高能偏振能量色散X射线荧光光谱仪应用现状和进展   总被引：4，自引：2，他引：2  

吉昂  李国会  张华 《岩矿测试》2008,27(6):451-462

对高能偏振能量色散X射线荧光光谱仪基本特点及其用于环境、生物、地质样品中痕量元素的分析和RoSH检测等领域的应用现状予以介绍,并对二次靶与滤光片在痕量元素分析中的应用作了探讨。  相似文献   

XEPOS型偏振能量色散X射线荧光光谱仪分析蒙古铁矿石   总被引：5，自引：4，他引：1  

耿刚强  宁国东  王巧玲  丁慧  朱明达  白福全  董海成  牛素琴  王再田 《岩矿测试》2008,27(6):423-426

以熔融玻璃片和粉末压片制样,采用XEPOS型偏振能量色散X射线荧光光谱仪,建立了铁矿石中总铁、氧化钙、氧化镁、二氧化硅、三氧化二铝、硫、磷、铜等组分的快速分析方法。着重讨论硫、磷两元素测定的可行性和Lucas-Tooth、Price数学校正模型的适应性和改善方法的途径。  相似文献   

A neutron diffraction study of alkali cation migration in montmorillonites     

D. Gournis  A. Lappas  M. A. Karakassides  D. Többens  A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58

Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.  相似文献   

基于EOF分析对南海西北海域水体光谱特性的研究   总被引：1，自引：0，他引：1  

付东洋  黄宇业  刘大召  廖珊  余果  张小龙 《海洋学报(英文版)》2020,39(7):107-114

This study presents an analysis of the spectral characteristics of remote sensing reflectance(R_(rs)) in northwestern South China Sea based on the in situ optical and water quality data for August 2018.R_(rs)was initially divided into four classes,classes A to D,using the max-classification algorithm,and the spectral properties of whole R_(rs) were characterized using the empirical orthogonal function(EOF) analysis.Subsequently,the dominant factors in each EOF mode were determined.The results indicated that more than 95% of the variances of R_(rs) are partly driven by the back-scattering characteristics of the suspended matter.The initial two EOF modes were well correlated with the total suspended matter and back-scattering coefficient.Furthermore,the first EOF modes of the four classes of R_(rs)(A-D R_(rs)-EOF_1) significantly contributed to the total variances of each R_(rs) class.In addition,the correlation coefficients between the amplitude factors of class A-D R_(rs)-EOF_1 and the variances of the relevant water quality and optical parameters were better than those of the unclassified ones.The spectral shape of class AR_(rs)-EOF_1 was governed by the absorption characteristic of chlorophyll a and colored dissolved organic matter(CDOM).The spectral shape of class B R_(rs)-EOF_1 was governed by the absorption characteristic of CDOM since it exhibited a high correlation with the absorption coefficient of CDOM(a_g(λ)),whereas the spectral shape of class C R_(rs)-EOF_1 was governed by the back-scattering characteristics but not affected by the suspended matter.The spectral shape of class D R_(rs)-EOF_1 exhibited a relatively good correlation with all the water quality parameters,which played a significant role in deciding its spectral shape.  相似文献   

海洋生物-光学算法研究──南黄海叶绿素浓度的估算     

傅克忖  曾宪模  李宝华  曾晓起  荒川久幸 《海洋与湖沼》1997,28(3):238-244

根据１９９５年９月中日合作南黄海现场观测资料，对南黄海生物－光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素α对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。  相似文献   

赤潮生物种类特征光谱获取技术   总被引：1，自引：0，他引：1  

范学炜  张汉德 《海洋科学进展》2002,20(2):83-90

较为系统地研究了赤潮生物水体反射率曲线获取方法。通过对 2类反射率反演方法得出的反射率曲线与实际反射率曲线进行比较 ,得出在不具备大气环境参数的情况下 ,经验线性法的反演结果与实际反射率曲线最接近的结论 ,并进一步对正常海水和赤潮生物水体的光谱特性进行分析 ,提取出赤潮生物水体的特征光谱。这是进行赤潮监测和识别的重要前提  相似文献   

偏振激光散斑的相关性研究     

冯一丁 《中国海洋大学学报(自然科学版)》1994,(3)

采用发送一束线偏振激光产生散斑的方法，研究线偏振激光散斑、＂平均椭圆偏振＂激光散斑以及非偏振激光散斑的相关性和精细结构。指出：当漫射器为一片毛玻璃时，散斑激光是线偏振的．其方向与入射激光束相同；当漫射器为涂无光白漆的毛玻璃时，散斑激光是部分或全部退偏的，涂层越厚，退偏越甚。对于强线偏振散斑场，当偏振方向改变时，散斑的精细结构无明显变化，即使是两个正交方向上的散斑图，也保持良好的相关性。对于非偏振散斑场，当照明激光束的偏振方向改变时．散斑精细结构有明显变化。  相似文献   

海洋生物-光学算法研究──南黄海叶绿素浓度的估算     

傅克忖  曾宪模  李宝华  曾晓起  荒川久幸 《海洋与湖沼》1997,28(3):238-244

根据1995年9月中日合作南黄海现场观测资料，对南黄海生物一光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素a浓度对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。  相似文献   

Sources and hydrothermal alteration of organic matter in Quaternary sediments: A synthesis of studies from the Central Gulf of California     

Bernd R. T. Simoneit 《Marine and Petroleum Geology》1986,3(4)

Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone.  相似文献   

Microphytobenthos vertical migratory photoresponse as characterised by light-response curves of surface biomass     

Joo Serdio  Helena Coelho  Snia Vieira  Snia Cruz 《Estuarine, Coastal and Shelf Science》2006,68(3-4):547

The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (F_o); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m⁻² s⁻¹, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by F_o or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m⁻² s⁻¹, maximum values under 100–250 μmol m⁻² s⁻¹, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring F_o or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments.  相似文献