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This study considered the possibility of using visible and near infrared (VNIR) spectral absorption feature parameters (SAFPs) in predicting the concentration and mapping the distribution of heavy metals in sediments of the Takab area. In total, 60 sediment samples were collected along main streams draining from the mining districts and tailing sites, in order to measure the concentration of As, Co, V, Cu, Cr, Ni, Hg, Ti, Pb and Zn and the reflectance spectra (350–2500 nm). The quantitative relationship between SAFPs (Depth500nm, R610/500nm, R1344/778nm, Area500nm, Depth2200nm, Area2200nm, Asym2200nm) and geochemical data were assessed using stepwise multiple linear regression (SMLR) and enter multiple linear regression (EMLR) methods. The results showed a strong negative correlation between Ni and Cr with Area2200nm, a significant positive correlation between As and Asym2200nm, Ni and Co with Depth2200nm, as well as Co, V and total values with Depth500nm. The EMLR method eventuated in a significant prediction result for Ni, Cr, Co and As concentrations based on spectral parameters, whereas the prediction for Zn, V and total value was relatively weak. The spatial distribution pattern of geochemical data showed that mining activities, along with the natural weathering of base metal occurrences and rock units, has caused high concentrations of heavy metals in sediments of the Sarough River tributaries. 相似文献
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Sagnac型干涉成像光谱仪研制及干涉成像光谱实验 总被引：3，自引：0，他引：3
空间调制干涉成像（傅里叶变换）光谱仪（SMIFTS）是一种有重要的研究和应用价值的空间遥感器。依据应用要求和信噪比方程设计并研制了Sagnac型干涉成像（傅里叶变换）光谱仪原理样机。用该样机进行了实验室干涉成像光谱实验，获取了较为清晰的可见光、近红外谱段干涉成像图像。对其中各像元的干涉图进行数据处理和计算，提取出了光谱特征明显的成像光谱图像和与被测图样光谱特征相符的像元光谱。由实测光谱辐射亮度曲线反演计算出的光谱反射曲线与标准仪器测得的图样光谱反射特性曲线进行了比较，结果表明二者对应相似。 相似文献
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应用多光谱ASTER数据对ETM遥感异常的定性判别研究——以东昆仑五龙沟为例 总被引：5，自引：0，他引：5
文中讨论了新的找矿参数——蚀变遥感异常的地质基础和光谱前提,在矿床地质学和蚀变矿物光谱参数特征的基础上,编制了一张用于遥感异常提取及对其地质解释的表格。ETM遥感异常提取技术已在全国推广,ASTER数据可以在三个方面对已推广的ETM起到重要的补充作用：1.利用短波红外增设的波段,对某些矿致异常区分其矿化（矿床）类型;2.利用增设的热红外波段区分某些岩性;3.可有助于解决ETM因第7波段太宽而产生的许多疑难问题。本文以东昆仑五龙沟为例讨论了ASTER对于解决ETM遥感异常性质判别困难方面的作用。 相似文献
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The multi-source data fusion methods are rarely involved in VNIR and thermal infrared remote sensing at present.Therefore,the potential advantages of the two kinds of data have not yet been adequately tapped,which results in low calculation precision of parameters related with land surface temperature.A new fusion method is put forward where the characteristics of the high spatial resolution of VNIR(visible and near infrared) data and the high temporal resolution of thermal infrared data are fully explored ... 相似文献
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Determination of multispectral specular reflectance is an important tool for ore identification in reflected light microscopy, and may be used for automated characterization of ores. However, reflectance values can be affected by compositional variations in a way that is seldom understood. The aim of the present work is to investigate this problem in chromite, an ore whose composition may show typically large natural variations as member of the spinel family, and whose relatively high reflectance variations are apparently unpredictable. For this research, eighteen samples of chromian spinel covering a large range of compositions in the base of the Hagerthy prism were selected for microprobe analysis and reflectance measure on polished sections. The samples belong to a variety of deposits and types (ultramafic massif, ophiolitic, and metamorphosed types: Ojén and Ronda Massifs, Spain; Mayarí, Moa-Baracoa, Camagüey and Sagua de Tánamo, Cuba; Golyamo Kemenyane, Avren and Yakovitsa, Bulgaria). The specular reflectances are characterized as multispectral values, measured at thirteen intervals (50 nm each) in the VNIR region (Visible and Near-Infrared: 400–1000 nm), using the automated CAMEVA System.The relationship between compositional and reflectance values is studied by multivariate analysis and subsequently tested on independent samples. For this purpose, the samples have been grouped in two sets: a larger population of fifteen samples constitutes the initial data set for mathematical processing, while a selection of three samples of widely differing compositions is used to test the resulting functions, so as to gain a critical appraisal of their validity.The results obtained show that the specular reflectance of chromite depends on composition and can be used to estimate compositional parameters, as #Cr = Cr/(Cr + Al) or #Mg = Mg/(Mg + Fe2+), but this relationship is complex and does not allow simple direct determinations, due to the multiplicity of possible changes and coupled substitutions (e.g. Al–Cr–Fe3+, or Mg-Fe2+, Ni, Zn, Ti …) in the chromian spinel family. On the other hand, the relationship of chromite composition with deposit type is also detectable through the reflectance values, but with a higher uncertainty. Reflectance increases with increasing Cr and Fe3+ contents in all cases, but the relationship of reflectance with Mg seems to be specific of the deposit type: while reflectance increases with increasing #Mg in the Ojén chromites, it shows the opposite behaviour in podiform chromites. Although these results should be regarded as preliminary until further studies on larger sample populations can be achieved, they are suggestive of possible practical applications for exploration, e. g. to approach Cr-spinel compositions or chromite deposit typology, early in an exploration campaign, by inexpensive reflected light determination of specular reflectance in a few samples. 相似文献
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Yunzhao WU Jun CHEN Junfeng JI Peng GONG Qilin LIAO Hongrui MA 《中国地球化学学报》2006,25(B08):225-226
Conventional methods for investigating soil heavy metal contamination based on raster sampling and chemical analysis are time consuming and relatively expensive. Reflectance spectroscopy within the visible-near-infrared （VNIR） region is known for being rapid, convenient, and accurate. Due to low abundance, heavy metals in soils cannot exhibit their inherently spectral features. The objective of this study were （1） to examine the possibility of reflectance spectra as a rapid method to assess Ni, Cr, Cu, Hg, Zn, As, Pb, and Cd in soils, and （2） to explore the mechanism by which to predict spectrally featureless heavy metals. Two research areas located in the south （120 samples） and north （61 samples） of Nanjing City were researched. Reflectance spectra of the samples were recorded on a Perkin-Elmer Lambda 900 spectrophotometer. Partial least-square regression （PLSR） approach was used to develop calibration equations between the spectral data and measured values for heavy metals. The prediction results of the two areas were consistent. Except for Cd all the other elements could be successfully predicted using the reflectance spectra. The prediction accuracy for Ni, Cr, and Cu was highest, while that for Hg and Cd was lowest. In order to further explore the physicochemical mechanism behind the relations between reflectance spectra and heavy metals, one more principal component analysis （PCA） was done for nine elements （eight heavy metals and Fe）. The results of PCA for the both areas were also consistent. Loading plot of factors 1 and 2 from the results of PCA showed that Ni, Cr and Cu, the prediction accuracy of which was highest, were clustered together with Fe. For the other elements that were less correlated with Fe, their prediction accuracy was also lower than that of the three elements. Fe is spectrally active and can exhibit its absorption features. Therefore, the inter-correlation between heavy metals and spectrally active total Fe is the major mechanism by which to predict spectrally featureless trace metals. This study for the two areas showed the potential of reflectance spectra to predict microelements in soils. 相似文献
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《Chemie der Erde / Geochemistry》2021,81(1):125729
We report the textures, mineralogy and mineral chemistry of the Mukundpura matrix component, a clast-bearing, brecciated, new CM2 carbonaceous chondrite. Like other CMs, Mukundpura is matrix-enriched and has experienced different degrees of aqueous alteration with evidences of fracturing and compaction of clasts due to the impact. A few relict chondrule clasts and CAIs (diopside and spinel) survived despite of the alteration amidst accessory phases of olivine, magnetite, sulphides and calcite. X-Ray Diffraction (XRD), Visible Near Infrared (VNIR) and Fourier Transform Infrared (FTIR) spectroscopic studies reveal higher phyllosilicate content (∼90 %) comprising of both Mg and Fe-serpentine and abundant serpentine-sulphide intergrowths. Even then, the presence of accessory olivine as relict clasts can be interpreted from the presence of certain typical olivine absorptions in the FTIR spectra. The non-stoichiometric, Tochilinite-Cronstedtite occurrences probably relate to broadening of XRD and FTIR spectra and can be explained by coupled Al–Si and Mg–Al substitutions in talc and serpentine. The FTIR spectra suggest widespread transformation of olivine to serpentine, unlike the largely unaltered chondrules. The correlations of mineralogical alteration index with FeO/SiO2 and S/SiO2 in different domains of matrix suggest different extent of alterations. Thus, the aqueous alteration is extensive but not pervasive. The majority of alteration seems to have occurred within the asteroidal parent body. The Mukundpura CM2 thus preserves a unique combination of relict chondrules and highly aqueous altered variegated matrix clasts, although the surface mineralogy resembles the C-type asteroids recently probed by OSIRIS-REx and Hayabusa-2 missions. 相似文献
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多光谱遥感技术预测矿产资源的潜能——以蒙古国欧玉陶勒盖铜金矿床为例 总被引：9，自引：0，他引：9
建议把蚀变遥感异常作为一个新的找矿参数,文中讨论了蚀变遥感异常的地质基础和光谱前提。在矿床地质学和蚀变矿物光谱参数特征的基础上,编制了一张用于蚀变遥感异常提取及对其地质解释的表格。设计了从ETM+和ASTER数据中提取羟基蚀变矿物组合信息的独特流程方案。这个方案称之为"去干扰异常主分量门限化技术",文中示以简化的流程图。ETM+数据用来研究位于欧玉陶勒盖铜金矿床东北部的汉保各德中酸性火成杂岩体岩性特征,ASTER近红外和短波红外数据用来提取欧玉陶勒盖斑岩铜金矿矿床及其近区的羟基异常,通过选择性主分量分析判断欧玉陶勒盖铜金矿矿床的矿床类型为斑岩型。已知矿区各矿体的羟基异常都十分清晰,此外在矿床西部还发现了三个新的有希望的羟基异常。此工作进一步展示出多光谱遥感技术对于金属矿床的预测具有极好的潜能。 相似文献
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空间调制干涉成像 (傅里叶变换 )光谱仪 (SMIFTS)是一种有重要的研究和应用价值的空间遥感器。该文介绍了研制的Sagnac型干涉成像 (傅里叶变换 )光谱仪原理样机及用该样机进行的外场干涉成像光谱实验。实验获取了可见光、近红外谱段干涉成像图像。对其中各像元的干涉图进行数据处理和计算 ,提取出了光谱特征明显突出的外场干涉成像光谱图像和与被测目标光谱特征相符的像元光谱 相似文献