Oxidation of pyrite during extraction of carbonate associated sulfate     

Pedro J. Marenco  Frank A. Corsetti  Douglas E. Hammond  Alan J. Kaufman  David J. Bottjer 《Chemical Geology》2008,247(1-2):124-132

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   

Tectonic evolution of the Intra-Pontide suture zone in the Armutlu Peninsula, NW Turkey     

Alastair H. F. Robertson  Timur Ustamer 《Tectonophysics》2004,381(1-4):175

The Armutlu Peninsula and adjacent areas in NW Turkey play a critical role in tectonic reconstructions of the southern margin of Eurasia in NW Turkey. This region includes an inferred Intra-Pontide oceanic basin that rifted from Eurasia in Early Mesozoic time and closed by Late Cretaceous time. The Armutlu Peninsula is divisible into two metamorphic units. The first, the Armutlu Metamorphics, comprises a ?Precambrian high-grade metamorphic basement, unconformably overlain by a ?Palaeozoic low-grade, mixed siliciclastic/carbonate/volcanogenic succession, including bimodal volcanics of inferred extensional origin, with a possibly inherited subduction signature. The second unit, the low-grade znik Metamorphics, is interpreted as a Triassic rift infilled with terrigenous, calcareous and volcanogenic lithologies, including basalts of within-plate type. The Triassic rift was unconformably overlain by a subsiding Jurassic–Late Cretaceous (Cenomanian) passive margin including siliciclastic/carbonate turbidites, radiolarian cherts and manganese deposits. The margin later collapsed to form a flexural foredeep associated with the emplacement of ophiolitic rocks in Turonian time. Geochemical evidence from meta-basalt blocks within ophiolite-derived melange suggests a supra-subduction zone origin for the ophiolite. The above major tectonic units of the Armutlu Peninsula were sealed by a Maastrichtian unconformity. Comparative evidence comes from the separate Almacık Flake further east.Considering alternatives, it is concluded that a Mesozoic Intra-Pontide oceanic basin separated Eurasia from a Sakarya microcontinent, with a wider Northern Neotethys to the south. Lateral displacement of exotic terranes along the south-Eurasian continental margin probably also played a role, e.g. during Late Cretaceous suturing, in addition to overthrusting.  相似文献   

High Resolution Optical Spectroscopy of a B-type Abundance Standard Candidate in Ori OB1—HD 35039     

Şahin  Timur  Dervişoğlu  Ahmet 《Astronomy Letters》2019,45(8):528-545

Astronomy Letters - We present LTE analysis of high resolution optical spectra for the B-type abundance standard candidate HD 35039 (HR 1765, 22 Ori) with an ambigous binary nature. The spectra...  相似文献   

From hazard to impact: flood damage assessment tools for mega cities     

Albert S. Chen  Michael J. Hammond  Slobodan Djordjević  David Butler  David M. Khan  William Veerbeek 《Natural Hazards》2016,82(2):857-890

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Effect of disturbed zone thickness on rock slope stability     

Ersöz  Timur  Özköse  Merve  Topal  Tamer 《Natural Hazards》2021,108(2):1919-1942

Natural Hazards - Cut slope surfaces are affected by excavation activities and weathering agents. Disturbances on the surface can penetrate down to a certain depth. Slope stability analyses made on...  相似文献   

Radon-222 as a tracer for mixing in the water column and benthic exchange in the southern California borderland     

W.M. Berelson  D.E. Hammond  C. Fuller 《Earth and Planetary Science Letters》1982,61(1):41-54

The concentrations of²²²Rn and²²⁶Ra in the water column and in the sediments of Santa Barbara and San Nicolas Basins have been measured semi-annually over the last four years. Approximately one-third of excess radon profiles obtained in the water column in these basins can be adequately fit with a one-dimensional eddy diffusion-decay model. Exponential profiles in the center of San Nicolas Basin yield a vertical eddy diffusivity of 26±16 cm²/s and 3.4±1.0 cm²/s for Santa Barbara Basin. The application of a two-dimensional eddy diffusion-decay model to profiles obtained in the center and on the margins of San Nicolas Basin produces a better fit than is found using a one-dimensional vertical eddy diffusivity. The two-dimensional model for San Nicolas Basin predicts a vertical eddy diffusivity of 17 cm²/s and a horizontal eddy diffusivity of 10⁵ cm²/s. These values are in reasonable agreement with those predicted from the vertical buoyancy gradient and the horizontal length scale.The vertically integrated radon excess (standing crop) in the water column of Santa Barbara Basin averages 53±23 atoms/m² s. This is in good agreement with the flux across the sediment-water interface of 60±15 atoms/m² s, calculated by measuring radon emanation in the sediments as a function of depth and applying a molecular diffusion-reaction model. Hence, one-dimensional molecular diffusion accurately predicts the flux of radon from the laminated Santa Barbara Basin sediments. In San Nicolas Basin the integrated radon excess in the water column is 376±143 atoms/m² s, but the diffusive randon flux from San Nicolas Basin sediments averages only 190±53 atoms/m² s. This descrepancy indicates that a non-diffusive process, probably macrofaunal irrigation, supplies much of the flux of radon from San Nicolas Basin sediments.  相似文献   

The ilmenite/titano-magnetite assemblage: kinetics of re-equilibration     

Patrick A. Hammond  Lawrence A. Taylor 《Earth and Planetary Science Letters》1982,61(1):143-150

Compositions of coexisting ilmenite and titano-magnetite commonly have been used to establish the conditions of formation for igneous and metamorphic rocks (Buddington-Lindsley geothermometer/oxybarometer). Temperatures so determined for some rocks are lower than might be expected for magmatic crystallization. These low temperatures are the result of re-equilibration of the Fe-Ti oxides during slow cooling. This process is one in which titano-magnetites are oxidized and ilmenites are reduced upon cooling along a buffer curve or in the presence of a fluid of constant composition. Textural studies indicate that the reduction of the ilmenite-hematite phase may be the slower reaction consequently, the rate-controlling step of the re-equilibration.The kinetics of the reduction reactions in the two-phase region between the joins for the ilmenite-hematite and magnetite-ulvöspinel solid solution series were studied by thermogravimetric analysis at controlledf_O2. With experiments conducted near the Ni/NiO and QFM buffers, annealed ilmenite(ss) synthetic charges were reduced isothermally. The temperature range for the experiments was 900–1250°C, with total gas-flow rates of 0.35 and 1.0 cm/s. Kinetic data were collected by measuring the weight change during each experiment as a function of time. Additionally, a cooling-rate (0.5°C/hr) experiment was conducted near the QFM buffer from 1150 to 985°C starting with an ilmenite-saturated spinel phase.At 1200°C and 0.35 cm/s flow rate, the reaction mechanism is an interfacial process where mass transport of the reacting gases is the rate-controlling step. In isothermal experiments at 1100°C and lower, diffusion of reactants through a solid product layer was the controlling mechanism. The activation energy for this diffusion process is 59±6 kcal/mole. Significant enhancement of diffusion occurs along grain boundaries.Although the individual phases may re-equilibrate internally upon cooling, the Fe-Ti contents must remain unchanged for proper use of this mineral indicator-i.e. no external re-equilibration. It is imperative that the kinetics of the situation be appreciated. These preliminary kinetic experiments indicate that extreme caution must be exercised when applying this ilmenite/titano-magnetite geothermometer/oxybarometer. These phases may only truly “quench” in the parameters of formation in the case of certain hypabyssal and extrusive occurrences  相似文献   

Characterizing groundwater flow in a faulted karst system using optical brighteners from septic systems as tracers     

K. E. Murray  D. R. Straud  W. W. Hammond 《Environmental Geology》2007,53(4):769-776

This study used optical brighteners (OB) released from septic systems to show that groundwater flow direction is largely controlled by the structural framework in a faulted karst groundwater system. Effective protection of groundwater resources requires that groundwater systems are adequately characterized and source water protection areas (SWPA) are developed for drinking water wells. Karst aquifers are among the most sensitive to contamination due to high recharge rates, and among the most difficult aquifers to characterize due to heterogeneity, and anisotropy. Because septic systems may be used to treat wastewater within SWPAs for karst aquifers there is a need to characterize these groundwater systems using tracers. The objective of this study was to characterize groundwater flow in a faulted portion of the Edwards aquifer in Bexar County, Texas using OB that are released as incidental tracers from septic systems. This study included measurement of water levels, sampling of groundwater and surface water, analysis for OB, and spatial analysis in a GIS. Results show that OB intensities were highest to the southwest of the septic area, a direction that is sub-parallel to the fault and fracture orientation and nearly perpendicular to the hydraulic gradient. This indicates that movement of OB, solutes, or non-aqueous liquids/solids in a faulted karst system can be largely controlled by fault/fracture orientation and structural relay ramps.  相似文献   

Erratum to “The Berit transect of the Tauride thrust belt, S Turkey: Late Cretaceous–Early Cenozoic accretionary/collisional processes related to closure of the Southern Neotethys” [Journal of Asian Earth Sciences 27 (2006) 108–145]     

Alastair H.F. Robertson  Timur Ustamer  Osman Parlak  Ulvi Can Ünlügen  Kemal Tal&#x;  Nurdan &#x;nan 《Journal of Asian Earth Sciences》2007,29(5-6):978-980

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U-Pb-Hf isotopic data from detrital zircons in late Carboniferous and Mid-Late Triassic sandstones,and also Carboniferous granites from the Tauride and Anatolide continental units in S Turkey: implications for Tethyan palaeogeography     

Timur Ustaomer  Petek Ayda Ustaömer  Alastair H. F. Robertson  Axel Gerdes 《International Geology Review》2020,62(9):1159-1186

ABSTRACT

Zircons from Carboniferous sandstones (three samples) and Mid-Late Triassic sandstones (four samples) from the Tauride and Anatolide continental units were analysed for U-Pb-Hf isotopes. For comparison, zircons were also analysed from Carboniferous granites of the Afyon Zone, Anatolides (three samples). A NE African/Arabian source is inferred for both the Carboniferous sandstones of the Taurides (Alada?) and the Anatolides (Konya Complex). In contrast, the Carboniferous Karaburun Melange is characterised by a NW African provenance. A prominent Devonian population occurs in the Carboniferous Karaburun Melange, characterised by mainly positive ε_Hf(t) values that differ significantly from those of the Devonian granites of the Sakarya continental crustal unit (Pontides). Middle-Late Triassic Tauride sandstones include minor Palaeozoic and Early Mesozoic zircons. In contrast, Devonian and Carboniferous zircons are relatively abundant in Late Triassic sandstones of the Karaburun Peninsula. The Hf isotopic compositions of 25 Carboniferous-aged zircons from three samples of Mid-Late Triassic sandstone and one of Late Carboniferous age (one sample) overlap with the ε_Hf(t) values of Carboniferous arc-type granites in the Anatolides. Taking account of the available U-Pb and Lu-Hf isotopic data from comparative crustal units, the Devonian zircon populations from the melanges in the Karaburun Peninsula and the Konya Complex are inferred to have a westerly source (e.g. granitic rocks of Aegean region or central Europe). A tectonic model is proposed in which Palaeozoic Tethys sutured during the late Carboniferous in the west (Aegean region westwards), leaving an eastward-widening oceanic gulf in which sandstone turbidites accumulated, including Devonian zircons.  相似文献