Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

On the orbits and masses of the satellites of the Pluto-Charon system     

Man Hoi Lee  S.J. Peale 《Icarus》2006,184(2):573-583

Two small satellites of Pluto, S/2005 P1 (hereafter P1) and S/2005 P2 (hereafter P2), have recently been discovered outside the orbit of Charon, and their orbits are nearly circular and nearly coplanar with that of Charon. Because the mass ratio of Charon-Pluto is ∼0.1, the orbits of P2 and P1 are significantly non-Keplerian even if P2 and P1 have negligible masses. We present an analytic theory, with P2 and P1 treated as test particles, which shows that the motion can be represented by the superposition of the circular motion of a guiding center, the forced oscillations due to the non-axisymmetric components of the potential rotating at the mean motion of Pluto-Charon, the epicyclic motion, and the vertical motion. The analytic theory shows that the azimuthal periods of P2 and P1 are shorter than the Keplerian orbital periods, and this deviation from Kepler's third law is already detected in the unperturbed Keplerian fit of Buie and coworkers. In this analytic theory, the periapse and ascending node of each of the small satellites precess at nearly equal rates in opposite directions. From direct numerical orbit integrations, we show the increasing influence of the proximity of P2 and P1 to the 3:2 mean-motion commensurability on their orbital motion as their masses increase within the ranges allowed by the albedo uncertainties. If the geometric albedos of P2 and P1 are high and of order of that of Charon, the masses of P2 and P1 are sufficiently low that their orbits are well described by the analytic theory. The variation in the orbital radius of P2 due to the forced oscillations is comparable in magnitude to that due to the best-fit Keplerian eccentricity, and there is at present no evidence that P2 has any significant epicyclic eccentricity. However, the orbit of P1 has a significant epicyclic eccentricity, and the prograde precession of its longitude of periapse with a period of 5300 days should be easily detectable. If the albedos of P2 and P1 are as low as that of comets, the large inferred masses induce significant short-term variations in the epicyclic eccentricities and/or periapse longitudes on the 400-500-day timescales due to the proximity to the 3:2 commensurability. In fact, for the maximum inferred masses, P2 and P1 may be in the 3:2 mean-motion resonance, with the resonance variable involving the periapse longitude of P1 librating. Observations that sample the orbits of P2 and P1 well on the 400-500-day timescales should provide strong constraints on the masses of P2 and P1 in the near future.  相似文献   

The nature of Europa's dark non-ice surface material: Spatially-resolved high spectral resolution spectroscopy from the Keck telescope     

John R. Spencer  William M. Grundy  Robert W. Carlson  Gary B. Hansen 《Icarus》2006,182(1):202-210

We present new 1.45-1.75 μm spectra of Europa's dark non-ice material with a spectral resolution (λ/δλ) of 1200, obtained by using adaptive optics on the Keck telescope to spatially separate the spectrum of the non-ice material from that of the surrounding ice-rich regions. Despite the great increase in spectral resolution over the previous best spectra of the non-ice material, taken with Galileo's near-infrared mapping spectrometer (NIMS) with λ/δλ=66, no new fine-scale spectral structure is revealed. The smoothness of the spectra is inconsistent with available laboratory spectra of crystalline hydrated salts at Europa temperatures, but is more consistent with various combinations of non-crystalline hydrated salts and/or hydrated sulfuric acid, as have been matched to the lower-resolution NIMS spectra.  相似文献   

Understanding the behavior of Prometheus and Pandora     

Alison J. Farmer  Peter Goldreich 《Icarus》2006,180(2):403-411

We revisit the dynamics of Prometheus and Pandora, two small moons flanking Saturn's F ring. Departures of their orbits from freely precessing ellipses result from mutual interactions via their 121:118 mean motion resonance. Motions are chaotic because the resonance is split into four overlapping components. Orbital longitudes were observed to drift away from predictions based on Voyager ephemerides. A sudden jump in mean motions took place close to the time at which the orbits' apses were antialigned in 2000. Numerical integrations reproduce both the longitude drifts and the jumps. The latter have been attributed to the greater strength of interactions near apse antialignment (every 6.2 yr), and it has been assumed that this drift-jump behavior will continue indefinitely. We re-examine the dynamics of the Prometheus-Pandora system by analogy with that of a nearly adiabatic, parametric pendulum. In terms of this analogy, the current value of the action of the satellite system is close to its maximum in the chaotic zone. Consequently, at present, the two separatrix crossings per precessional cycle occur close to apse antialignment. In this state libration only occurs when the potential's amplitude is nearly maximal, and the “jumps” in mean motion arise during the short intervals of libration that separate long stretches of circulation. Because chaotic systems explore the entire region of phase space available to them, we expect that at other times the Prometheus-Pandora system would be found in states of medium or low action. In a low action state it would spend most of the time in libration, and separatrix crossings would occur near apse alignment. We predict that transitions between these different states can happen in as little as a decade. Therefore, it is incorrect to assume that sudden changes in the orbits only happen near apse antialignment.  相似文献   

Origin of chaos in the Prometheus-Pandora system     

Peter Goldreich  Nicole Rappaport 《Icarus》2003,166(2):320-327

We demonstrate that the chaotic orbits of Prometheus and Pandora are due to interactions associated with the 121:118 mean motion resonance. Differential precession splits this resonance into a quartet of components equally spaced in frequency. Libration widths of the individual components exceed the splitting, resulting in resonance overlap which causes the chaos. Mean motions of Prometheus and Pandora wander chaotically in zones of width 1.8 and 3.1 deg yr⁻¹, respectively. A model with 1.5 degrees of freedom captures the essential features of the chaotic dynamics. We use it to show that the Lyapunov exponent of 0.3 yr⁻¹ arises because the critical argument of the dominant member of the resonant quartet makes approximately two separatrix crossings every 6.2 year precessional cycle.  相似文献   

The spectral variability of Triton from 1997-2000     

Michael D Hicks  Bonnie J Buratti 《Icarus》2004,171(1):210-218

We present the results of a three-year observational program of long-slit spectroscopy and UBVRI photometry of Triton. We find evidence for short-lived albedo variations at wavelengths less than 0.5 μm with the most notable reddening event measured in October 1997 and “normal” colors returning by May 1998. We report a possible variation in the relative 0.73/0.89 μm methane absorption band strengths, suggesting that the transport or denudation of this species may play a major role in the reddening events.  相似文献   

海洋水色卫星遥感器特性参数探讨     

于连生 《海洋技术学报》2001,20(2):76-80

为了评价海洋水色卫星遥感器特性参数的优劣，确定仪器的计量特性及其使用价值，准确的理解和科学的定义仪器的特性参数是非常重要的。作者曾有幸参加了海洋水色卫星的立项论证工作，本文就作者的一些工作体会，对海洋水色卫星遥感器的特性参数作初步探讨。  相似文献   

Origin and thermal evolution of icy satellites     

Angioletta Coradini  Costanzo Federico  Olivier Forni  Gianfranco Magni 《Surveys in Geophysics》1995,16(4):533-591

The paper reviews the problem of formation and evolution of the so-called regular satellites of the giant planets, and it consists of two parts: the first describes the possible origin of the satellites, the second studies their evolution, attempting to stress the relations of the present status of the satellites with their evolutionary history.The formation of regular satellite systems around giant planets is probably related to the formation of the central planet. Some characteristics of regular satellite systems are quite similar, and suggest a common origin in a disk present around the central body. This disk can originate through different mechanisms which we will describe, paying attention to the so-called accretion disk model, in which the satellite-forming material is captured. The disk phase links the formation of the primary body with the formation of satellites. The subsequent stages of the disk's evolution can lead first to the formation of intermediate size bodies, and through the collisional evolution of these bodies, to the birth of satellite embryos able to gravitationally capture smaller bodies.Given the scenario in which icy satellites may be formed by homogeneous accretion of planetesimals made of a mixtures of ice and silicates, if no melting occurs during accretion, the satellites have a homogeneous ice-rock composition. For the smaller satellites this homogeneous structure should not be substantially modified; only sporadic local events, such as large impacts, can modify the surface structure of the smaller satellites. For the larger satellites, if some degree of melting appears during accretion, a differentiation of the silicate part occurs, the amount of differentiation and hence the core size depending on the fraction of gravitational potential energy retained during the accumulation process. Melting and differentiation soon after the accretion, for the larger satellites, could also depend on the convective evolution in presence of phase transitions and generate an intermediate rock layer, considerably denser than the underlying, still homogeneous core, and unstable to overturning on a geologic time scale. Moreover the liquid water mantle could be a transient feature because the mantle would freeze over several hundred million years. For these large bodies the stable configuration is expected to be one consisting of a silicate core and a mantle of mixed rock and ice.  相似文献   

利用SPOT和ETM+影像进行县级土地利用调查--以河北省万全县为例   总被引：7，自引：0，他引：7  

朱运海 江涛曹银璇  张运生 《四川测绘》2004,27(1):26-29

本文以SPOT和ETM 影像作为主要信息源，经过对图像进行几何纠正、配准、增强和融合等一系列处理后，在ARCVIEW GIS基础上，成功完成了对河北省万全县土地资源利用情况的调查分析。同时还对应用遥感技术成功获取土地资源利用信息的方法和技术进行了探讨。  相似文献   

Stratospheric warming effects on the tropical mesospheric temperature field   总被引：1，自引：0，他引：1  

M.G. Shepherd  D.L. Wu  I.N. Fedulina  S. Gurubaran  J.M. Russell  M.G. Mlynczak  G.G. Shepherd 《Journal of Atmospheric and Solar》2007,69(17-18):2309

Temperature observations at 20–90 km height and 5–15°N during the winter of 1992–1993, 1993–1994 and 2003–2004, from the Wind Imaging Interferometer (WINDII) and Microwave Limb Sounder (MLS) experiments on the Upper Atmosphere Research Satellite (UARS) satellite and the Sounding the Atmosphere using Broadband Emission Radiometry (SABER) experiment on the Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics (TIMED) satellite are analyzed together with MF radar winds and UK Meteorological Office (UKMO) assimilated fields. Mesospheric cooling is observed at the time of stratospheric warming at the tropics correlative with stratospheric warming events at middle and high latitudes. Planetary waves m=1 with periods of 4–5, 6–8, 10 and 12–18 days are found to dominate the period. Westward 7- and 16-day waves at the tropics appear enhanced by stationary planetary waves during sudden stratospheric warming events.  相似文献