Geostatistical inversion of coupled problems: dealing with computational burden and different types of data     

《Journal of Hydrology》2003,281(4):251-264

Practical application of geostatistical inversion to coupled problems is hampered by a number of difficulties. In this paper, we address two of them: first, the computational cost of sensitivity (Jacobian) matrices and, second, the evaluation of the relative weights of different types of data. Regarding the first, we revise the adjoint state equations to propose a form whose cost is independent of the number of unknown parameters and only grows with the number of observation wells. Regarding the second, we derive expressions for the relative weights of different types of data. These expressions are based on minimizing the expected likelihood, rather than the likelihood itself. The efficiency of both improvements is tested on a synthetic example. The example analyzes a wide range of groundwater flow and solute transport conditions. Yet, the expected likelihood consistently yields the optimal weights. The proposed form of the adjoint state equations leads to one order of magnitude reduction in CPU time with respect to the conventional sensitivity equations.  相似文献   

Oxidation of As-bearing gold ore—a comparison of batch and column experiments     

《Journal of Geochemical Exploration》2004,81(1-3):59-70

This study deals with the experimental determination of the rate of weathering and As release from Au-bearing sulfide ores of the Mokrsko-West deposit (Czech Republic). The elevated As contents in the ore and the possible As mobilisation must be taken into account due to the close proximity of the deposit to the Vltava River, a source of drinking water for Prague. Crushed and homogenized ore material was divided into four grain-size fractions showing uniform chemical and mineralogical composition and subjected to batch and column leaching experiments. The most important reactions controlling metal leaching include (i) oxidation of sulfides, (ii) carbonate equilibrium and (iii) precipitation of hydrated ferric oxides (HFO). Hydrated ferric oxides were found to be important sorbents of mobilized As. The highest concentration of As in the leachates was obtained from the 64–1000 μm fraction. The oxidation rate in the agitated batch experiment calculated on the basis of sulfate concentrations is an order of magnitude higher (3.8×10⁻⁹ to 4.4×10⁻⁸ mol SO₄²⁻ h⁻¹ g⁻¹) than in the static column experiment (9.6×10⁻¹⁰ to 7.4×10⁻⁹ mol SO₄²⁻ h⁻¹ g⁻¹). The higher oxidation rate of batch experiments is explained by abrasion of oxidation products (mainly HFO) and by further exposition of reaction surfaces of the sulfide grains.  相似文献   

Characterization of hydrogeologic properties for a multi-layered alluvial aquifer using hydraulic and tracer tests and electrical resistivity survey     

Jeong-Woo Kim  Heechul Choi  Jin-Yong Lee 《Environmental Geology》2005,48(8):991-1001

A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties. The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt, sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10⁻² cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10⁻⁴ cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10⁻³ and 2.44×10⁻² cm/s with a geometric mean of 6.89×10⁻³ cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests, and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties of the multi-layered alluvial aquifer.  相似文献   

Laboratory simulation of natural leaching processes of eastern USA oil shale     

M. Shirav  T. L. Robl 《Environmental Geology》1993,22(1):88-94

Raw and retorted spent oil shales from Kentucky, as well as soil and overburden materials, were subjected to laboratory and field leaching tests. Standard batch leaching tests grossly undervalue the amount of dissolved ions as measured in the field, being too brief to enable slow reactions of the mineral matrix, such as hydrolysis and oxidation of sulfides or reactions of acidic leachates with soluble components of the clays. Laboratory column tests, devised to closely simulate natural leaching processes, achieved concentration levels and elemental release patterns similar to those found in field tests. The column tests provide a reliable means to assess the leachability of metals in these materials.  相似文献   

The Contribution of Ecdysis to the Fate of Copper, Zinc and Cadmium in Grass Shrimp, Palaemonetes pugio Holthius     

K. A. Keteles  J. W. Fleeger 《Marine pollution bulletin》2001,42(12)

Depuration through ecdysis by grass shrimp, Palaemonetes pugio, was examined by exposure to a sublethal mixture of copper, zinc and cadmium for 72 h, followed by placement in uncontaminated water to molt. Percent eliminated with the exuviae varied for each metal; of the total intermolt body burden, 11% Cu, 18% Zn and 26% Cd was associated with the exuviae. Cu concentrations of intermolt exoskeletons were significantly higher than of the exuviae of post-ecdysis shrimp suggesting that Cu contained in the exoskeleton was reabsorbed before molting. Exuvial Cd concentration was not significantly different than the concentration of the intermolt exoskeleton, suggesting that most Cd in the exoskeleton was depurated with the exuviae. Although Zn whole-body burdens were lower after a molt, Zn losses were most likely due to excretion because exuvial concentrations were significantly lower than in the intermolt exoskeleton. Cu, Cd and Zn concentrations in exuviae shed in metal-enriched water were significantly higher due to adsorption than exuviae produced in uncontaminated water.  相似文献   

Partitioning of heavy metals on soil samples from column tests   总被引：3，自引：0，他引：3  

R. N. Yong  W. Z. W. Yaacob  S. P. Bentley  C. Harris  B. K. Tan   《Engineering Geology》2001,60(1-4):307-322

In this study, column tests were used to determine the retention capability of three types of estuarine alluvia collected adjacent to landfill sites in South Wales. Selective sequential extraction (SSE) was used to study the retention mechanisms of heavy metals in the soil columns obtained from leaching experiments. Acid digestion was later used to check the validity of the SSE results. Breakthrough curves show good retention of heavy metal ions (Pb, Cu, and Zn) by all soils, where almost 99% of heavy metals were retained with the C_e/C_o values in the order of 10⁻³. The retention strength of these soils was observed to be constant up to five pore volumes (PV). This corresponds with the pH of the effluents and pore water of soil slices, which also show good buffering capacity against very acidic leachate up to 5PV. The heavy metal extraction profiles from SSE show very similar trends with the retention profiles from the leaching experiments, where heavy metals were retained mainly at the top part where the leachate entered the column. SSE indicates qualitatively that heavy metals precipitated with carbonates and amorphous materials (oxides/hydroxides) are higher than heavy metal retention via exchangeable mechanisms. The mass balance calculation gives range of deviation of 1–16% of the total soil extraction. The distribution of the heavy metals with various soil constituents are ranked in the following order: Carbonates>Amorphous oxides hydroxides>Organic matter>Exchangeable phases.  相似文献   

大气重力信号的理论计算及其检测   总被引：22，自引：6，他引：16       下载免费PDF全文

孙和平  罗少聪 《地球物理学报》1998,41(5):634-641

基于标准大气定律和大气圆柱体分布模型,本文引进了大气重力格林函数,用离散格积方法求得了大气对重力场观测的影响,对台站高程、周围地形和地表温度变化等因素的影响问题进行了讨论．结果说明台站近区气压变化是大气重力信号的主要贡献者,考虑大气质量负荷引起的弹性地球形变效应后,对距台站0．5°的区域积分获得的大气重力导纳值为-0．3603μGal／hPa,占全球大气变化引起的总信号的90％以上,这一理论模型结果与超导重力仪实测结果相吻合,并能较有效地用于消除重力观测中的气压干扰成分．  相似文献   

Results based management in fisheries: Delegating responsibility to resource users     

《Marine Policy》2015

While the notion of results based management has been devoted recent attention in the context of reforming European fisheries management, it remains unclear what it entails. A conceptual model of results based management in fisheries is proposed as a way for public authorities to delegate specific management and documentation responsibilities to resource users. The model comprises three defining features: (1) That authorities define measurable objectives for the utilization of fisheries resources; (2) that resource users are made responsible for achieving these objectives and for (3) providing documentation that allows for an audit of the extent to which they are met. Selected cases are used to illustrate these features. Rationales and prospects of introducing results based management as an alternative in a European fisheries management context are discussed, giving consideration to how it may be pursued under the reformed common fisheries policy.  相似文献   

A new analysis of the ESO Very Large Telescope (VLT) observations of Titan at 2 μm     

T. Cours  P. Rannou  A. Hamdouni 《Planetary and Space Science》2010,58(13):1708-1714

We have performed an analysis of ESO Very Large Telescope (VLT) observations of Titan at 2 μm. The data were acquired with the Nasmyth Adaptative Optics System Near-Infrared Imager and Spectrograph (NAOS/CONICA), on the 16th of January 2005, that is 2 days after the landing of the Huygens probe (Hirtzig et al., 2007). The data consist in 21 spectra taken along two diameters of Titan’s disk at wavelengths between 2.03 and 2.5 μm. This range covers a part of the 2 μm methane window and the adjacent band. The data received a preliminary analysis in a recent paper (Negrão et al., 2007), essentially focused on the surface albedo near Huygens landing site. In this work, we perform an in-depth analysis to retrieve information about several aspects: the latitude haze distribution in the stratosphere and in the low atmosphere, the latitudinal variation of the surface albedo and its spectral behaviour. Also, this analysis allowed us to make sensitivity tests on the influence of the scatterer profiles on the retrieved surface albedo and its spectral slope. The news analysis confirms that, as was the case with VIMS observations at the same epoch, the Northern (currently winter) Hemisphere contains more haze than the southern one (Summer Hemisphere). The sensitivity tests show that the scatterer profiles have just a little impact on the surface albedo and its spectral slope. The analysis seems to confirm the presence of H₂O and CH₄ ices.  相似文献   

Regional GHG reduction targets based on effort sharing: a comparison of studies     

Niklas Höhne  Michel den Elzen  Donovan Escalante 《Climate Policy》2014,14(1):122-147

Over 40 studies that analyse future GHG emissions allowances or reduction targets for different regions based on a wide range of effort-sharing approaches and long-term concentration stabilization levels are compared. This updates previous work undertaken for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Regional reduction targets differ significantly for each effort-sharing approach. For example, in the Organisation for Economic Co-operation and Development (OECD) 1990 region, new proposals that emphasize the equity principles of responsibility, capability, and need, and those based on equal cumulative per capita emissions (carbon budgets), lead to relatively stringent emissions reduction targets. In order to reach a low concentration stabilization level of 450?ppm CO₂e, the allowances under all effort sharing approaches in OECD1990 for 2030 would be approximately half of the emissions of 2010 with a large range, roughly two-thirds in the Economies in Transition (EIT), roughly at the 2010 emissions level or slightly below in Asia, slightly above the 2010 level in the Middle East and Africa and well below the 2010 level in Latin America. For 2050, allowances in OECD1990 and EIT would be a fraction of today's emissions, approximately half of 2010 emission levels in Asia, and possibly less than half of the 2010 level in Latin America.

Policy relevance

The concept of equity and the stringency of future national GHG reduction targets are at the heart of the current debate on the new international climate change agreement to be adopted in 2015. Policy insights gained from an analysis of over 40 studies, which have quantitatively analysed the proposed GHG reduction targets, are presented. It is found that the outcome of effort-sharing approaches is often largely determined by the way the equity principle is implemented and that the distributional impacts of such approaches can be significantly different depending on the criteria used, the stabilization level and shape of the global emissions pathway. However, the current literature only covers a small proportion of the possible allocation approaches. There should thus be an in-depth modelling comparison to ensure consistency and comparability of results and inform decision making regarding the reduction of GHG emissions.  相似文献