In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer     

Robel A. Gebrekristos  Allen M. Shapiro  Brent H. Usher 《Hydrogeology Journal》2008,16(4):629-639

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10^?6 m²/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment.  相似文献   

石墨炉原子吸收分光光度法测定土壤样品中痕量镉   总被引：2，自引：0，他引：2  

董丽  沈谷苗 《江苏地质》2004,28(1):42-44

研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应，并比较了两种试样分解体系。方法检出限为0.01pg／L，精密度(RSD，n=8)为3．29％-7．69％，经国家一级标准物质分析验证，结果与标准值符合。  相似文献   

从景观生态学构建城市旅游开发与规划的操作模式   总被引：13，自引：0，他引：13  

李蕾蕾 《地理研究》1995,14(3):69-73

本文尝试建立一个关于旅游开发与规划的应用理论模式,以兼顾理论的抽象性和操作性。模式的构建依据地理空间分析方法,同时借用景观生态学斑、廊、基的概念。文中详细论述了该斑廊基网络结构操作模式的基本特点、变换空间分析方法等运行机制,并以不同城市旅游规划、设计实例说明三大操作块的功能和操作意义。  相似文献   

气象场相关结构对EOFs展开稳定性的影响   总被引：4，自引：2，他引：4       下载免费PDF全文

丁裕国  江志红 《气象学报》1993,51(4):448-456

本文从矩阵扰动理论出发,提出利用矩阵的范数(norm)作为度量气象场随机扰动的稳定性指标,并由此间接推估EOFs展开的稳定性。经理论论证、数值试验和实例计算表明,气象场的相关性越好,达到稳定相关结构所需样本越小,由此得到的EOFs稳定性也越好,反之则不然。上述规律又直接受样本大小n和站点数目p的影响。对于不同的气象场来说,达到稳定EOFs的样本临界值不同,必须警惕EOFs展开有可能不是稳定的。  相似文献   

裂隙各向异性介质波场VSP多分量记录的数值模拟   总被引：5，自引：2，他引：5       下载免费PDF全文

牛滨华  何樵登 《地球物理学报》1995,38(4):519-527

从各向异性介质中最为普遍的裂隙各向异性介质出发，推导了同零井源距ＶＳＰ三分量观测方式相一致的一维三分量波动方程．为了更符合实际观测，引入了坐标旋转，可以模拟井中任意方位的多层各向异性介质的波场响应．用有限元方法进行了波场数值模拟，重点突出了获得凡Ｒ_３×３矩阵剖面的方法，同时对Ｒ_３×３，矩阵剖面进行了一般性的分析解释，事实证明，Ｒ_３×３矩阵剖面含有介质丰富的各向异性信息．  相似文献   

东马珠穆沁旗中铁陨石表面的角砾状橄榄石的特征     

陶克捷  杨主明等 《岩石学报》2001,17(2):321-324

东乌珠穆沁旗中铁陨石中有二种橄榄石。一种是陨石中基质橄榄石，另一种是镶嵌在陨石表面的角砾状橄榄石。电子探针成分分析结果表明，两种橄榄石中的FeO和MnO比值，包体矿物种类，包体铁纹石和镍纹石中Fe,Ni的含量等，均有较大区别。陨石中基质橄榄石矿物是本陨石中原物质，而角砾状橄榄石是宇宙中物质。他们是两块自由翱于宇宙中的物质碰撞混合而形成的东乌珠穆旗陨石中这种现象。  相似文献   

全球气侯长期振动的Fokker-Planck方程及其求解     

封国林  曹鸿兴  邵耀椿  曹永忠 《气象学报》1996,54(6):753-758

假定行星反照率为温度的平方关系，导出了零维随机动力气候模式。对相应的ＦｏｋｋｅｒＰｌａｎｃｋ方程用矩阵连分法求解，得到了１０万年，４万年，２万年气候周期的本征值和本征向量。数值计算表明，在随机噪声强度Ｄ＝１．９５时，１０万年气候振动具有最大的振幅，即Ｍｉｌａｎｋｏｖｉｔｃｈ理论无法解释的１０万年周期。  相似文献   

不同大地坐标系大地坐标求解转换参数模型的应用和权阵的选取     

朱华统 《测绘学院学报》1992,(3)

本文介绍了布尔莎(L,B,H)公式求解转换参数模型的应用,重点是讨论权阵的选取。其结果表明,按最小二乘平差求转换参数时,必须使用相关权阵。  相似文献   

层次分析法（AHP法）在金矿勘查中的应用—新疆金窝子金矿床为例     

贺连顺 《矿产与地质》1992,6(6):420-424

应用层次分析法（Analystical Hierarchy Process,简称AHP法）确定金窝子金矿床合理的工业品位指标。将影响工业品位的因素及各因素间的隶属关系构成系统的多层次分析结构模型，进行层次排序，制订工业品位指标的总目标，通过分析和计算，确定工业品位指标的最佳方案，取得了较满意的结果。  相似文献   

Application of matrix analysis in delineating sinkhole risk areas along highway (I-70 near Frederick,Maryland)     

Wanfang?ZhouEmail author  Barry?F.?Beck  Angela?L.?Adams 《Environmental Geology》2003,44(7):834-842

Sinkhole collapse in the area of Maryland Interstate 70 (I-70) and nearby roadways south of Frederick, Maryland, has been posing a threat to the safety of the highway operation as well as other structures. The occurrence of sinkholes is associated with intensive land development. However, the geological conditions that have been developing over the past 200 million years in the Frederick Valley control the locations of the sinkholes. Within an area of approximately 8 km², 138 sinkholes are recorded and their spatial distribution is irregular, but clustered. The clustering indicates the existence of an interaction between the sinkholes. The point pattern of sinkholes is considered to be a sample of a Gibbsian point process from which the hard-core Strauss Model is developed. The radius of influence is calculated for the recorded sinkholes which are most likely to occur within 30 m of an existing sinkhole. The stochastic analysis of the existing sinkholes is biased toward the areas with intensive land use. This bias is adjusted by considering (1) topography, (2) proximity to topographic depressions, (3) interpreted rock formation, (4) soil type, (5) geophysical anomalies, (6) proximity to geologic structures, and (7) thickness of overburden. Based on the properties of each factor, a scoring system is developed and the average relative risk score for individual 30-m segments of the study area is calculated. The areas designated by higher risk levels would have greater risk of a sinkhole collapse than the areas designated by lower risk levels. This risk assessment approach can be updated as more information becomes available.  相似文献