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It has long been customary to assume that in the bulk composition of the Earth, all refractory-lithophile elements (including major oxides Al2O3 and CaO, all of the REE, and the heat-producing elements Th and U) occur in chondritic, bulk solar system, proportion to one another. Recently, however, Nd-isotopic studies (most notably Boyet M. and Carlson R. W. (2006) A new geochemical model for the Earth’s mantle inferred from 146Sm-142Nd systematics. Earth Planet. Sci. Lett.250, 254-268) have suggested that at least the outer portion of the planet features a Nd/Sm ratio depleted to ∼0.93 times the chondritic ratio. The primary reaction to this type of evidence has been to invoke a “hidden” reservoir of enriched matter, sequestered into the deepest mantle as a consequence of primordial differentiation. I propose a hypothesis that potentially explains the evidence for Nd/Sm depletion in a very different way. Among the handful of major types of differentiated asteroidal meteorites, two (ureilites and aubrites) are ultramafic restites so consistently devoid of plagioclase that meteoriticists were once mystified as to how all the complementary plagioclase-rich matter (basalt) was lost. The explanation appears to be basalt loss by graphite-fueled explosive volcanism on roughly 100-km sized planetesimals; with the dispersiveness of the process dramatically enhanced, relative to terrestrial experience, because the pyroclastic gases expand into vacuous space (Wilson L. and Keil K. (1991) Consequences of explosive eruptions on small Solar System bodies: the case of the missing basalts on the aubrite parent body. Earth Planet. Sci. Lett.104, 505-512). By analogy with lunar pyroclastic products, the typical size of pyroclastic melt/glass droplets under these circumstances will be roughly 0.1 mm. Once separated from an asteroidal or planetesimal gravitational field, droplets of this size will generally spiral toward the Sun, rather than reaccrete, because drag forces such the Poynting-Robertson effect quickly modify their orbits (the semimajor axis, in a typical scenario, is reduced by several hundred km during the first trip around the Sun). Assuming a similar process occurred on many of the Earth’s precursor planetesimals while they were still roughly 100 km in diameter, the net effect would be a depleted composition for the final Earth. I have modeled the process of trace-element depletion in the planetesimal mantles, assuming the partial melting was nonmodal and either batch or dynamic in terms of the melt-removal style. Assuming the process is moderately efficient, typical final-Earth Nd/Sm ratios are 0.93-0.96 times chondritic. Depletion is enhanced by a relatively low assumed residual porosity in batch-melting scenarios, but dampened by a relatively high value for “continuous” residue porosity in dynamic melting scenarios. Pigeonite in the source matter has a dampening effect on depletion. There are important side effects to the Nd/Sm depletion. The heat-producing elements, Th, U and K, might be severely depleted. The Eu/Eu ratio of the planet is unlikely to remain precisely chondritic. One of the most inevitable side effects, depletion of the Al/Ca ratio, is consistent with an otherwise puzzling aspect of the composition of the upper mantle. A perfectly undepleted composition for the bulk Earth is dubious.  相似文献   
3.
This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m3 of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (87Sr/86Sr average 0.722087) and S (δ34S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.  相似文献   
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The First Law of Thermodynamics is developed from fundamentals for open, non-equilibrium systems of seawater in motion, exchanging salt and freshwater internally and with their surroundings, and varying continuously in temperature, pressure, and salinity. The aim is clarity and consistency of concepts – and precision in the accompanying vocabulary. Particular attention is given to the way in which salinity variation plays out in the logical structures. The arbitrary constants in the thermodynamic potentials and the various First Law equations are highlighted, in order to remove them, and to recover the physically meaningful content. When this is done, it is seen that salinity variations have little consequence in application of the First Law to the ocean, apart from affecting values of coefficients.  相似文献   
6.
Iapetus (S8) is unique in our solar system in that the albedo of its leading hemisphere is only 0.05 while that of the trailing side is 0.5. Several existing hypotheses are examined and found inadequate. Photometric studies of the dark side are compared to comet nuclei and class D asteroids. It is hypothesized that in the last 106–108 yrs the leading side suffered a high-velocity collision with a cometary body of mass 1013–1015 kg and traveling at a speed of 20 km s–1. About 5–16% of the excavated material was ejected into space, where the vaporized ices dissipated while the dark carbonaceous/silicate material was reaccreted on the leading side. The collision, although not sufficient to break Iapetus' tidal lock, resulted in a period of oscillation of about 5 yr. Until tidal friction reasserted a lock, the oscillation gave rise to the longitude effect, viz., the observed fact that the dark material covers more than 220 of longitude but only 110 of latitude.  相似文献   
7.
RecentR-matrix calculations of electron impact excitation rates in Ov are used to derive the emission line intensity ratios (in energy units) $$\begin{gathered} R_1 = I(2s2p^{ 3} P - 2p^{2 3} P)/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(761.1\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ ), \hfill \\ R_2 = I(2s^{2 1} S_0 - 2s2p^{ 3} P_1 )/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(1218.4\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ ), \hfill \\ \end{gathered} $$ and $$R_3 = I(2s2p^{ 1} P_1 - 2p^{2 1} S_0 )/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(774.5\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ )$$ as a function of electron temperature (T e) and density (N e). These results are presented as plots ofR 1 vsR 2, andR 1 vsR 3, which should allowboth N e andT e to be deduced for the Ov line emitting region of a plasma. Electron densities derived from the (R 1,R 2) and (R 1,R 3) diagrams in conjunction with observational data for several solar features obtained with the Harvard S-055 spectrometer on boardSkylab are found to be compatible, and in good agreement with values ofN e estimated from line ratios in species formed at similar electron temperatures to Ov. In addition, values ofT e determined from (R 1,R 2) and (R 1,R 3) are generally close to that expected theoretically. These results provide experimental support for the accuracy of the diagnostic calculations presented in this paper, and hence the atomic data used in their derivation.  相似文献   
8.
The deposit size frequency (DSF) method has been developed as a generalization of the method that was used in the National Uranium Resource Evaluation (NURE) program to estimate the uranium endowment of the United States. The DSF method overcomes difficulties encountered during the NURE program when geologists were asked to provide subjective estimates of (1) the endowed fraction of an area judged favorable (factorF) for the occurrence of undiscovered uranium deposits and (2) the tons of endowed rock per unit area (factorT) within the endowed fraction of the favorable area. Because the magnitudes of factorsF andT were unfamiliar to nearly all of the geologists, most geologists responded by estimating the number of undiscovered deposits likely to occur within the favorable area and the average size of these deposits. The DSF method combines factorsF andT into a single factor (F·T) that represents the tons of endowed rock per unit area of the undiscovered deposits within the favorable area. FactorF·T, provided by the geologist, is the estimated number of undiscovered deposits per unit area in each of a number of specified deposit-size classes. The number of deposit-size classes and the size interval of each class are based on the data collected from the deposits in known (control) areas. The DSF method affords greater latitude in making subjective estimates than the NURE method and emphasizes more of the everyday experience of exploration geologists. Using the DSF method, new assessments have been made for the young, organic-rich surficial uranium deposits in Washington and idaho and for the solution-collapse breccia pipe uranium deposits in the Grand Canyon region in Arizona and adjacent Utah.  相似文献   
9.
Photoelectric observations of the light intensity from the solar crescent before and after totality were made during the eclipses of 7 March, 1970 and 26 February, 1979. Effective wavelengths were determined by interference filters of 20 nm bandwidth. To obtain the limb darkening function, the resulting intensity curves were analyzed by an extension of the method of Julius in which we take into account the actual lunar limb profile. The limb darkening function at 433 nm was obtained for the region 0.937 < sin < 0.9999. Our results are in good agreement with existing center-to-limb measurements in the region of overlap which extends to sin = 0.99. Additional data were obtained at 600 nm for 0.994 < sin < 0.9999. The curves at both wavelengths show a distinctive limb brightening effect at sin = 0.999.  相似文献   
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