed seismic energy release in the swarm. However, the statistics do show that a significant compensated-linear-vector-dipole component maybe present in the bulk of the seismicity. Given the network used in this study, such a component could not be precisely resolved for individual earthquakes. This possibility deserves further investigation because of its bearing on the nature of fluid-fault-earthquake processes in swarms.  相似文献   

Refining the pre-industrial atmospheric Pb isotope evolution curve in Europe using an 8000 year old peat core from NW Spain   总被引：1，自引：0，他引：1  

M.E. Kylander  D.J. Weiss  A. Martínez Cortízas  R. Garcia-Sanchez 《Earth and Planetary Science Letters》2005,240(2):467-485

Pb pollution has existed for several millennia and remains relevant today. By using peat cores as environmental archives it is possible to reconstruct this long history on a regional scale. This is a significant contribution to the findings from ice core records, the only other archive recording purely atmospheric additions. Without information that allows linking and comparison between sites regionally, within Europe and elsewhere, our ability to make coherent global models of the natural Pb cycle, and anthropogenic forcing of this cycle, is limited. In this respect, the characteristics of the Pb pre-pollution aerosol (PPA) are important to define globally. We characterize for the first time a PPA in Southern Europe with [Pb] = 0.78 ± 0.86 μg g^− 1, net Pb accumulation rates of 0.032 ± 0.030 mg m^− 2 y^− 1 and a ²⁰⁶Pb / ²⁰⁷Pb signature of 1.25470 ± 0.02575. This PPA Pb isotope signature is more radiogenic than that found thus far in Western and Northern Europe. Spain is a historically important mining site. Using three-isotope plots and a pool of potential Pb isotope signatures, a detailed source appointment of both natural and anthropogenic Pb sources was made. We found evidence of Saharan aridification and its termination ∼4400 BP and/or agricultural signals and strong local control (from rock and soil) of the Pb PPA. Human impact is first recorded at 3210 BP but does not exceed 50% of deposited Pb until 3005 BP. Mines in SE Spain dominate early Pb pollution history at this site. During the rise of Roman rule, contributions come from mines in N, NW and SW Spain with no strong indication of other European mining activities. In Medieval and Industrial times local contributions to the peat bog are reduced.  相似文献   

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho          下载免费PDF全文

L. M. Stevens  J. A. Baldwin  J. M. Cottle  A. R. C. Kylander‐Clark 《Journal of Metamorphic Geology》2015,33(4):385-411

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.  相似文献   

9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR     

Antonio Martínez Cortizas  Jenny K. Sjöström  Eleonor E. Ryberg  Malin E. Kylander  Joeri Kaal  Olalla López-Costas  Noemi Álvarez Fernández  Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   

Lunar tidal componentsN 1 andO 2 in the atmospheric pressure     

S. R. C. Malin  S. Chapman 《Pure and Applied Geophysics》1970,80(1):309-318

Summary The lunar tidal componentsO ₁(p) andN ₂(p) in the barometric pressure are determined for several observatories for which long series of data are available in machine readable form. AlsoN ₂(p) results are derived from some earlier analyses. The results are compared with those predicted by equilibrium tidal theory.This paper was presented at the General Scientific Assembly of I.A.G.A., held in Madrid in September 1969.  相似文献   

Annual variation of the geomagnetic field     

S. R. C. Malin  A. Mete Isikara 《Geophysical Journal International》1976,47(3):445-457

Summary. Horizontal and vertical intensity data, obtained between 1957.0 and 1961.0 at 69 observatories, are analysed to determine the worldwide distribution of the annual variation of the geomagnetic field. Only data observed near local midnight are used, to avoid the small, but significant contamination from Sq. Over most of the world the variation is found to be small, with a clear dependence on latitude, but near the poles it is larger and more erratic. The non-polar variation is subjected to spherical harmonic analysis and separated into parts of internal and external origin. The polar variations are shown to be consistent with a north—south oscillation of the mean position of the auroral electrojets during the year. It is suggested that, with the exception of the polar effect, the annual variation is not due to ionospheric currents (as was hitherto believed), but results from an annual variation in the latitude of the ring current.  相似文献   

The Determination of Lunar Daily Geophysical Variations by the Chapman–Miller Method     

S. R. C. Malin  S. Chapman† 《Geophysical Journal International》1970,19(1):15-35

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Progress in modeling the distribution of elastic inhomogeneities in the lunar crust     

P.E. Malin  Y. Nakamura 《Physics of the Earth and Planetary Interiors》1981,26(4):261-263

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