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Structural similarities between dry diopside melt and superhydrous albite melt (X
w
>0.5) — both lack three-dimensional silicate units — suggest that thermodynamic relations may be similar. A model based on that assumption successfully predicts diopside melting relations and H2O solubilities. For the model, the three partial differential equations describing solution of H2O in albite melt for X
w
>0.5 have been integrated for diopside melt from X
w
=0 to X
w at least as large as 0.76, with two exceptions: an alternative partial differential equation for Henrian solution of H2O in dilute melts was applied for X
w
<0.20, and an alternative differential equation for the pressure dependence of a
w
at pressures below 2 kbar was developed. The latter alternative equation yields relatively small ¯Vw's at low pressures rather than the large ¯Vw's calculated from the equation from the albite system. Available experimental solubility data are not precise enough to offer a choice between the small-¯Vw and large-¯Vw equations. Integration of all the partial differential equations was constrained solely by the P and T of a single experimentally-determined point on the H2O-saturated solidus.Solubilities calculated by a Henrian-analogue solution model (a
di=X
di
2
) from the experimental H2O saturated solidus lie outside experimental solubility constraints for dilute melts. On the other hand, a Henrian model (a
di=Xdi) successfully predicts solubilities in dilute melts. The formulation of the Henrian model and magnitudes of model molar entropies of solution are consistent with the hypothesis that H2O dissolves in diopside melt as an essentially undissociated species with little ordering on melt structural sites. That species could in turn be consistently, if not uniquely, interpreted to be molecular H2O or a hydroxylation (OH–) complex formed from nonbridging oxygens. 相似文献
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Steven L. Morey Mark A. Bourassa Dmitry S. Dukhovskoy James J. O’Brien 《Ocean Dynamics》2006,56(5-6):594-606
A coupled ocean and boundary layer flux numerical modeling system is used to study the upper ocean response to surface heat
and momentum fluxes associated with a major hurricane, namely, Hurricane Dennis (July 2005) in the Gulf of Mexico. A suite
of experiments is run using this modeling system, constructed by coupling a Navy Coastal Ocean Model simulation of the Gulf
of Mexico to an atmospheric flux model. The modeling system is forced by wind fields produced from satellite scatterometer
and atmospheric model wind data, and by numerical weather prediction air temperature data. The experiments are initialized
from a data assimilative hindcast model run and then forced by surface fluxes with no assimilation for the time during which
Hurricane Dennis impacted the region. Four experiments are run to aid in the analysis: one is forced by heat and momentum
fluxes, one by only momentum fluxes, one by only heat fluxes, and one with no surface forcing. An equation describing the
change in the upper ocean hurricane heat potential due to the storm is developed. Analysis of the model results show that
surface heat fluxes are primarily responsible for widespread reduction (0.5°–1.5°C) of sea surface temperature over the inner
West Florida Shelf 100–300 km away from the storm center. Momentum fluxes are responsible for stronger surface cooling (2°C)
near the center of the storm. The upper ocean heat loss near the storm center of more than 200 MJ/m2 is primarily due to the vertical flux of thermal energy between the surface layer and deep ocean. Heat loss to the atmosphere
during the storm’s passage is approximately 100–150 MJ/m2. The upper ocean cooling is enhanced where the preexisting mixed layer is shallow, e.g., within a cyclonic circulation feature,
although the heat flux to the atmosphere in these locations is markedly reduced. 相似文献
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Dmitry S. Dukhovskoy Steven L. Morey Paul J. Martin James J. O&#x;Brien Cortis Cooper 《Ocean Modelling》2009,28(4):250-265
Recent observations over the Sigsbee Escarpment in the Gulf of Mexico have revealed extremely energetic deep currents (near 1 m s−1), which are trapped along the escarpment. Both scientific interest and engineering needs demand dynamical understanding of these extreme events, and can benefit from a numerical model designed to complement observational and theoretical investigations in this region of complicated topography. The primary objective of this study is to develop a modeling methodology capable of simulating these physical processes and apply the model to the Sigsbee Escarpment region. The very steep slope of the Sigsbee Escarpment (0.05–0.1) limits the application of ocean models with traditional terrain-following (sigma) vertical coordinates, which may represent the very complicated topography in the region adequately, can result in large truncation errors during calculation of the horizontal pressure gradient. A new vertical coordinate system, termed a vanishing quasi-sigma coordinate, is implemented in the Navy Coastal Ocean Model for application to the Sigsbee Escarpment region. Vertical coordinate surfaces for this grid have noticeably gentler slopes than a traditional sigma grid, while still following the terrain near the ocean bottom. The new vertical grid is tested with a suite of numerical experiments and compared to a classical sigma-layer model. The numerical error is substantially reduced in the model with the new vertical grid. A one-year, realistic, numerical simulation is performed to simulate strong, deep currents over the Escarpment using a very-high-resolution nested modeling approach. The model results are analyzed to demonstrate that the deep-ocean currents in the simulation replicate the prominent dynamical features of the observed intense currents in the region. 相似文献
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Irish J.D. Morey K.E. Needell G.J. Wood J.D. 《Oceanic Engineering, IEEE Journal of》1991,16(4):319-328
To measure oceanographic parameters such as currents, temperature, conductivity, pressure, and suspended sediment concentrations, two film-recording current meters were upgraded with microprocessor-controlled data recorders and additional sensors. Two telemetry links relay data and allow the in situ operation of the remote instrument to be checked. In one configuration, the bottom-mounted current meter communicated by a 35-m-long wire to a small surface spar buoy, and then by a packet radio link to a nearby ship. In another development, the current meter relays data to a controller and buoyant data capsule on the bottom instrument package. The controller collects and processes the data from the current meter and periodically transfers these processed data to a data capsule and releases it. When released, the capsule rises to the surface and transmits its data to shore via the ARGOS satellite, while acting as a satellite tracked drifter 相似文献
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Maps of satellite-derived estimates of monthly averaged chlorophyll a concentration over the northern West Florida Shelf show interannual variations concentrated near the coastline, but also extending offshore over the shelf in a tongue-like pattern from the Apalachicola River during the late winter and early spring. These anomalies are significantly correlated with interannual variability in the flow rate of the Apalachicola River, which is linked to the precipitation anomalies over the watershed, over a region extending 150–200 km offshore out to roughly the 100 m isobath. This study examines the variability of the Apalachicola River and its impacts on the variability of water properties over the northern West Florida Shelf. A series of numerical model experiments show that episodic wind-driven offshore transport of the Apalachicola River plume is a likely physical mechanism for connecting the variability of the river discharge with oceanic variability over the middle and outer shelf. 相似文献