Estimate of heavy metals in soil and streams using combined geochemistry and field spectroscopy in Wan-sheng mining area,Chongqing, China     

《International Journal of Applied Earth Observation and Geoinformation》2015

Heavy metals contaminated soils and water will become a major environmental issue in the mining areas. This paper intends to use field hyper-spectra to estimate the heavy metals in the soil and water in Wan-sheng mining area in Chongqing. With analyzing the spectra of soil and water, the spectral features deriving from the spectral of the soils and water can be found to build the models between these features and the contents of Al, Cu and Cr in the soil and water by using the Stepwise Multiple Linear Regression (SMLR). The spectral features of Al are: 480 nm, 500 nm, 565 nm, 610 nm, 680 nm, 750 nm, 1000 nm, 1430 nm, 1755 nm, 1887 nm, 1920 nm, 1950 nm, 2210 nm, 2260 nm; The spectral features of Cu are: 480 nm, 500 nm, 610 nm, 750 nm, 860 nm, 1300 nm, 1430 nm, 1920 nm, 2150 nm, 2260 nm; And the spectral features of Cr are: 480 nm, 500 nm, 610 nm, 715 nm, 750 nm, 860 nm, 1300 nm, 1430 nm, 1755 nm, 1920 nm, 1950 nm. With these features, the best models to estimate the heavy metals in the study area were built according to the maximal R². The R² of the models of estimating Al, Cu and Cr in the soil and water are 0.813, 0.638, 0.604 and 0.742, 0.584, 0.513 respectively. And the gradient maps of these three types of heavy metals’ concentrations can be created by using the Inverse distance weighted (IDW).The gradient maps indicate that the heavy metals in the soil have similar patterns, but in the North-west of the streams in the study area, the contents are of great differences. These results show that it is feasible to predict contaminated heavy metals in the soils and streams due to mining activities by using the rapid and cost-effective field spectroscopy.  相似文献   

基于高光谱的土壤养分含量反演模型研究     

陶培峰  王建华  李志忠  周萍  杨佳佳  高樊琦 《地质与资源》2020,29(1):68-75,84

为实现土壤养分（有机质SOM、全氮TN、全磷TP、全硫TS）含量的快速测定,以建三江创业农场为例,对土壤原始反射率进行了一阶微分（FD）、倒数对数（RL）、倒数一阶微分（FDR）、多元散射校正（MSC）和连续统去除（CR）变换,分析6种光谱变量与土壤养分的相关性,将在α=0.01水平上显著相关的波段作为特征波段,运用多元逐步回归（SMLR）、偏最小二乘回归（PLSR）和BP神经网络（BPNN）三种分析方法分别建立有机质、全氮、全磷和全硫的高光谱预测模型,并利用决定系数（R²）、均方根误差（RMSE）和相对分析误差（RPD）对预测模型进行评价.结果显示,PLSR和BPNN建立的土壤养分含量预测模型均优于SMLR,能极好地预测有机质和全氮含量,同时具有粗略估算全硫含量的能力.三种方法中仅有CR-BPNN能对全磷含量进行粗略估算.对有机质、全氮、全磷和全硫预测效果最佳的模型及其验证集决定系数分别为：MSC-PLSR （0.86）、MSC-PLSR （0.75）、CR-BPNN （0.56）、FDR-BPNN （0.67）.  相似文献