Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

QUEST on DASI: a South Pole CMB polarization experiment     

Sarah Church  Peter Ade  James Bock  Melanie Bowden  John Carlstrom  Ken Ganga  Walter Gear  James Hinderks  Wayne Hu  Brian Keating  John Kovac  Andrew Lange  Eric Leitch  Olivier Mallie  Simon Melhuish  Anthony Murphy  Ben Rusholme  Creidhe O&#x;Sullivan  Lucio Piccirillo  Clem Pryke  Andy Taylor  Keith Thompson 《New Astronomy Reviews》2003,47(11-12):1083

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   

A search for high-redshift molecular absorption lines towards millimetre-loud, optically faint quasars     

M. T. Murphy  S. J. Curran  J. K. Webb 《Monthly notices of the Royal Astronomical Society》2003,342(3):830-836

We describe initial results of a search for redshifted molecular absorption towards four millimetre-loud, optically faint quasars. A wide frequency bandwidth of up to 23 GHz per quasar was scanned using the Swedish–ESO Submillimetre Telescope at La Silla. Using a search list of commonly detected molecules, we obtained nearly complete redshift coverage up to   z _abs= 5  . The sensitivity of our data is adequate to have revealed absorption systems with characteristics similar to those seen in the four known redshifted millimetre-band absorption systems, but none were found. Our frequency-scan technique nevertheless demonstrates the value of wide-band correlator instruments for searches such as these. We suggest that a somewhat larger sample of similar observations should lead to the discovery of new millimetre-band absorption systems.  相似文献   

Enhancing understanding of breakdown and collapse in the Yorkshire Dales using ground penetrating radar on cave sediments     

P. Murphy  A.R. Westerman  R. Clark  A. Booth  A. Parr 《Engineering Geology》2008,99(3-4):160

Historical evidence shows block breakdown and collapse are actively occurring in large fault aligned caverns in the Yorkshire Dales karst. Deployment of ground penetrating radar at two such sites has provided detailed images of the sedimentary sequences below the present day cavern floor but no large blocks are imaged within the sediments. Solutional processes must be removing limestone from the sediment to allow continued cavern growth. Possible mechanisms to account for the lack of large blocks within the sediment fill are discussed.  相似文献   

The distributions of particulate atmospheric trace metals and mineral aerosols over the Indian Ocean     

R. Chester  A. S. Berry  K. J. T. Murphy 《Marine Chemistry》1991,34(3-4)

Data are presented for the concentrations of Al, Fe, Mn, Ni, Co, Cr, V, Cu, Zn, Pb and Cd in aerosols collected over two contrasting regions of the Indian Ocean. These are: (1) the northern Arabian Sea (AS), from which samples were collected in the northeast monsoon, during which the region receives an input of crustal material from the surrounding arid land masses; and (2) the Tropical Southern Indian Ocean (TSIO), a remote region from which samples were collected from air masses for which there were no large-scale up-wind continental aerosol sources. The TSIO samples can be divided into two populations: Population I aerosols, collected from air masses which have probably impinged on Madagascar, and Population II aerosols, which have been confined to open-ocean regions to the south of the area.The data indicate that there are strong latitudinal variations in the chemical signatures of aerosols over the Indian Ocean. The input of crustal material to the Arabian Sea gives rise to an average Al concentration of about 1000 ng m⁻³ of air in the northeast monsoon regime. As a result, the concentrations of all trace metals are relatively high, and the values of crustal enrichment factors are less than 10 for most metals, in the AS aerosols. In contrast, TSIO Population II ‘open-ocean southern air’ sampled during the southwest monsoon season, has an average Al concentration of only about 10 ng m⁻³ of air. Trace metal concentrations in the TSIO ‘open-ocean southern air’ during the southwest monsoon season are representative of ‘clean’ remote marine air and are generally similar to those reported over the central North Pacific.Mineral dust concentrations over the Indian Ocean decrease in a north to south direction, from about 15–20 μg m⁻³ of air in the extreme north to about 0.01–0.25 μg m⁻³ of air in the far south. The deposition of mineral dust over the northern Arabian Sea can account for approximately 75% of the non-carbonate material incorporated into the underlying sediments.In the Arabian Sea the dissolved atmospheric inputs of all the trace metals, with the exception of Cu and Co, exceed those from fluvial run-off by factors which range from 9.6 for Pb to 1.6 for Cr.  相似文献   

The Southern Antarctic Circumpolar Current Front: physical and biological coupling at South Georgia     

Peter Ward  Mick Whitehouse  Mike Meredith  Eugene Murphy  Rachael Shreeve  Rebecca Korb  Jon Watkins  Sally Thorpe  Rachel Woodd-Walker  Andrew Brierley  Nathan Cunningham  Sharon Grant  Doug Bone 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12):139

The coupling of physics and biology was examined along a 160 km long transect running out from the north coast of South Georgia Island and crossing the Southern Antarctic Circumpolar Current Front (SACCF) during late December 2000. Surface and near surface potential TS properties indicated the presence of three water types: a near-shore group of stations characterised by water which became progressively warmer and fresher closer to South Georgia, an offshore grouping in which sea surface temperatures and those at the winter water level were relatively warm (1.8°C and 0.5°C, respectively), and a third in which surface and winter water temperatures were cooler and reflected the presence of the SACCF. The transect bisected the SACCF twice, revealing that it was flowing in opposite directions, north-westward closest to South Georgia and south-eastwards at its furthest point from the island. The innermost limb was a narrow intense feature located just off the shelf break in 2000–3500 m of water and in which rapid surface baroclinic velocities (up to 35 cm s⁻¹) were encountered. Offshore in the outermost limb, shown subsequently to be a mesoscale eddy that had meandered south from the retroflected limb of the SACCF, flow was broader and slower with peak velocities around 20 cm s⁻¹. Chlorophyll a biomass was generally low (<1 mg m⁻³) over much of the transect but increased dramatically in the region of the innermost limb of the SACCF, where a deepening of the surface mixed layer was coincident with a subsurface chlorophyll maximum (7.4 mg m⁻³) and elevated concentrations down to 100 m. The bloom was coincident with depleted nutrient concentrations, particularly silicate, nitrate and phosphate, and although ammonium concentrations were locally depleted the bloom lay within an elevated band (up to 1.5 mmol m⁻³) associated with the frontal jet. Increased zooplankton abundance, higher copepod body carbon mass and egg production rates all showed a strong spatial integrity with the front. The population structure of the copepods Calanoides acutus and Rhincalanus gigas at stations within the front suggested that rather than simply resulting from entrainment and concentration within the jet, increased copepod abundance was the result of development in situ. Estimates of bloom duration, based on silicate and carbon budget calculations, set the likely duration between 82 and 122 d, a figure supported by the development schedule of the two copepod species. Given this timescale, model outputs from FRAM and OCCAM indicated that particles that occurred on the north side of South Georgia in December would have been in the central-southern Scotia Sea 2–3 months earlier, probably in sea ice affected regions.  相似文献   

Two Offner-based IR camera optical designs     

D. C. Murphy 《Experimental Astronomy》1994,3(1-4):141-142

Tracing results for two designs based on the Offner reimager are given: a practical 256×256 NICMOS-3 IR/CCD I-K camera designed for use on a f/13.5 1-m telescope yielding a 154×154 field, and a hypothetical 1024×1024 pixel nextgeneration IR camera for a f/7.5 2.5-m telescope yielding a 244×244 field. Both designs produce near-diffration limited results.  相似文献   

Relative flow of H⁺ and O⁺ ions in the topside ionosphere at mid-latitudes     

G.I. Bailey  R.J. Moffett  J.A. Murphy 《Planetary and Space Science》1977,25(10):967-972

Theoretical results on the daily variation of O⁺ and H⁺ field-aligned velocities in the topside ionosphere are presented. The results are for an L = 3 magnetic field tube under sunspot minimum conditions at equinox. They come from calculations of time-dependent O⁺ and H⁺ continuity and momentum balance in a magnetic field tube which extends from the lower F2 region to the equatorial plane (Murphy et al., 1976).There are occasions when ion counterstreaming occurs, with the O⁺ velocity upward and H⁺ velocity downward. The conditions causing this counterstreaming are described: the H⁺ layer is descending whilst O⁺ is supplied from below either to increase the O⁺ concentration at fixed heights or to replace O⁺ ions lost by charge exchange with neutral H. It is suggested that the results of observations at Arecibo by Vickrey et al. (1976) of O⁺ and H⁺ concentrations and counterstreaming velocities are significantly affected by $\text{E}\text{×}\text{B}$ drift.  相似文献   

Interhemispheric flow of thermal plasma in a closed magnetic flux tube at mid-latitudes under sunspot minimum conditions     

G.J. Bailey  R.J. Moffett  J.A. Murphy 《Planetary and Space Science》1978,26(8):753-765

The coupled H⁺ and O⁺ time-dependent continuity and momentum equations are solved within a region of the L = 3 magnetic flux tube lying between (and including) the F2-layers of conjugate hemispheres. The method of solution is an extended and modified version of the Murphy et al. (1976) method. The model is used to study the coupling between the F2-layers of conjugate hemispheres during magnetically quiet periods.The results of the calculations strongly indicate that the protonosphere acts as a reservoir, with variable H⁺ content, which prevents direct coupling between the F2-layers of conjugate hemispheres. However there is generally a significant interhemispheric flow of plasma. This flow is caused by conditions in the summer and winter topside ionospheres and it maintains continuity in the plasma concentration within the protonosphere. There are times when the direction of flow is from the winter hemisphere to the summer hemisphere. It is suggested that maintenance of the winter F2-layer at night is not assisted directly by the F2-layer of the conjugate summer hemisphere.It is shown that during the first few days of protonosphere replenishment after a magnetic storm there is an upflow of H⁺ in the topside ionosphere at all times in the summer hemisphere. There is also an upflow of H⁺ during the daytime in both hemispheres. A comparison with the results obtained when the interhemispheric H⁺ flux is held permanently at zero shows that both F2-layers are little affected by the interhemispheric H⁺ flux. Nevertheless both F2-layers are affected by the H⁺ tube content of the protonosphere. When the H⁺ flux at 1000 km in one hemisphere is much greater than the H⁺ flux at 1000 km in the conjugate hemisphere, there is a corresponding signature in the interhemispheric H⁺ flux.The results suggest that there is insufficient time between magnetic storms for complete replenishment of the protonosphere to occur.  相似文献   

Using Remote Sensing to Assess Russian Forest Fire Carbon Emissions   总被引：7，自引：0，他引：7  

A. S. Isaev  G. N. Korovin  S. A. Bartalev  D. V. Ershov  A. Janetos  E. S. Kasischke  H. H. Shugart  N. H. F. French  B. E. Orlick  T. L. Murphy 《Climatic change》2002,55(1-2):235-249

Russian boreal forests are subject to frequent wildfires. The resulting combustion of large amounts of biomass not only transforms forest vegetation, but it also creates significant carbon emissions that total, according to some authors, from 35–94 Mt C per year. These carbon emissions from forest fires should be considered an important part of the forest ecosystem carbon balance and a significant influence on atmospheric trace gases. In this paper we discuss a new method to assess forest fire damage. This method is based on using multi-spectral high-resolution satellite images, large-scale aerial photography, and declassified images obtained from the space-borne national security systems. A normalized difference vegetation index (NDVI) difference image was produced from pre- and post-fire satellite images from SPOT/HRVIR and RESURS-O/MSU-E images. A close relationship was found between values of the NDVI difference image and forest damage level. High-resolution satellite data and large-scale aerial-photos were used to calibrate the NDVI-derived forest damage map. The method was used for mapping of forest fire extent and damage and for estimating carbon emissions from burned forest areas.  相似文献