排序方式： 共有13条查询结果，搜索用时 93 毫秒
1.
A. Hofzumahaus T. Brauers U. Platt J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298
The latitudinal variation of the photolysis frequency of ozone to O(1D) atoms, J(O1D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O1D) noon values exhibited a maximum of 3.6×10-5 s-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O1D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O1D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O1D) measurements and simultaneously recorded O3 and H2O mixing ratios. While the latitudinal distribution of J(O1D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH. 相似文献
2.
D. Hongve 《洁净——土壤、空气、水》1994,22(3):117-120
Coloured bog water and an aqueous solution of fulvic acid were exposed to natural sunlight. Up to 67% reduction in colour and 32% reduction in DOC concentration were measured after 12 days exposure. Colour bleaching and reduction in ultraviolet light absorbance were independent of added preservatives. The high molecular weight fraction of dissolved organic matter was most reduced in concentration while substances with low molecular weight increased. The reduction in absorbance (λ = 254 nm) per DOC was most significant for substances with high molecular weight. The final concentration of DOC was highest in samples where microbial activity was suppressed. 相似文献
3.
4.
James C. G. Walker 《Pure and Applied Geophysics》1978,116(2-3):222-231
From time to time there appears in the literature the assertion that photolysis of water vapor could have maintained an appreciable concentration of oxygen in the primitive (prebiological) atmosphere. The implausibility of this assertion is argued in this paper.By itself, photolysis does not provide a source of oxygen because it is usually followed by recombination of the products of photolysis. Only the escape to space (at a much smaller rate) of the hydrogen produced by photolysis of water results in a net source of oxygen. The oxidation state of the primitive atmosphere depended on the relative magnitudes of this net source of oxygen and a volcanic source of hydrogen and other reduced gases. Today the volcanic source of reduced gases is approximately equal to the oxygen source provided by photolysis followed by escape. The oxygen source depends on the mixing ratio of water vapor in the stratosphere, which ultimately determines the rate of escape of hydrogen produced from water vapor. Its magnitude may not have been very different in the past. The volcanic source of hydrogen, on the other hand, is likely to have been much larger when the earth was tectonically young. Hydrogen was therefore released to the primitive atmosphere more rapidly than oxygen, probably. Photochemical reactions with the excess hydrogen maintained oxygen mixing ratios at negligibly small levels. The hydrogen mixing ratio was determined by a balance between the volcanic source (reduced by recombination with oxygen) and escape to space.In time, either because of decline of the volcanic source of hydrogen or because of addition of a biological source of oxygen, the input of oxygen to the atmosphere rose above the input of hydrogen. The oxidation state of the atmosphere changed rapidly. Volcanic hydrogen was now consumed by photochemical reactions with excess oxygen, while the oxygen mixing ratio was determined by a balance between the source (reduced by recombination with volcanic hydrogen) and consumption in reactions with reduced material at the surface. 相似文献
5.
Results from kinetic laboratory studies of reactions of the carbonate radical anion (CO3–·) with aromatic compounds in aqueous solution at T = 298 K are presented. Data were obtained in using a laser photolysis laser long-path absorption (LP-LPLA) apparatus which was designed for direct time-resolved studies of radical reactions. For the reactions of CO3–· with hydroquinone dimethyl ether (2), methyl anisole (3), benzene (4), p-xylene (5), toluene (6), chlorobenzene (7), nitrobenzene (8), and benzonitrile (9), rate coefficients of k2 = (3.0 ± 0.6)·107 M–1 s–1, k3 = (9.7 ± 1.7)·105 M–1 s–1, k4 = (3.2 ± 0.7)·105 M–1 s–1, k5 = (3.8 ± 0.9)·104 M–1 s–1, k6 = (6.8 ± 2.3)·104 M–1 s–1, k7 = (2.7 ± 0.6)·105 M–1 s–1, k8 = (1.4 ± 0.5)·104 M–1 s–1, and k9 < 1.3·102 M–1 s–1 were obtained. In further studies the effect of temperature on the reactions (2), (4), and (5) has been studied. The kinetic data obtained for the reaction of the carbonate radical anion with aromatic compounds were compared to the corresponding reactions of the hydroxyl radical. Finally, these kinetic data were used within a simple model system to investigate the implications of carbonate radical anion kinetics within water treatment processes. It is shown that the degradation of organic pollutants in ·OH-radical based water treatment may proceed via the CO3–·/HCO3· radical under certain conditions. 相似文献
6.
Using a filter radiometer, the meridional profile of the NO2 photolysis frequency, J(NO2), was measured between 50° N and 30° S during the cruise ANTVII/1 September/October 1988 of the research vessel Polarstern on the Atlantic Ocean. Simultaneously, global broadband irradiance and acrosol were monitored. Clean marine background air with low aerosol loads (b
sp=(1–2)×10-5 m-1) was encountered at the latitudes 25° N–30° N and 18° S–27° S, respectively. Under these conditions and an almost cloudless sky J(NO2) reached 7.3×10-3 s-1 (2 sr) for a zenith angle of 30°. Between 30° N and 30° S, the latitudinal variation of the J(NO2) noontime maxima was less than ± 10%, while the mean value at noon was 7.8×10-3 s-1. For the set of all data between 50° N and 30° S, a nearly linear correlation of J(NO2) vs. global broadland irradiance was found. The slope of (8.24±0.03)×10-5 s-1/mW cm-2 agrees within 10% with observations in Jülich (51° N, 6.2° E). 相似文献
7.
Biodegradation of the Photolysis Products of FeIIIEDTA Ethylenediaminetetraacetate (EDTA) is not biodegraded by activated sludge from a wastewater treatment plant. This work shows that after photolysis of FeIIIEDTA, easily degradable metabolites are formed. The OECD Test 302 B yielded a 53% bioelimination with a sunlight irradiation time of 6.5 hours followed by a 4-week incubation. After 20 hours of sunlight irradiation, EDTA is bioeliminated to 92%. One of the photolytic degradation products, ethylenediaminediacetate (EDDA), has been quantitatively eliminated within 14 days following a lag-phase of 2 weeks. The photolysis of the iron complexes of the phosphonates ATMP and DTPMP did not result in biologically degradable metabolites. With these results, the environmental impact of EDTA can be re-evaluated emphasizing the amount and fate of FeIIIEDTA in the environment. FeIIIEDTA was found to be present in effluents of wastewater treatment plants at fractions from 20 to 90% of the total EDTA. FeIIIEDTA has a half life of about 2 hours in sunlit waters. Complexes of EDTA with other metals do not exchange with iron and are photostable. Therefore, EDTA behaves like 2 different compounds: – FeIIIEDTA undergoes fast photolysis with biodegradation of the metabolites. – The other metal-EDTA complexes are persistent in the environment. Ecological arguments against the use of EDTA are therefore still valid for all EDTA-complexes except the one of Fe(III). However, Fe(III) complexes with the phosphonates ATMP and DTPMP do not exhibit such favorable properties over other metal-complexes, and so all arguments against the use of phosphonates are still valid. 相似文献
8.
南京地区大气颗粒物影响近地面臭氧的个例研究 总被引：4，自引：0，他引：4
通过对2008年4月2～7日南京地区地面气象观测数据以及两个站点空气质量(O3、NOx、PM10)监测资料的分析, 发现O3和PM10之间存在一定程度的反相关。利用一个光化学箱模式对该个例中大气颗粒物影响近地面臭氧的过程进行模拟, 结果发现大气颗粒物浓度的升高使得气溶胶光学厚度增加20％～40%, 导致NO2和O3近地面光解率下降20%～30%, OH和HO2自由基浓度分别减少20%～50%, 造成O3净生成率下降30%～40%。研究表明, 颗粒物对光化学过程的抑制造成了大气氧化能力的降低, 是近地面臭氧浓度减少的可能原因。 相似文献
9.
Dongchul Kim Christopher P. Loughner Melanie A. Wetzel Wendy S. Goliff William R. Stockwell 《Journal of Atmospheric Chemistry》2007,57(1):59-71
Photolysis rate parameters depend upon solar actinic flux and chemical species dependent quantum yields and cross sections.
Spectrally resolved measurements of actinic flux should be preferred over flux derived from models for the analysis of field
observations. Actinic flux can be difficult to derive from the irradiance measurements of flat-plate radiometers. It is also
difficult to estimate from models due to uncertainties in the ozone column, aerosol concentrations and distributions, cloud
cover, optical depth and surface albedo. A series of actinic flux measurements were performed at Storm Peak Laboratory (3,210 m
above sea level), Colorado, United States with spectroradiometers during the wintertime (January 07–10, 2004). The site is
relatively remote with a clean atmosphere and during the wintertime the ground is generally covered by fresh snow with a high
albedo. The actinic flux measurements were used to estimate the photolysis rate parameters of ozone, nitrogen dioxide and
formaldehyde. The measured actinic flux and the photolysis rate parameters derived from the flux were compared to calculations
using the Tropospheric Ultraviolet-Visible Model (TUV), version 4.2 (Madronich and Flocke, 1998). The TUV modeled actinic
flux, the measured flux and the photolysis rate parameters derived from them had similar temporal patterns. However there
were significant differences in their magnitude due to uncertainties in the data available to initialize the TUV model and
the calibration of the spectroradiometer. 相似文献
10.
Yu. I. Skurlatov L. S. Ernestova E. V. Vichutinskaya D. P. Samsonov R. I. Pervunina I. V. Semenova V. O. Sjvydly 《洁净——土壤、空气、水》1998,26(1):31-35
It is shown that in the direct photolysis of polychlorinated phenols (2,4,5-TCP, PCP) in aqueous solution, under the action of solar light or UV-radiation from artificial sources, polychlorinated dibenzodioxins (PCDD) and dibenzofurans (PCDF) are found among the products of transformation. A mechanism is suggested of formation of these toxic compounds via the intermediate formation of free radicals. In the oxidation of chlorophenols by singlet oxygen, free radicals are not formed. Addition of fulvic acids prevents formation of PCDD and PCDF in solar light, possibly as a result of trapping of intermediate radicals. 相似文献