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1.
David T. Adamson PhD PE Grayson Uhlir BS Sharon R. Rauch BA Tessa Klein BS Anthony S. Danko PhD PE 《Ground Water Monitoring & Remediation》2021,41(3):29-40
1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance. 相似文献
2.
Tessa M. Hill Gregg R. Brooks David S. Duncan Franco S. Medioli 《Marine Geology》2003,200(1-4):263-272
The sedimentology, stratigraphic position, and benthic foraminiferal biostratigraphy of early- to mid-Holocene deposits from the west-central Florida shelf suggest that barrier islands developed along this coast as early as 8.3 ka, in an environment that was more arid than today. Predominant foraminifera of three paralic sedimentary facies deposited between 5.3 and 8.3 ka include miliolids, Elphidium spp., and Ammonia spp., all of which are common in back-barrier environments. Foraminiferal assemblages also suggest that early back-barrier sediments were deposited in a hypersaline environment, similar to that of the arid Laguna Madre of the western Gulf of Mexico. Modern back-barrier foraminifera in the Tampa Bay region are indicative of the humid subtropical climate of today. Thus, the climate of west-central Florida at approximately 8 ka was more arid than today, which is consistent with recent studies showing that climate in the Gulf of Mexico was dryer and cooler during this time period. 相似文献
3.
Daniel E. Gilbert John R. Hauser James W. Harrison Jimmie J. Wortman 《Ocean Engineering》1974,2(6):265-273
The present study indicates that most semiconductor components are fabricated such that they are not affected by operation in a dielectric oil environment. A quantitative estimate of the conditions under which oil-soluble ions will invert semiconductor surfaces and interfere with proper device operation is developed. The results are discussed in terms of pressure-tolerant electronic systems—solid-state components operated immersed in chemically inert dielectric oils when these components are subject to, and experience, ambient hydrostatic pressures of the ocean depths. The feasibility of pressure-tolerant electronic systems is demonstrated. 相似文献
4.
Reconstructing Aragonite Saturation State Based on an Empirical Relationship for Northern California
Catherine V. Davis Tessa M. Hill John L. Largier Brian Gaylord Jaime Jahncke 《Estuaries and Coasts》2018,41(7):2056-2069
Ocean acidification is a global phenomenon with highly regional spatial and temporal patterns. In order to address the challenges of future ocean acidification at a regional scale, it is necessary to increase the resolution of spatial and temporal monitoring of the inorganic carbon system beyond what is currently available. One approach is to develop empirical regional models that enable aragonite saturation state to be estimated from existing hydrographic measurements, for which greater spatial coverage and longer time series exist in addition to higher spatial and temporal resolution. We present such a relationship for aragonite saturation state for waters off Northern California based on in situ bottle sampling and instrumental measurements of temperature, salinity, and dissolved oxygen. Application of this relationship to existing datasets (5 to 200 m depth) demonstrates both seasonal and interannual variability in aragonite saturation state. We document a deeper aragonite saturation horizon and higher near surface aragonite saturation state in the summers of 2014 and 2015 (compared with 2010–2013), associated with anomalous warm conditions and decadal scale oscillations. Application of this model to time series data reiterates the direct association between low aragonite saturation state and upwelled waters and highlights the extent to which benthic communities on the Northern California shelf are already exposed to aragonite undersaturated waters. 相似文献
5.
Patricia C. Fanning Simon J. Holdaway Ed J. Rhodes Tessa G. Bryant 《Geoarchaeology》2009,24(2):121-146
The conventional approach to assessing the archaeological record in most parts of the world involves a combination of excavation of stratified deposits and extensive survey of surface deposits. Although widely applied in Australia, in both research‐based and management archaeology, the method does not conform well to the nature of the surface archaeological record here. Over much of semi‐arid and arid Australia, archaeological “sites” are, in fact, accretion phenomena that are not easily interpreted as the outcome of short‐term behavioral events. Using results from twelve years of geoarchaeological research in western New South Wales, we demonstrate that there is considerable variability in landsurface age, and hence the “availability” of archaeological surfaces, over relatively short distances. Therefore, it cannot be assumed that stone artifact deposits, for example, that appear to be similar in character are of similar age. Data are also presented that demonstrate that the presence of artifacts on the surface, their apparent absence in sediments buried beneath the surface, and the apparent recent ubiquity of the archaeological record are all a function of geomorphic processes that, at the same time, expose some artifact deposits at the surface and erode and bury others amid large volumes of sediment. Interpreting the surface artifact record within a spatial and temporal geomorphic framework is crucial to understanding the past human behavior that the artifact deposits represent. © 2009 Wiley Periodicals, Inc. 相似文献
6.
River basins in south‐western USA are some of the most extensively studied arid land fluvial systems in the world. Since the early 1960s their hydro‐climatic histories have been reconstructed from the analysis of alluvial cut‐and‐fill cycles, while from the late 1970s there have been investigations of slackwater deposits and palaeostage indicators for large floods in stable‐boundary bedrock reaches. However, no studies have regionally integrated Holocene fluvial histories from these two different types of fluvial environments. The current study combines the alluvial archive with flood records from bedrock reaches to generate a probability‐based 12,000 year record of flooding in south‐western USA. Using more than 700 14C‐dated fluvial units, the analysis produces a high resolution (centennial) flood record. Seven episodes of increased flooding occurred at 11,250–10,400, 8800–8350, 8230–7600, 6700–5700, 5600–4820, 4550–3320 and 2000–0 cal. BP. Bedrock reaches are found to record more frequent floods during the middle to late Holocene, while in alluvial rivers more flood units are dated to the early and middle Holocene. These differences are primarily the result of selective preservation with alluvial reaches tending to erode during periods characterised by very large floods. Episodes of major Holocene flooding recorded in slackwater deposits within bedrock systems correspond with periods of increased precipitation in the region and lower temperatures. In contrast, within alluvial rivers above‐average flooding probabilities, as well as regionally extensive channel entrenchment episodes, match with reduced annual precipitation and lower temperatures. The results of this study clearly demonstrate the value of the Holocene fluvial archive for reconstructing regional, short‐term hydro‐climatic change in south‐western USA. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
7.
The early magmatic and tectonic history of the Carolina terrane and its possible affinities with other Neoproterozoic circum-Atlantic arc terranes have been poorly understood, in large part because of a lack of reliable geochronological data. Precise U-Pb zircon dates for the Virgilina sequence, the oldest exposed part, constrain the timing of the earliest known stage of magmatism in the terrane and of the Virgilina orogeny. A flow-banded rhyolite sampled from a metavolcanic sequence near Chapel Hill, North Carolina, yielded a U-Pb zircon date of 632.9 +2.6/-1.9 Ma. A granitic unit of the Chapel Hill pluton, which intrudes the metavolcanic sequence, yielded a nearly identical U-Pb zircon date of 633 +2/-1.5 Ma, interpreted as its crystallization age. A felsic gneiss and a dacitic tuff from the Hyco Formation yielded U-Pb zircon dates of 619.9 +4.5/-3 Ma and 615.7 +3.7/-1.9 Ma, respectively. Diorite and granite of the Flat River complex have indistinguishable U-Pb upper-intercept dates of 613.9 +1.6/-1.5 Ma and 613.4 +2.8/-2 Ma. The Osmond biotite-granite gneiss, which intruded the Hyco Formation before the Virgilina orogeny, crystallized at 612.4 +5.2/-1.7 Ma. Granite of the Roxboro pluton, an intrusion that postdated the Virgilina orogeny, yielded a U-Pb upper intercept date of 546.5 +3.0/-2.4 Ma, interpreted as the time of its crystallization. These new dates both provide the first reliable estimates of the age of the Virgilina sequence and document that the earliest known stage of magmatism in the Carolina terrane had begun by 633 +2/-1.5 Ma and continued at least until 612.4 +5.2/-1.7 Ma, an interval of approximately 25 m.yr. Timing of the Virgilina orogeny is bracketed between 612.4 +5.2/-1.7 Ma and 586+/-10 Ma (reported age of the upper Uwharrie Formation). The U-Pb systematics of all units studied in the Virgilina sequence are simple and lack any evidence of an older xenocrystic zircon component, which would indicate the presence of a continental-type basement. This observation, together with the juvenile Nd isotopic character of the Virgilina volcanic arc sequence, suggests that the oldest part of the Carolina terrane was built on oceanic crust away from a continental crustal influence. 相似文献
8.
Scott D. Samson James P. Hibbard Greg L. Wortman 《Contributions to Mineralogy and Petrology》1995,121(2):171-184
Nd isotopic analyses of whole-rock samples from the older portion of the Carolina terrane, one of the largest terranes in
the Appalachian orogen, demonstrate that part of this terrane is composed of juvenile, mantle-derived crust. These data suggest
that the terrane may not have originally been built upon old, evolved basement material but rather may have been built upon
oceanic crust. A recent study by other workers demonstrates a more crustally evolved Nd isotopic signature for younger components
of the Carolina terrane. These data may indicate that the terrane interacted with evolved crust at a later time, possibly
by amalgamation with a more evolved crustal fragment before final accretion to Laurentia, rather than indicating a primary
old basement. A juvenile nature for the older portion of the terrane contrasts with models that suggest it is an evolved crustal
fragment that formed in a continental margin setting — a scenario proposed to explain the high proportion of felsic volcanic
rocks within the terrane. It is herein suggested that Carolina is a chemically evolved but isotopically juvenile crustal fragment,
because it remained in an oceanic setting for an unusually long time. In this regard the Carolina terrane is similar to some
of the large accreted terranes in the Canadian Cordillera, such as Wrangellia and Alexander. The presence of juvenile crust
in the Carolina terrane documents that at least part of the southern Appalachian orogen is not composed solely of reactivated
pre-existing continental crust. The importance of this part of the orogen in terms of the volume of juvenile Phanerozoic crustal
material in North America may be larger than previously thought. However, until additional major Appalachian terranes have
been isotopically characterized the volume of juvenile crust in the whole orogen remains unknown. The isotopic make-up of
a terrane can be an important aspect of terrane analysis as different terranes may have significantly different isotopic compositions,
while even widespread pieces of a single terrane should have very similar isotopic characteristics. The Nd isotopic data for
the Carolina terrane form the beginning of an isotope database for terranes in the southern Appalachians.
Received: 15 June 1994/Accepted: 31 January 1995 相似文献
9.
Silvania Avelar Tessa S. van der Voort Timothy I. Eglinton 《Carbon balance and management》2017,12(1):10
Background
Determining national carbon stocks is essential in the framework of ongoing climate change mitigation actions. Presently, assessment of carbon stocks in the context of greenhouse gas (GHG)-reporting on a nation-by-nation basis focuses on the terrestrial realm, i.e., carbon held in living plant biomass and soils, and on potential changes in these stocks in response to anthropogenic activities. However, while the ocean and underlying sediments store substantial quantities of carbon, this pool is presently not considered in the context of national inventories. The ongoing disturbances to both terrestrial and marine ecosystems as a consequence of food production, pollution, climate change and other factors, as well as alteration of linkages and C-exchange between continental and oceanic realms, highlight the need for a better understanding of the quantity and vulnerability of carbon stocks in both systems. We present a preliminary comparison of the stocks of organic carbon held in continental margin sediments within the Exclusive Economic Zone of maritime nations with those in their soils. Our study focuses on Namibia, where there is a wealth of marine sediment data, and draws comparisons with sediment data from two other countries with different characteristics, which are Pakistan and the United Kingdom.Results
Results indicate that marine sediment carbon stocks in maritime nations can be similar in magnitude to those of soils. Therefore, if human activities in these areas are managed, carbon stocks in the oceanic realm—particularly over continental margins—could be considered as part of national GHG inventories.Conclusions
This study shows that marine sediment organic carbon stocks can be equal in size or exceed terrestrial carbon stocks of maritime nations. This provides motivation both for improved assessment of sedimentary carbon inventories and for reevaluation of the way that carbon stocks are assessed and valued. The latter carries potential implications for the management of human activities on coastal environments and for their GHG inventories.10.
Ecosystem-based management is now widely accepted as the standard strategy for achieving sustainable delivery of marine and estuarine ecosystem services. The ubiquity and rate of change in marine ecosystems necessitate incorporating visions of future ecosystem states into ecosystem management strategies. Creating visions of the future enables policy makers to set realistic objectives and targets, and to explore the consequences of potential management decisions on ecosystems under multiple potential scenarios of change. Several classes of futures are used in marine ecosystem management program, and three are highlighted here: visioning, predictive models, and scenario analysis. Each approach is briefly described, and their use in current marine ecosystem management programs in North America is reviewed. In particular, the importance of using scenario analysis to identify and incorporate the influence of exogenous drivers into management strategies is highlighted. Then, some of the perils and promises associated with each approach are described, and a way forward is proposed that incorporates multiple types of future envisioning approaches into management programs. Key contributions of future analyses include highlighting connections and trade-offs among ecosystem components, setting realistic targets, and incorporating exogenous drivers, and their uncertainties, into ecosystem management programs. 相似文献