Ten-year change of total phosphorous pollution in the Min River,an upstream tributary of the Three Gorges Reservoir     

Chunping Ren  Lijing Wang  Binghui Zheng  Jun Qian  Hongjin Ton 《Environmental Earth Sciences》2016,75(12):1015

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The photoelectron spectra of some Tl-Sb sulphosalts     

Ivan Gržetić  Tonći Balić Žunic 《Physics and Chemistry of Minerals》1993,20(4):285-296

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.  相似文献   

Possible Evidence of Long-Term Oscillations in the Solar Atmosphere     

Raju  K.P.  Singh  Jagdev  Srikanth  R.  Chou  Dean-Yi  Team  the Ton 《Solar physics》2001,199(1):1-11

We have obtained the temporal correlation function, Q(t), from time sequences of Caii K filtergrams and Dopplergrams from Antarctica, Taiwan Oscillation Network (TON) and Solar and Heliospheric Observatory (SOHO). Q(t) gives the time evolution of the pattern under examination, supergranulation in this case. It has been found that Q(t) shows oscillatory signals of both 5-min and long-term periods. The 5-min oscillations are suppressed by averaging the images over 10 min. An exponential decay curve which represents the lifetime trend of supergranules, is fitted to Q(t) and subtracted out. The Q(t) residuals thus obtained contain the oscillatory component and are then subjected to a periodogram analysis. Significant periodicities in the range of 1.4–10 hours have been noted. The causes of these oscillations are not fully known at present, but the instrumental and atmospheric factors can be ruled out, pointing to solar origin. Various possibilities are discussed. Some of the observed periodicities may be considered as probable candidates for long-term oscillations in the Sun, such as the elusive gravity modes.  相似文献   

Rotation history of Alaskan tectonic blocks     

George L. Freeland  Robert S. Dietz 《Tectonophysics》1973,18(3-4)

Alaska is considered to be tectonically comprised of five elongate blocks separated by transcurrent faults formed prior to rotation which enter the state from the southeast and continue westward to the edge of the Bering Sea continental shelf. We propose an additional, inactive fault, indicated by gravity and magnetic data and other observations, to extend between the Bering Strait and the Arctic Ocean continental shelf east of the Northwind escarpment, separating northern Alaska from northeast Siberia. Near the center of the state the faults are bent, concave to the south, about the north-south axis of the so-called Alaska orocline. In our reconstruction the blocks have rotated from a position whereby the north slope was adjacent to Banks Island of the Canadian basin. During the rotation the northernmost, or Brooks block, was squeezed, up to 15% in the western end, to its present width. After rotation, when the three southern blocks were in their present position, the Brooks block and the next block to the south were pushed eastward by North America moving against Siberia, forming the bend in the British-Richardson-Ogilvie Mountains we call the Ogilvie orocline.  相似文献   

Some economics of ‘dangerous’ climate change: Reflections on the Stern Review     

Simon Dietz  Chris Hope  Nicola Patmore 《Global Environmental Change》2007,17(3-4):311-325

The Stern Review on the Economics of Climate Change concluded that there can be “no doubt” the economic risks of business-as-usual (BAU) climate change are “very severe” [Stern, 2006. The Economics of Climate Change. HM Treasury, London, p. 188]. The total cost of climate change was estimated to be equivalent to a one-off, permanent 5–20% loss in global mean per-capita consumption today. And the marginal damage cost of a tonne of carbon emitted today was estimated to be around $312 [p. 344]. Both of these estimates are higher than most reported in the previous literature. Subsequently, a number of critiques have appeared, arguing that discounting is the principal explanation for this discrepancy. Discounting is important, but in this paper we emphasise that how one approaches the economics of risk and uncertainty, and how one attempts to model the very closely related issue of low-probability/high-damage scenarios (which we connect to the recent discussion of ‘dangerous’ climate change), can matter just as much. We demonstrate these arguments empirically, using the same models applied in the Stern Review. Together, the issues of risk and uncertainty on the one hand, and ‘dangerous’ climate change on the other, raise very strongly questions about the limits of a welfare-economic approach, where the loss of natural capital might be irreversible and impossible to compensate. Thus we also critically reflect on the state-of-the-art in integrated assessment modelling. There will always be an imperative to carry out integrated assessment modelling, bringing together scientific ‘fact’ and value judgement systematically. But we agree with those cautioning against a literal interpretation of current estimates. Ironically, the Stern Review is one of those voices. A fixation with cost-benefit analysis misses the point that arguments for stabilisation should, and are, built on broader foundations.  相似文献   

The crystal structure of bøgvadite (Na2SrBa2Al4F20)     

Tonči Balić-Žunić 《Mineralogy and Petrology》2014,108(4):479-486

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.  相似文献   

Prospects for the GLAS Rayleigh laser beacon on the 4.2-m WHT     

Ren Rutten  Maarten Blanken  Richard McDermid  Thomas Gregory  Paul Jolley  Tim Morris  Richard Myers  Johan Pragt  Ton Schoenmaker  Remko Stuik  Gordon Talbot 《New Astronomy Reviews》2006,49(10-12):632

The scientific exploitation of adaptive optics (AO) with natural guide stars is severely constrained by the limited presence of bright guide stars for wavefront sensing. Use of a laser beam as an alternative means to provide a source for wavefront sensing has the potential of drastically improving the sky coverage for AO. For this reason at the 4.2-m William Herschel Telescope a project was started to develop a Rayleigh laser beacon to work together with the existing NAOMI adaptive optics instrumentation and the OASIS integral field spectrograph. This paper presents the rationale for this development, highlights some of the technical aspects, and gives some expected performance measures.  相似文献   

Addendum to paper on Roter Kamm     

Robert S. Dietz 《Meteoritics & planetary science》1966,3(1):33-34

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Real‐time distributed hybrid testing: coupling geographically distributed scientific equipment across the Internet to extend seismic testing capabilities          下载免费PDF全文

Martin S. Williams  Matt S. Dietz  Anthony Blakeborough  Ignacio Lamata Martínez 《地震工程与结构动力学》2014,43(7):1023-1043

Large‐scale testing and qualification of structural systems and their components is crucial for the development of earthquake engineering knowledge and practice. However, laboratory capacity is often limited when attempting larger experiments due to the sheer size of the structures involved. To overcome traditional laboratory capacity limitations, we present a new earthquake engineering testing method: real‐time distributed hybrid testing. Extending current approaches, the technique enables geographically distributed scientific equipment including controllers, dynamic actuators and sensors to be coupled across the Internet in real‐time. As a result, hybrid structural emulations consisting of physical and numerical substructures need no longer be limited to a single laboratory. Larger experiments may distribute substructures across laboratories located in different cities whilst maintaining correct dynamic coupling, required to accurately capture physical rate effects. The various aspects of the distributed testing environment have been considered. In particular, to ensure accurate control across an environment not designed for real‐time testing, new higher level control protocols are introduced acting over an optimised communication system. New large time‐step prediction algorithms are used, capable of overcoming both local actuation and distributed system delays. An overview of the architecture and algorithms developed is presented together with results demonstrating a number of current capabilities. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Shaking‐table tests of flat‐bottom circular silos containing grain‐like material          下载免费PDF全文

Stefano Silvestri  Salvador Ivorra  Laura Di Chiacchio  Tomaso Trombetti  Dora Foti  Giada Gasparini  Luca Pieraccini  Matt Dietz  Colin Taylor 《地震工程与结构动力学》2016,45(1):69-89

According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献