Electro-chemical mineralization of recalcitrant indole by platinum-coated titanium electrode: multi-response optimization,mechanistic and sludge disposal study     

A. D. Hiwarkar  S. Singh  V. C. Srivastava  C. Thakur  I. D. Mall  S.-L. Lo 《International Journal of Environmental Science and Technology》2018,15(2):349-360

Indole is a highly recalcitrant aromatic heterocyclic organic compound consisting of a five-membered nitrogen-containing pyrrole ring fused to a six-membered benzene ring. This study presents the results of the electro-chemical mineralization of indole in an aqueous solution using platinum-coated titanium (Pt/Ti) electrode. A central composite design was used to investigate the effect of four parameters namely initial pH (pH_o), current density (j), conductivity (k) and treatment time (t) at 5 levels. Multiple responses namely chemical oxygen demand (COD) removal (Y ₁) and specific energy consumption (Y ₂) were simultaneously maximized and minimized, respectively, by optimizing the parameters affecting the mineralization of indole by using the desirability function approach. At the operating conditions of pH 8.6, j = 161 A/m², k = 6.7 mS/cm and t = 150 min, 83.8% COD removal with specific energy consumption of 36.3 kWh/kg of COD removed was observed. Ultra performance liquid chromatography, UV–visible spectroscopy, Fourier transform infrared spectroscopy and cyclic voltammetry of the indole solution were performed at the optimum condition of the treatment so as to report a plausible mechanism of indole degradation. Field emission scanning electron microscopy analysis of electrodes before and after treatment was performed for determining the changes on anode surface during the treatment. Thermal analysis of the solid residue (scum) obtained was also performed for exploring its disposal prospects. Present study shows that electro-chemical oxidation can be used for mineralization of nitrogenous heterocyclic compounds such as indole.  相似文献   

Modeling the effects of the variability of temperature-related dynamic viscosity on the thermal-affected zone of groundwater heat-pump systems     

Lo Russo  Stefano  Taddia  Glenda  Cerino Abdin  Elena 《Hydrogeology Journal》2018,26(4):1239-1247

Thermal perturbation in the subsurface produced in an open-loop groundwater heat pump (GWHP) plant is a complex transport phenomenon affected by several factors, including the exploited aquifer’s hydrogeological and thermal characteristics, well construction features, and the temporal dynamics of the plant’s groundwater abstraction and reinjection system. Hydraulic conductivity has a major influence on heat transport because plume propagation, which occurs primarily through advection, tends to degrade following conductive heat transport and convection within moving water. Hydraulic conductivity is, in turn, influenced by water reinjection because the dynamic viscosity of groundwater varies with temperature. This paper reports on a computational analysis conducted using FEFLOW software to quantify how the thermal-affected zone (TAZ) is influenced by the variation in dynamic viscosity due to reinjected groundwater in a well-doublet scheme. The modeling results demonstrate non-negligible groundwater dynamic-viscosity variation that affects thermal plume propagation in the aquifer. This influence on TAZ calculation was enhanced for aquifers with high intrinsic permeability and/or substantial temperature differences between abstracted and post-heat-pump-reinjected groundwater.

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Seismic risk perception in the aftermath of Wenchuan earthquakes in southwestern China     

Alex Y. Lo  Lewis T. O. Cheung 《Natural Hazards》2015,78(3):1979-1996

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Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)     

D. Lo Pò  R. Braga 《Journal of Metamorphic Geology》2014,32(4):371-387

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.  相似文献   

Influence of food web structure on the biochemical composition of seston,zooplankton and recently deposited sediment in experimental freshwater mesocosms     

Béatrice Allard  Michaël Danger  Loïc Ten-Hage  Gérard Lacroix 《Aquatic Sciences - Research Across Boundaries》2011,73(1):113-126

The effects of food web structure on the quantity and biochemical composition of seston, zooplankton and recently deposited sediment in experimental freshwater mesocosms were examined. Food web structure was manipulated by addition of zooplanktivorous fish. Biochemical characterisations were carried out using lipid biomarkers (sterols, fatty acids, chlorophyll-derived compounds and long-chain alkanediols). Fish addition decreased zooplankton biomass and increased seston biomass and deposited sediment through a trophic cascade. Fish presence strongly influenced the biochemical characteristics of seston and sediment. In contrast, food web structure had a minor impact on the lipid biomarker composition of zooplankton. Although the relative abundance of sterols in the different compartments did not differ strongly between treatments, sterol profiles in seston and sediment depended on food web structure. The predominance of Δ⁷-sterols in seston and sediment in the fish treatment indicated a major contribution of Chlorophyceae. In contrast, the distribution of sterols in seston and sediment in the fishless treatment, dominated by cholesterol, indicated a major zooplanktonic input. The distribution of fatty acids and the relative abundance of chlorophyll-derived compounds and long-chain alkanediols agreed with the predominant contribution of phytoplankton or zooplankton to seston and sediment in the two treatments. The relative abundance of bacterial biomarkers suggested that the contribution of bacteria was rather low. The high relative abundance of polyunsaturated fatty acids (PUFAs) and the absence of stanols in sediments suggested low microbial reworking of organic matter in the recently accumulated sediments. The trophic cascade, generated by the addition of fish, increased the relative abundance of PUFAs in deposited organic matter, thus enhancing sediment quality and potential degradability.  相似文献   

Preface: Proceedings of the 5th International Symposium on Lithographic Limestone and Plattenkalk   总被引：1，自引：0，他引：1  

Daniel Marty  Jean-Paul Billon-Bruyat  Christian A. Meyer  Loïc Costeur  Basil Thüring 《Swiss Journal of Geoscience》2011,104(1):1-29

Magmatic rocks from the pre-Mesozoic basements of the Sambuco and Maggia nappes have been dated by U–Pb zircon ages with the LA-ICPMS technique. Several magmatic events have been identified in the Sambuco nappe. The mafic banded calc-alkaline suite of Scheggia is dated at 540 Ma, an age comparable to that of mafic rocks in the Austroalpine Silvretta nappe. The Sasso Nero peraluminous augengneiss has an age of 480–470 Ma, like many other “older orthogneisses” in Alpine basement units. It hosts a large proportion of inherited zircons, which were dated around 630 Ma, a Panafrican age indicating the Gondwanan affiliation of the Sambuco basement. The calc-alkaline Matorello pluton yielded ages around 300 Ma, similar to numerous Late Carboniferous intrusions in other basement units of the Lower Penninic (Monte Leone, Antigorio, Verampio) and Helvetic domains (Gotthard and other External Crystalline Massifs). Associated lamprophyric dykes are slightly younger (300–290 Ma), like similar dykes sampled in gneiss blocks included in the sedimentary cover of the underlying Antigorio nappe (290–285 Ma). The Cocco granodiorite and Rüscada leucogranite, both intruding the basement of the neighbouring Maggia nappe, yielded ages of ca. 300–310 Ma, identical within errors to the age of the Matorello pluton. They are significantly older than former age determinations. This age coincidence, coupled with remarkable petrologic similarities between the Cocco and Matorello granodiorites, strongly suggests paleogeographic proximity of the Sambuco and Maggia nappes in Late Carboniferous times. In recent publications these two nappes have been interpreted as belonging to distinct Mesozoic paleogeographic domains: “European” for Sambuco and “Briançonnais” for Maggia, separated by the “Valais” oceanic basin. In this case, the similarity of the Matorello and Cocco intrusions would demonstrate the absence of any significant transcurrent movement between these two continental domains. Alternatively, according to a more traditional view, Sambuco and Maggia might belong to a single large Alpine tectonic unit.  相似文献   

Measuring and modeling atmospheric particles and particle bound mercury Hg(p) at five characteristic-sampling sites     

Guor-Cheng Fang  Chaur-Tsuen Lo  Winn-Jung Huang  Jyh-Cherng Chen  Yuh-Shen Wu  Jun-Han Huang  Yi-Liang Huang 《Environmental Earth Sciences》2011,64(5):1237-1247

The main purpose of this study was to monitor ambient air particles and particulate-bound mercury Hg(p) in total suspended particulates (TSP) concentration, dry deposition at five characteristic-sampling sites. In addition, the calculated/measured dry deposition flux ratios of ambient air particles and particulate-bound mercury Hg(p) using three dry deposition models during the years of 2009–2010 were also studied. The results showed that the order of seasonal variations for mean particulate-bound mercury Hg(p) concentrations in TSP at Bei-shi (suburban/coastal), Chang-hua (downtown) and He-mei (residential) were all shown as spring > fall, winter > summer, respectively. However, the order of seasonal variations mean particulate-bound mercury Hg(p) concentrations in TSP that occurred at Gao-mei (wetland) were shown as spring > fall > winter > summer, respectively. Finally, the results of this study also indicated that using the Noll and Fang model exhibited batten prediction results for ambient air particles and particulate-bound mercury Hg(p) dry deposition when compared with the other depositions models at any of the characteristic-sampling sites for this study.  相似文献   

Cliff retreat and progressive development of talus deposits in Hungtsaiping rockfall area,NanTou, Taiwan     

Chia-Ming Lo 《Landslides》2015,12(1):29-54

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Dominant amphipods of Posidonia oceanica seagrass meadows display considerable trophic diversity          下载免费PDF全文

Loïc N. Michel  Patrick Dauby  Sylvie Gobert  Martin Graeve  Fabienne Nyssen  Nicolas Thelen  Gilles Lepoint 《Marine Ecology》2015,36(4):969-981

Gut content examination and trophic markers (fatty acids, stable isotopes of C and N) were combined to delineate the diet of the dominant species of amphipods from Mediterranean Posidonia oceanica seagrass meadows and to highlight trophic diversity among this community. Our results indicate that, although all dominant species heavily relied on macroalgal epiphytes, considerable interspecific dietary differences existed. Carbon stable isotope ratios notably showed that some of the amphipod species favored grazing on epiphytes from leaves or litter fragments (Apherusa chiereghinii, Aora spinicornis, Gammarus aequicauda), while others such as Dexamine spiniventris preferred epiphytes from rhizomes. The remaining amphipods (Caprella acanthifera, Ampithoe helleri and Gammarella fucicola) readily consumed both groups. In addition, SIAR modeling suggested that most species had a mixed diet, and relied on several food items. Fatty acid analysis and gut contents revealed that contributions of microepiphytic diatoms and of benthic and suspended particulate organic matter to the diet of amphipods were anecdotal. None of the examined species seemed to graze on their seagrass host [low 18:2(n‐6) and 18:3(n‐3) fatty acids contents], but Gammarus aequicauda partly relied on seagrass leaf detritus, as demonstrated by the lesser ¹³C‐depletion of their tissues. Overall, our findings suggest that amphipods, because of their importance in the transfer of organic matter from primary producers and detritus to higher rank consumers, are key items in P. oceanica‐associated food webs.  相似文献   

Impoverishment of recent floodplain forest mollusc fauna in the lower Ohře River (Czech Republic) as a result of prehistoric human impact     

Lucie Juřičková  Jitka Horáčková  Vojen Ložek  Michal Horsák 《Boreas: An International Journal of Quaternary Research》2013,42(4):932-946

Analyses of fossil mollusc successions have rarely been used to study the development of floodplain forests during the Holocene. The Oh?e River, located in a prehistorically settled chernozem area in the Czech Republic, is partly situated in Cretaceous marlstones, yielding sediments suitable for fossilization directly in floodplain deposits. We analysed five fossil mollusc successions situated in the lower stretch of the Oh?e River and compared the results with recent mollusc assemblages studied along the entire 256 km of the river. Fossil samples were composed mostly of open‐country species throughout the Holocene or the whole preserved succession. Only some samples also contained woodland assemblages, but these were always greatly impoverished, with a very low frequency of strictly woodland species. Although the natural‐looking appearance of the present‐day floodplain forests of the lower river stretch has resulted in its being declared a nature reserve, modern floodplain forest mollusc assemblages there are also impoverished. This reduction in the distribution of strictly woodland species compared with modern assemblages in the upper stretch of the river seems to be the result of an ancient human settlement and continuous disturbances of the floodplain forest development since the Neolithic. Thus, fully developed floodplain forest assemblages occur recently only in the upper non‐impacted stretch of the river. Based on the studied fossil successions we can conclude that the lower Oh?e River floodplain was probably a mosaic of open and disturbed forest habitats throughout the Holocene. This area is part of a central European landscape island, where forests probably never fully developed and open patches from the early Holocene continually developed into an agricultural landscape.  相似文献